DOI: 10.1038/srep19892. Super Soft All-Ethylene Oxide Polymer Electrolyte for Safe All-Solid Lithium Batteries

Super Soft All-Ethylene Oxide Polymer Electrolyte for Safe All-Solid Lithium Batteries

10.1038/srep19892

Crossref journal-article

Springer Science and Business Media LLC

Scientific Reports (297)

Abstract

AbstractHere we demonstrate that by regulating the mobility of classic −EO− based backbones, an innovative polymer electrolyte system can be architectured. This polymer electrolyte allows the construction of all solid lithium-based polymer cells having outstanding cycling behaviour in terms of rate capability and stability over a wide range of operating temperatures. Polymer electrolytes are obtained by UV-induced (co)polymerization, which promotes an effective interlinking between the polyethylene oxide (PEO) chains plasticized by tetraglyme at various lithium salt concentrations. The polymer networks exhibit sterling mechanical robustness, high flexibility, homogeneous and highly amorphous characteristics. Ambient temperature ionic conductivity values exceeding 0.1 mS cm−1 are obtained, along with a wide electrochemical stability window (>5 V vs. Li/Li+), excellent lithium ion transference number (>0.6) as well as interfacial stability. Moreover, the efficacious resistance to lithium dendrite nucleation and growth postulates the implementation of these polymer electrolytes in next generation of all-solid Li-metal batteries working at ambient conditions.

Bibliography

Porcarelli, L., Gerbaldi, C., Bella, F., & Nair, J. R. (2016). Super Soft All-Ethylene Oxide Polymer Electrolyte for Safe All-Solid Lithium Batteries. Scientific Reports, 6(1).

Authors 4

Luca Porcarelli (first)
Claudio Gerbaldi (additional)
Federico Bella (additional)
Jijeesh Ravi Nair (additional)

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Dates

Type	When
Created	9 years, 7 months ago (Jan. 21, 2016, 6:13 a.m.)
Deposited	2 years, 7 months ago (Jan. 4, 2023, 6:44 p.m.)
Indexed	1 day, 3 hours ago (Aug. 21, 2025, 2:23 p.m.)
Issued	9 years, 7 months ago (Jan. 21, 2016)
Published	9 years, 7 months ago (Jan. 21, 2016)
Published Online	9 years, 7 months ago (Jan. 21, 2016)

Funders 0

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BibTeX

@article{Porcarelli_2016, title={Super Soft All-Ethylene Oxide Polymer Electrolyte for Safe All-Solid Lithium Batteries}, volume={6}, ISSN={2045-2322}, url={http://dx.doi.org/10.1038/srep19892}, DOI={10.1038/srep19892}, number={1}, journal={Scientific Reports}, publisher={Springer Science and Business Media LLC}, author={Porcarelli, Luca and Gerbaldi, Claudio and Bella, Federico and Nair, Jijeesh Ravi}, year={2016}, month=jan }

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  "abstract": "<jats:title>Abstract</jats:title><jats:p>Here we demonstrate that by regulating the mobility of classic \u2212EO\u2212 based backbones, an innovative polymer electrolyte system can be architectured. This polymer electrolyte allows the construction of all solid lithium-based polymer cells having outstanding cycling behaviour in terms of rate capability and stability over a wide range of operating temperatures. Polymer electrolytes are obtained by UV-induced (co)polymerization, which promotes an effective interlinking between the polyethylene oxide (PEO) chains plasticized by tetraglyme at various lithium salt concentrations. The polymer networks exhibit sterling mechanical robustness, high flexibility, homogeneous and highly amorphous characteristics. Ambient temperature ionic conductivity values exceeding 0.1\u2009mS cm<jats:sup>\u22121</jats:sup> are obtained, along with a wide electrochemical stability window (&gt;5\u2009V <jats:italic>vs.</jats:italic> Li/Li<jats:sup>+</jats:sup>), excellent lithium ion transference number (&gt;0.6) as well as interfacial stability. Moreover, the efficacious resistance to lithium dendrite nucleation and growth postulates the implementation of these polymer electrolytes in next generation of all-solid Li-metal batteries working at ambient conditions.</jats:p>",
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