Abstract
We present that earth-abundant and environmentally friendly SnS is a promising thermoelectric material due to its high ZT of 0.6 despite its relatively wide band gap of 1.2 eV. Ag doping significantly improved electrical conductivity but maintained the Seebeck coefficient above 400 μV K−1 and the thermal conductivity below 0.45 W m−1 K−1 at 873 K.
References
38
Referenced
281
10.1126/science.1158899
/ Science by Bell (2008)10.1021/cm902195j
/ Chem. Mater. by Kanatzidis (2010)10.1038/nmat2090
/ Nat. Mater. by Snyder (2008)10.1179/095066003225010182
/ Int. Mater. Rev. by Chen (2003)10.1126/science.1156446
/ Science by Poudel (2008)10.1039/c1cc16368j
/ Chem. Commun. by Ge (2011){'key': 'C4TA04462B-(cit7)/*[position()=1]', 'first-page': '412', 'volume': '11', 'author': 'Liu', 'year': '2012', 'journal-title': 'Nat. Mater.'}
/ Nat. Mater. by Liu (2012)10.1088/0022-3727/43/8/085406
/ J. Phys. D: Appl. Phys. by Liu (2010)10.1103/PhysRevLett.108.166601
/ Phys. Rev. Lett. by Liu (2012)10.1002/adma.201004782
/ Adv. Mater. by Nong (2011)10.1021/ja410753k
/ J. Am. Chem. Soc. by Heinrich (2014)10.1063/1.3485050
/ Appl. Phys. Lett. by Zhao (2010)10.1039/c2nr31193c
/ Nanoscale by Liang (2012)10.1038/nature13184
/ Nature by Zhao (2014)10.1016/j.jallcom.2005.02.025
/ J. Alloys Compd. by Nassary (2005)10.1080/0895795031000114368
/ High Pressure Res. by Patel (2003){'key': 'C4TA04462B-(cit16)/*[position()=1]', 'first-page': '549', 'volume': '6', 'author': 'Nariya', 'year': '2009', 'journal-title': 'Chalcogenide Lett.'}
/ Chalcogenide Lett. by Nariya (2009)10.1016/j.apsusc.2011.10.124
/ Appl. Surf. Sci. by Jayasree (2012)10.1016/j.apsusc.2011.02.116
/ Appl. Surf. Sci. by Gao (2011)10.1016/j.matlet.2010.12.029
/ Mater. Lett. by Sohila (2011){'key': 'C4TA04462B-(cit20)/*[position()=1]', 'first-page': '15', 'volume': '1', 'author': 'Shaposhnikov', 'year': '2012', 'journal-title': 'ScienceJet'}
/ ScienceJet by Shaposhnikov (2012)10.1063/1.3496661
/ J. Appl. Phys. by Parker (2010)10.1039/C4CP02871F
/ Phys. Chem. Chem. Phys. by Bera (2014)10.1007/s11664-014-3127-0
/ J. Electron. Mater. by Tan (2014)10.1051/rphysap:01984001909080700
/ Rev. Phys. Appl. by Chattopadhyay (1984)10.1016/0022-3697(86)90059-4
/ J. Phys. Chem. Solids by Chattopadhyay (1986)10.1016/0368-2048(78)85029-4
/ J. Electron Spectrosc. Relat. Phenom. by Romand (1978)- O. Madelung , U.Rössler and M.Schulz, Landolt–Börnstein-Group III Condensed Matter, Springer, Verlag, 1983 / Landolt–Börnstein-Group III Condensed Matter by Madelung (1983)
10.1021/j100063a022
/ J. Phys. Chem. by Vogel (1994){'key': 'C4TA04462B-(cit30)/*[position()=1]', 'first-page': '156', 'volume': '172', 'author': 'von der Oster', 'year': '1982', 'journal-title': 'Landolt-Börnstein'}
/ Landolt-Börnstein by von der Oster (1982)10.1039/C0EE00517G
/ Energy Environ. Sci. by Zevalkink (2011)10.1038/nature09996
/ Nature by Pei (2011)-
D. W. Rowe , Materials, Preparation, and Characterization in Thermoelectrics, CRC Press, New York, 2012
(
10.1201/b11891
) / Materials, Preparation, and Characterization in Thermoelectrics by Rowe (2012) 10.1021/ja306527n
/ J. Am. Chem. Soc. by Zhao (2012)10.1007/s11664-009-0975-0
/ J. Electron. Mater. by Ohta (2010)10.1016/j.actamat.2012.09.035
/ Acta Mater. by Ohta (2012)10.1063/1.3130718
/ Appl. Phys. Lett. by Liu (2009)10.1063/1.4789389
/ Appl. Phys. A: Mater. Sci. Process. by Suekuni (2013)
Dates
Type | When |
---|---|
Created | 10 years, 11 months ago (Sept. 8, 2014, 7:05 a.m.) |
Deposited | 1 year, 4 months ago (April 17, 2024, 12:51 p.m.) |
Indexed | 4 days, 20 hours ago (Aug. 30, 2025, 1:05 p.m.) |
Issued | 11 years, 8 months ago (Jan. 1, 2014) |
Published | 11 years, 8 months ago (Jan. 1, 2014) |
Published Online | 11 years, 8 months ago (Jan. 1, 2014) |
@article{Tan_2014, title={Thermoelectrics with earth abundant elements: low thermal conductivity and high thermopower in doped SnS}, volume={2}, ISSN={2050-7496}, url={http://dx.doi.org/10.1039/c4ta04462b}, DOI={10.1039/c4ta04462b}, number={41}, journal={J. Mater. Chem. A}, publisher={Royal Society of Chemistry (RSC)}, author={Tan, Qing and Zhao, Li-Dong and Li, Jing-Feng and Wu, Chao-Feng and Wei, Tian-Ran and Xing, Zhi-Bo and Kanatzidis, Mercouri G.}, year={2014}, pages={17302–17306} }