DOI: 10.1039/c5cc04247j. Facile rotation around a silicon–phosphorus double bond enabled through coordination to tungsten

Facile rotation around a silicon–phosphorus double bond enabled through coordination to tungsten

10.1039/c5cc04247j

Crossref journal-article

Royal Society of Chemistry (RSC)

Chemical Communications (292)

Abstract

Coordination of a zwitterionic phosphasilene to tungsten significantly weakens its SiP bond, so rotation and E/Z-isomerization of a SiP bond were observed for the first time.

Bibliography

Breit, N. C., SzilvÃ¡si, T., & Inoue, S. (2015). Facile rotation around a siliconâphosphorus double bond enabled through coordination to tungsten. Chemical Communications, 51(56), 11272â11275.

Authors 3

Nora C. Breit (first)
Tibor Szilvási (additional)
Shigeyoshi Inoue (additional)

References 33 Referenced 29

E. L. Eliel and S. H.Wilen , Stereochemistry of Organic Compounds , John Wiley & Sons, Ltd , New York , 1994 , pp. 544–550 / Stereochemistry of Organic Compounds by Eliel (1994)
I. Fleming , Molecular Orbitals and Organic Chemical Reactions , John Wiley & Sons, Ltd , 2010 , p. 101 (10.1002/9780470689493) / Molecular Orbitals and Organic Chemical Reactions by Fleming (2010)
10.1016/S0040-4039(01)89865-8 / Tetrahedron Lett. by Shvo (1967)
10.1021/om00124a004 / Organometallics by Michalczyk (1985)
10.1021/ja00181a052 / J. Am. Chem. Soc. by Batcheller (1990)
10.1021/om990982k / Organometallics by Kira (2000)
10.1021/ja00075a096 / J. Am. Chem. Soc. by Tokitoh (1993)
10.1021/ja00274a074 / J. Am. Chem. Soc. by Yokelson (1986)
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10.1002/anie.201005866 / Angew. Chem., Int. Ed. by Sen (2011)
10.1021/ja4072699 / J. Am. Chem. Soc. by Hansen (2013)
10.1002/chem.201303906 / Chem. – Eur. J. by Hansen (2014)
10.1002/chem.201402693 / Chem. – Eur. J. by Breit (2014)
10.1016/S0022-328X(96)06483-2 / J. Organomet. Chem. by Driess (1997)
10.1002/anie.200504145 / Angew. Chem., Int. Ed. by Driess (2006)
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10.1021/ja409720c / J. Am. Chem. Soc. by Breit (2013)
10.1002/anie.199002951 / Angew. Chem., Int. Ed. Engl. by Karsch (1990)
10.1021/ja074019e / J. Am. Chem. Soc. by So (2007)
10.1021/om3003762 / Organometallics by Azhakar (2012)
10.1021/om3008184 / Organometallics by Cui (2013)
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10.1021/om3008794 / Organometallics by Azhakar (2012)
10.1021/ja210697p / J. Am. Chem. Soc. by Azhakar (2012)
10.1002/anie.201203109 / Angew. Chem., Int. Ed. by Junold (2012)

Dates

Type	When
Created	10 years, 2 months ago (June 10, 2015, 6:07 a.m.)
Deposited	1 year, 4 months ago (April 17, 2024, 1:43 p.m.)
Indexed	6 months, 1 week ago (Feb. 21, 2025, 3:08 a.m.)
Issued	10 years, 8 months ago (Jan. 1, 2015)
Published	10 years, 8 months ago (Jan. 1, 2015)
Published Online	10 years, 8 months ago (Jan. 1, 2015)

Funders 1

Alexander von Humboldt-Stiftung 10.13039/100005156
Region: Europe
pri (Trusts, charities, foundations (both public and private))
Labels5
1. Humboldt-Stiftung
2. Humboldt Foundation
3. Alexander von Humboldt Foundation
4. Humboldt Stiftung
5. AvH
Awards1
1. Sofia Kovalevskaja Program

BibTeX

@article{Breit_2015, title={Facile rotation around a silicon–phosphorus double bond enabled through coordination to tungsten}, volume={51}, ISSN={1364-548X}, url={http://dx.doi.org/10.1039/c5cc04247j}, DOI={10.1039/c5cc04247j}, number={56}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Breit, Nora C. and Szilvási, Tibor and Inoue, Shigeyoshi}, year={2015}, pages={11272–11275} }

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      "value": "This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)",
      "name": "copyright_licence",
      "label": "OPEN ACCESS",
      "group": {
        "name": "copyright_licensing",
        "label": "COPYRIGHT AND LICENSING"
      }
    },
    {
      "value": "Single-blind",
      "order": 2,
      "name": "peer_review_method",
      "group": {
        "name": "peer_review_method",
        "label": "PEER REVIEW METHOD"
      }
    },
    {
      "value": "Received 22 May 2015; Accepted 9 June 2015;  Accepted Manuscript published 10 June 2015;  Advance Article published 17 June 2015;  Version of Record published 30 June 2015",
      "order": 1,
      "name": "history",
      "group": {
        "name": "publication_history",
        "label": "PUBLICATION HISTORY"
      }
    }
  ]
}