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References
139
Referenced
339
-
Tang, K.-T. & Toennies, J. P. Johannes Diderik van der Waals: a pioneer in the molecular sciences and nobel prize winner in 1910. Angew. Chem. Int. Ed. 49, 9574–9579 (2010).
(
10.1002/anie.201002332
) / Angew. Chem. Int. Ed. by K-T Tang (2010) -
London, F. Zur Theorie und Systematik der Molekularkräfte. Z. Physik. 63, 245 (1930); English translation available in London, F. The general theory of molecular forces. Trans. Faraday Soc. 33, 8b–26 (1937).
(
10.1007/BF01421741
) / Z. Physik. by F London (1937) -
Parsegian, V. A. in Van der Waals Forces: A Handbook for Biologists, Chemists, Engineers, and Physicists (Cambridge Univ. Press, 2005).
(
10.1017/CBO9780511614606
) / Van der Waals Forces: A Handbook for Biologists, Chemists, Engineers, and Physicists by VA Parsegian (2005) -
Eisenschitz, R. & London, F. Über das Verhältnis der van der Waalsschen Kräfte zu den homöopolaren Bindungskräften. Z. Phys. 60, 491–527 (in German) (1930).
(
10.1007/BF01341258
) / Z. Phys. by R Eisenschitz (1930) -
Pace, N. C., Scholtz, J. M. & Grimsley, G. R. Forces stabilizing proteins. FEBS Lett. 588, 2177–2184 (2014).
(
10.1016/j.febslet.2014.05.006
) / FEBS Lett. by NC Pace (2014) -
Biedermann, F. & Schneider, H.-J. Experimental binding energies in supramolecular complexes. Chem. Rev. 116, 5216–5300 (2016).
(
10.1021/acs.chemrev.5b00583
) / Chem. Rev. by F Biedermann (2016) -
Mosher, H. S. & Tidwell, T. T. Frank C. Whitmore and steric hindrance: a duo of centennials. J. Chem. Educ. 67, 9–14 (1990).
(
10.1021/ed067p9
) / J. Chem. Educ. by HS Mosher (1990) - Newman, M. S. Steric Effects in Organic Chemistry (Wiley, 1956). / Steric Effects in Organic Chemistry by MS Newman (1956)
-
Power, P. P. Some highlights from the development and use of bulky monodentate ligands. J. Organomet. Chem. 689, 3904–3919 (2004).
(
10.1016/j.jorganchem.2004.06.010
) / J. Organomet. Chem. by PP Power (2004) -
Clyburne, J. A. C. & McMullen, N. Unusual structures of main group organometallic compounds containing m-terphenyl ligands. Coord. Chem. Rev. 210, 73–99 (2000).
(
10.1016/S0010-8545(00)00317-9
) / Coord. Chem. Rev. by JAC Clyburne (2000) - Twamley, B., Haubrich, S. T. & Power, P. P. in Advances in Organometallic Chemistry Vol. 44 1–65 (Academic Press, 1999). / Advances in Organometallic Chemistry by B Twamley (1999)
-
Ni, C. & Power, P. P. in Metal–Metal Bonding Vol. 136 (ed. Parkin, G. ) 59–111 (Springer, 2010).
(
10.1007/978-3-642-05243-9_3
) / Metal–Metal Bonding by C Ni (2010) -
Arduengo, A. J. III Looking for stable carbenes: the difficulty in starting anew. Acc. Chem. Res. 32, 913–921 (1999).
(
10.1021/ar980126p
) / Acc. Chem. Res. by AJ Arduengo III (1999) -
Bourissou, D., Guerret, O., Gabbai, F. P. & Bertrand, G. Stable carbenes. Chem. Rev. 100, 39–92 (2000).
(
10.1021/cr940472u
) / Chem. Rev. by D Bourissou (2000) -
Valente, C. et al. Complexes for the most-challenging cross-coupling reactions. Angew. Chem. Int. Ed. 51, 3314–3332 (2012).
(
10.1002/anie.201106131
) / Angew. Chem. Int. Ed. by C Valente (2012) - Scott, N. M. & Nolan, S. P. Stabilization of organometallic species achieved by the use of N-heterocyclic carbene (NHC) ligands. Eur. J. Inorg. Chem. 18, 5–1828 (2005). / Eur. J. Inorg. Chem. by NM Scott (2005)
-
Asay, M., Jones, C. & Driess, M. N-Heterocyclic carbene analogues with low-valent group 13 and group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands. Chem. Rev. 111, 354–396 (2011).
(
10.1021/cr100216y
) / Chem. Rev. by M Asay (2011) -
Jones, C. Bulky guanidinates for the stabilization of low oxidation state metallacycles. Coord. Chem. Rev. 254, 1273–1289 (2010).
(
10.1016/j.ccr.2009.07.014
) / Coord. Chem. Rev. by C Jones (2010) - Edelmann, F. T. in Advances in Organometallic Chemistry Vol. 57 (eds hill, F. E. & Fink, M. J. ) 183–352 (Academic Press, 2008). / Advances in Organometallic Chemistry by FT Edelmann (2008)
- Mindiola, D. J., Holland, P. L. & Warren, T. H. in Inorganic Syntheses (ed. Rauchfuss, T. B. ) (Wiley, 2010). / Inorganic Syntheses by DJ Mindiola (2010)
-
Bourget-Merle, L., Lappert, M. F. & Severin, J. R. The chemistry of β-diketiminatometal complexes. Chem. Rev. 102, 3031–3066 (2002).
(
10.1021/cr010424r
) / Chem. Rev. by L Bourget-Merle (2002) -
Schreiner, P. R. et al. Overcoming lability of extremely long alkane carbon–carbon bonds through dispersion forces. Nature 477, 308–311 (2011).
(
10.1038/nature10367
) / Nature by PR Schreiner (2011) -
Fokin, A. A. et al. Stable alkanes containing very long carbon–carbon bonds. J. Am. Chem. Soc. 134, 13641–13650 (2012).
(
10.1021/ja302258q
) / J. Am. Chem. Soc. by AA Fokin (2012) -
Grimme, S. & Schreiner, P. R. Steric crowding can stabilize a labile molecule: solving the hexaphenylethane riddle. Angew. Chem. Int. Ed. 50, 12639–12642 (2011).
(
10.1002/anie.201103615
) / Angew. Chem. Int. Ed. by S Grimme (2011) -
Echeverría, J., Aullón, G., Danovich, D., Shaik, S. & Alvarez, S. Dihydrogen contacts in alkanes are subtle but not faint. Nat. Chem. 3, 323–330 (2011).
(
10.1038/nchem.1004
) / Nat. Chem. by J Echeverría (2011) -
Pyykkö, P. Strong closed-shell interactions in inorganic chemistry. Chem. Rev. 97, 597–636 (1997).
(
10.1021/cr940396v
) / Chem. Rev. by P Pyykkö (1997) -
Brandenburg, J. G., Hocheim, M., Bredow, T. & Grimme, S. Low-cost quantum chemical methods for noncovalent interactions. J. Phys. Chem. Lett. 5, 4275–4284 (2014).
(
10.1021/jz5021313
) / J. Phys. Chem. Lett. by JG Brandenburg (2014) -
Fey, N., Ridgway, B. M., Jover, J., McMullin, C. L. & Harvey, J. N. Organometallic reactivity: the role of metal–ligand bond energies from a computational perspective. Dalton Trans. 40, 11184–11191 (2011).
(
10.1039/c1dt10909j
) / Dalton Trans. by N Fey (2011) -
Grimme, S. Accurate description of van der Waals complexes by density functional theory including empirical corrections. J. Comput. Chem. 25, 1463–1473 (2004).
(
10.1002/jcc.20078
) / J. Comput. Chem. by S Grimme (2004) -
Grimme, S. Semiempirical GGA-type density functional constructed with a long-range dispersion correction. J. Comput. Chem. 27, 1787–1799 (2006).
(
10.1002/jcc.20495
) / J. Comput. Chem. by S Grimme (2006) -
Alrichs, R., Penco, R. & Scoles, G. Intermolecular forces in simple systems. Chem. Phys. 19, 119–130 (1977).
(
10.1016/0301-0104(77)85124-0
) / Chem. Phys. by R Alrichs (1977) -
Becke, A. D. & Johnson, E. R. A density-functional model of the dispersion interaction. J. Chem. Phys. 123, 154101 (2005).
(
10.1063/1.2065267
) / J. Chem. Phys. by AD Becke (2005) -
Jurecˇka, P., Cˇerny, J., Hobza, P. & Salahub, D. R. Density functional theory augmented with an empirical dispersion term. Interaction energies and geometries of 80 noncovalent complexes compared with ab initio quantum mechanics calculations. J. Comput. Chem. 28, 555–569 (2007).
(
10.1002/jcc.20570
) / J. Comput. Chem. by P Jurecˇka (2007) -
Zhao, Y. & Truhlar, D. G. Density functionals with broad applicability in chemistry. Acc. Chem. Res. 41, 157–167 (2008).
(
10.1021/ar700111a
) / Acc. Chem. Res. by Y Zhao (2008) -
Zhao, Y. & Truhlar, D. G. Applications and validations of the Minnesota density functionals. Chem. Phys. Lett. 502, 1–13 (2011).
(
10.1016/j.cplett.2010.11.060
) / Chem. Phys. Lett. by Y Zhao (2011) -
Johnson, E. R. & Becke, A. D. Van der Waals interactions from the exchange hole dipole moment: application to bio-organic benchmark systems. J. Chem. Phys. Lett. 432, 600–603 (2006).
(
10.1016/j.cplett.2006.10.094
) / J. Chem. Phys. Lett. by ER Johnson (2006) -
Becke, A. D. & Johnson, E. R. A unified density-functional treatment of dynamical, nondynamical, and dispersion correlations. J. Chem. Phys. 127, 124108 (2007).
(
10.1063/1.2768530
) / J. Chem. Phys. by AD Becke (2007) -
Ruszinsky, A., Perdew, J. P. & Csonka, G. J. A simple but fully nonlocal correction to the random phase approximation. J. Chem. Phys. 134, 114110 (2011).
(
10.1063/1.3569483
) / J. Chem. Phys. by A Ruszinsky (2011) -
Eshuis, H., Yarkony, J. & Furche, F. Fast computation of molecular random phase approximation correlation energies using resolution of the identity and imaginary frequency integration. J. Chem. Phys. 132, 234114 (2010).
(
10.1063/1.3442749
) / J. Chem. Phys. by H Eshuis (2010) -
Furche, F. & Perdew, J. P. The performance of semilocal and hybrid density functionals in 3d transition-metal chemistry. J. Chem. Phys. 124, 044103 (2006).
(
10.1063/1.2162161
) / J. Chem. Phys. by F Furche (2006) -
Jiménez-Hoyos, C. A., Janesko, B. G. & Scuseria, G. E. Evaluation of range-separated hybrid and other density functional approaches on test sets relevant for transition metal-based homogeneous catalysts. J. Phys. Chem. A. 113, 11742–11749 (2009).
(
10.1021/jp902879m
) / J. Phys. Chem. A. by CA Jiménez-Hoyos (2009) -
Ryde, U., Mata, R. A. & Grimme, S. Does DFT-D estimate accurate energies for the binding of ligands to metal complexes? Dalton Trans. 40, 11176–11183 (2011).
(
10.1039/c1dt10867k
) / Dalton Trans. by U Ryde (2011) -
Swart, M., Solá, M. & Bickelhaupt, F. M. Inter- and intramolecular dispersion interactions. J. Comput. Chem. 32, 1117–1127 (2011).
(
10.1002/jcc.21693
) / J. Comput. Chem. by M Swart (2011) -
Yang, L., Adam, C., Nichol, G. S. & Cockroft, S. L. How much do van der Waals dispersion forces contribute to molecular recognition in solution? Nat. Chem. 5, 1006–1010 (2013).
(
10.1038/nchem.1779
) / Nat. Chem. by L Yang (2013) -
Hansen, A. et al. The thermochemistry of london dispersion-driven transition metal reactions: getting the ‘right answer for the right reason’. ChemistryOpen 3, 177–189 (2014).
(
10.1002/open.201402017
) / ChemistryOpen by A Hansen (2014) -
Kronik, L. & Tkatchenko, A. Understanding molecular crystals with dispersion-inclusive density functional theory: pairwise corrections and beyond. Acc. Chem. Res. 47, 3208–3216 (2014).
(
10.1021/ar500144s
) / Acc. Chem. Res. by L Kronik (2014) -
Berland, K. et al. I. van der Waals forces in density functional theory: a review of the vdW-DF method. Rep. Prog. Phys. 78, 066501 (2015).
(
10.1088/0034-4885/78/6/066501
) / Rep. Prog. Phys. by K Berland (2015) -
Grimme, S. in The Chemical Bond: Chemical Bonding Across the Periodic Table (eds Frenking, G. & Shaik, S. ) 477–500 (Wiley, 2014).
(
10.1002/9783527664658.ch16
) / The Chemical Bond: Chemical Bonding Across the Periodic Table by S Grimme (2014) -
Grimme, S., Hansen, A., Brandenburg, J. G. & Bannwarth, C. Dispersion-corrected mean-field electronic structure methods. Chem. Rev. 116, 5105–5154 (2016).
(
10.1021/acs.chemrev.5b00533
) / Chem. Rev. by S Grimme (2016) -
Bondi, A. Van der Waals volumes and radii. J. Phys. Chem. 68, 441–451 (1964).
(
10.1021/j100785a001
) / J. Phys. Chem. by A Bondi (1964) -
Gomberg, M. Triphenylmethyl, ein Fall von dreiwerthigem Kohlenstoff. Ber. Dtsch. Chem. Ges. 33, 3150–3163 (in German) (1900).
(
10.1002/cber.19000330369
) / Ber. Dtsch. Chem. Ges. by M Gomberg (1900) -
Gomberg, M. An instance of trivalent carbon: triphenylmethyl. J. Am. Chem. Soc. 22, 757–771 (1900).
(
10.1021/ja02049a006
) / J. Am. Chem. Soc. by M Gomberg (1900) -
Lankamp, H., Nauta, W. Th. & MacLean, C. A new interpretation of the monomer-dimer equilibrium of triphenylmethyl- and alkylsubstituted-diphenyl methyl-radicals in solution. Tetrahedron Lett. 9, 249–254 (1968).
(
10.1016/S0040-4039(00)75598-5
) / Tetrahedron Lett. by H Lankamp (1968) -
Stein, M., Winter, W. & Rieker, A. Hexakis(2,6-di-tert-butyl-4-biphenylyl)ethane — the first unbridged hexaarylethane. Angew. Chem. Int. Ed. Engl. 17, 692–694 (1978).
(
10.1002/anie.197806921
) / Angew. Chem. Int. Ed. Engl. by M Stein (1978) -
Kahr, B., van Engen, D. & Mislow, K. Length of the ethane bond in hexaphenylethane and its derivatives. J. Am. Chem. Soc. 108, 8305–8307 (1986).
(
10.1021/ja00286a053
) / J. Am. Chem. Soc. by B Kahr (1986) -
Wagner, J. P. & Schreiner, P. R. London dispersion in molecular chemistry — reconsidering steric effects. Angew. Chem. Int. Ed. 54, 12274–12296 (2016).
(
10.1002/anie.201503476
) / Angew. Chem. Int. Ed. by JP Wagner (2016) -
Schwertfeger, H., Fokin, A. A. & Schreiner, P. R. Diamonds are a chemist's best friend: diamondoid chemistry beyond adamantane. Angew. Chem. Int. Ed. 47, 1022–1036 (2008).
(
10.1002/anie.200701684
) / Angew. Chem. Int. Ed. by H Schwertfeger (2008) -
Maier, G., Pfriem, S., Schäfer, R. & Mausch, R. Tetra-tert-butyltetrahedrane. Angew. Chem. Int. Ed. 17, 520–521 (1978).
(
10.1002/anie.197805201
) / Angew. Chem. Int. Ed. by G Maier (1978) -
Balci, M., McKee, M. & Schleyer, P. v. R. Theoretical study of tetramethyl- and tetra-tert-butyl-substituted cyclobutadiene and tetrahedrane. J. Phys. Chem. 104, 1246–1255 (2000).
(
10.1021/jp9922054
) / J. Phys. Chem. by M Balci (2000) -
Monteiro, N. K. V., de Oliveira, J. F. & Firme, C. L. Stability and electronic structures of substituted tetrahedranes, silicon and germanium parents — a DFT, ADMP, QTAIM and GVB study. New. J. Chem. 38, 5892–5904 (2014).
(
10.1039/C4NJ01271B
) / New. J. Chem. by NKV Monteiro (2014) -
Nemirowski, A., Reisenauer, H. P. & Schreiner, P. R. Tetrahedrane — dossier of an unknown. Chem. Eur. J. 12, 7411–7420 (2006).
(
10.1002/chem.200600451
) / Chem. Eur. J. by A Nemirowski (2006) -
Wiberg, N. Sterically overloaded supersilylated main group elements and main group element clusters. Coord. Chem. Rev. 163, 217–252 (1997).
(
10.1016/S0010-8545(97)00012-X
) / Coord. Chem. Rev. by N Wiberg (1997) -
Schäfer, A., Weidenbruch, M., Peters, K. & von Schnering, H. Hexa-tert-butylcyclotrisilane, a strained molecule with unusually long Si–Si and Si–C bonds. Angew. Chem. Int. Ed. 23, 302–303 (1984).
(
10.1002/anie.198403021
) / Angew. Chem. Int. Ed. by A Schäfer (1984) -
Wiberg, N., Schuster, A., Simon, A. & Peters, K. Hexa-tert-butyldisilane — the molecule with the longest Si–Si bond. Angew. Chem. Int. Ed. 25, 79–80 (1986).
(
10.1002/anie.198600791
) / Angew. Chem. Int. Ed. by N Wiberg (1986) -
Pyykkö, P. & Atsumi, M. Molecular single-bond covalent radii for elements 1–118. Chem. Eur. J. 15, 186–197 (2008).
(
10.1002/chem.200800987
) / Chem. Eur. J. by P Pyykkö (2008) - Pauling, L. Nature of the Chemical Bond 239 (Cornell Univ. Press, 1960). / Nature of the Chemical Bond by L Pauling (1960)
-
Paolini, J. P. The bond order–bond length relationship. J. Comput. Chem. 11, 1160–1163 (1990).
(
10.1002/jcc.540111007
) / J. Comput. Chem. by JP Paolini (1990) -
Bock, H., Meuret, J. & Ruppert, K. Sterically overcrowded or charge perturbed molecules: XXIII. Hexakis(trimethylsilyl)disilane: structure and photoelectron spectrum of a sterically overcrowded molecule. J. Organomet. Chem. 445, 19–28 (1993).
(
10.1016/0022-328X(93)80181-A
) / J. Organomet. Chem. by H Bock (1993) -
Weidenbruch, M. et al. Hexa-t-butyldigerman und Hexa-t-butylcyclotrigerman: moleküle mit den derzeit längsten Ge–Ge− und Ge–C-Bindungen. J. Organomet. Chem. 341, 335–343 (in German) (1988).
(
10.1016/0022-328X(88)89087-9
) / J. Organomet. Chem. by M Weidenbruch (1988) -
Puff, H. et al. Bindungsabstände zwischen organylsubstituierten Zinnatomen: III. Offenkettige Verbindungen. J. Organomet. Chem. 363, 265–280 (in German) (1989).
(
10.1016/0022-328X(89)87114-1
) / J. Organomet. Chem. by H Puff (1989) -
Wiberg, N. et al. Tetrasupersilyl-tristannaallene and -tristannacyclopropene (tBu3Si)4Sn3 — isomers with the shortest S=Sn double bonds to date. Eur. J. Inorg. Chem. 1999, 1211–1218 (1999).
(
10.1002/(SICI)1099-0682(199908)1999:8<1211::AID-EJIC1211>3.0.CO;2-0
) / Eur. J. Inorg. Chem. by N Wiberg (1999) -
Peng, Y. et al. Substituent effects in ditetrel alkyne analogues: multiple versus single bonded isomers. Chem. Sci. 1, 461–468 (2010).
(
10.1039/c0sc00240b
) / Chem. Sci. by Y Peng (2010) -
Wiberg, N., Amelunxen, K., Blank, T., Nöth, H. & Knizek, J. Tetrasupersilyldialuminum [(t-Bu)3Si]2Al–Al[Si(t-Bu)3]2: the dialane(4) with the longest Al–Al bond to date. J. Organometallics 17, 5431–5433 (1998).
(
10.1021/om980469r
) / J. Organometallics by N Wiberg (1998) -
Uhl, W. Tetrakis[bis(trimethylsilyl)methyl]dialan(4), eine Verbindung mit Aluminium–Aluminium-Bindung. Z. Naturforsch. B 43, 1113–1118 (in German) (1988).
(
10.1515/znb-1988-0905
) / Z. Naturforsch. B by W Uhl (1988) -
Wehmschulte, R. J. et al. Reduction of a tetraaryldialane to generate Al–Al π-bonding. Inorg. Chem. 32, 2983–2984 (1993).
(
10.1021/ic00066a002
) / Inorg. Chem. by RJ Wehmschulte (1993) -
Wiberg, N. et al. Ditrielanes (R3Si)2E–E(SiR3)2 and heterocubanes (R3Si)4E4Y4 (R3Si = tBu3Si, tBu2PhSi; E = Al, Ga, In, Tl; Y = O, Se). Eur. J. Inorg. Chem. 341–350 (2002).
(
10.1002/1099-0682(20022)2002:2<341::AID-EJIC341>3.0.CO;2-K
) / European Journal of Inorganic Chemistry by Nils Wiberg (2002) -
Wiberg, N. et al. Tris(tri-tert-butylsilyl)digallanyl (tBu3Si)3Ga2: a new type of compound for a heavy group 13 element. Angew. Chem. Int. Ed. 36, 1213–1215 (1997).
(
10.1002/anie.199712131
) / Angew. Chem. Int. Ed. by N Wiberg (1997) -
Power, P. P. π-Bonding and the lone pair effect in multiple bonds between heavier main group elements. Chem. Rev. 99, 3463–3503 (1999).
(
10.1021/cr9408989
) / Chem. Rev. by PP Power (1999) -
Fischer, R. C. & Power, P. P. π-Bonding and the lone pair effect in multiple bonds involving heavier main group elements: developments in the new millennium. Chem. Rev. 110, 3877–3923 (2010).
(
10.1021/cr100133q
) / Chem. Rev. by RC Fischer (2010) -
Arp, H., Baumgartner, J., Marschner, C., Zark, P. & Müller, T. Dispersion energy enforced dimerization of a cyclic disilylated plumbylene. J. Am. Chem. Soc. 134, 6409–6415 (2012).
(
10.1021/ja300654t
) / J. Am. Chem. Soc. by H Arp (2012) -
Weidenbruch, M., Kilian, H., Peters, K., von Schnering, H. G. & Marsmann, H. Compounds of germanium and tin, 16. A tetraaryldistannene with a long tin–tin multiple bond and differing environments at the tin atoms. Chem. Ber. 128, 983–985 (1995).
(
10.1002/cber.19951281004
) / Chem. Ber. by M Weidenbruch (1995) -
Guo, J.-D., Liptrot, D. J., Nagase, S. & Power, P. P. The multiple bonding in heavier group 14 element alkene analogues is stabilized mainly by dispersion force effects. Chem. Sci. 6, 6235–6244 (2015).
(
10.1039/C5SC02707A
) / Chem. Sci. by J-D Guo (2015) -
Lee, V. Ya. et al. (tBu2MeSi)2SnSn(SiMetBu2)2: a distannene with a > Sn=Sn < double bond that is stable both in the solid state and in solution. J. Am. Chem. Soc. 128, 11643–11651 (2006).
(
10.1021/ja063322x
) / J. Am. Chem. Soc. by VYa Lee (2006) -
Guo, J.-D., Nagase, S. & Power, P. P. Dispersion force effects on the dissociation of ‘Jack-in-the-box’ diphosphanes and diarsanes. Organometallics 34, 2028–2033 (2015).
(
10.1021/acs.organomet.5b00254
) / Organometallics by J-D Guo (2015) -
Hinchley, S. L. et al. Spontaneous generation of stable pnictinyl radicals from ‘Jack-in-the-box’ dipnictines: a solid-state, gas-phase, and theoretical investigation of the origins of steric Stabilization. J. Am. Chem. Soc. 123, 9045–9053 (2001).
(
10.1021/ja010615b
) / J. Am. Chem. Soc. by SL Hinchley (2001) -
Seidu, I., Seth, M. & Ziegler, T. Role played by isopropyl substituents in stabilizing the putative triple bond in Ar′EEAr′[E = Si, Ge, Sn; Ar′ = C6H3-2,6-(C6H3-2,6-Pri2)2] and Ar*PbPbAr* [Ar* = C6H3-2,6-(C6H2-2,4,6-Pri3)2]. Inorg. Chem. 52, 8378–8388 (2013).
(
10.1021/ic401149h
) / Inorg. Chem. by I Seidu (2013) -
Stender, M., Phillips, A. D., Wright, R. J. & Power, P. P. Synthesis and characterization of a digermanium analogue of an alkyne. Angew. Chem. Int. Ed. 41, 1785–1787 (2002).
(
10.1002/1521-3773(20020517)41:10<1785::AID-ANIE1785>3.0.CO;2-6
) / Angew. Chem. Int. Ed. by M Stender (2002) -
Phillips, A. D., Wright, R. J., Olmstead, M. M. & Power, P. P. Synthesis and characterization of 2,6-Dipp2-H3C6SnSnC6H3-2,6-Dipp2 (Dipp = C6H3-2,6-Pri2): a tin analogue of an alkyne. J. Am. Chem. Soc. 124, 5930–5931 (2002).
(
10.1021/ja0257164
) / J. Am. Chem. Soc. by AD Phillips (2002) -
Pu, L., Twamley, B. & Power, P. P. Synthesis and characterization of 2,6-Trip2H3C6PbPbC6H3-2,6-Trip2 (Trip = C6H2-2,4,6-i-Pr3): a stable heavier group 14 element analogue of an alkyne. J. Am. Chem. Soc. 122, 3524–3525 (2000).
(
10.1021/ja993346m
) / J. Am. Chem. Soc. by L Pu (2000) -
Mitoraj, M., Michalak, A. & Ziegler, T. A. Combined charge and energy decomposition scheme for bond analysis. J. Chem. Theor. Comput. 5, 962–975 (2009).
(
10.1021/ct800503d
) / J. Chem. Theor. Comput. by M Mitoraj (2009) -
Wu, L.-C., Jones, C., Stasch, A., Platts, J. A. & Overgaard, J. Non-nuclear attractor in a molecular compound under external pressure. Eur. J. Inorg. Chem. 32, 5536–5540 (2014).
(
10.1002/ejic.201402606
) / Eur. J. Inorg. Chem. by L-C Wu (2014) -
Wagner, J. P. & Schreiner, P. R. London dispersion decisively contributes to the thermodynamic stability of bulky NHC-coordinated main group compounds. J. Chem. Theor. Comp. 12, 231–237 (2016).
(
10.1021/acs.jctc.5b01100
) / J. Chem. Theor. Comp. by JP Wagner (2016) -
Hänninen, M., Pal, K., Day, B. M., Pugh, T. & Layfield, R. A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces. Dalton Trans. 45, 11301–11305 (2016).
(
10.1039/C6DT02486F
) / Dalton Trans. by M Hänninen (2016) -
Albers, L., Rathjen, S., Baumgartner, J., Marschner, C. & Müller, T. Dispersion-energy-driven Wagner–Meerwein rearrangements in oligosilanes. J. Am. Chem. Soc. 138, 6886–6892 (2016).
(
10.1021/jacs.6b03560
) / J. Am. Chem. Soc. by L Albers (2016) -
Andersen, R. A. et al. The molecular structures of bis(pentamethylcyclopentadienyl)-calcium and -ytterbium in the gas phase; two bent metallocenes. J. Organomet. Chem. 312, C49–C52 (1986).
(
10.1016/0022-328X(86)80328-X
) / J. Organomet. Chem. by RA Andersen (1986) -
Andersen, R. A., Blom, R., Boncella, J. M., Burns, C. J. & Volden, H. V. The thermal average molecular structures of bis(pentamethylcyclopentadienyl)magnesium(ii), -calcium(ii) and -ytterbium(ii) in the gas phase. Acta Chem. Scand. 41A, 24–35 (1987).
(
10.3891/acta.chem.scand.41a-0024
) / Acta Chem. Scand. by RA Andersen (1987) -
Andersen, R. A., Blom, R., Burns, C. J. & Volden, H. V. Synthesis and thermal average gas phase molecular structures of bis(pentamethylcyclopentadienyl)-strontium and -barium; the first organo-strontium and -barium structures. J. Chem. Soc., Chem. Commun. 768–769 (1987).
(
10.1039/c39870000768
) -
Blom, R., Faegri, K. Jr & Volden, H. V. Molecular structures of alkaline earth-metal metallocenes: electron diffraction and ab initio investigations. Organometallics 9, 372–379 (1990).
(
10.1021/om00116a012
) / Organometallics by R Blom (1990) -
Williams, R. A., Hanusa, T. P. & Huffman, J. C. Structures of ionic decamethylmetallocenes: crystallographic characterization of bis(pentamethylcyclopentadienyl)calcium and -barium and a comparison with related organolanthanide species. Organometallics 9, 1128–1134 (1990).
(
10.1021/om00118a036
) / Organometallics by RA Williams (1990) -
Hollis, T. K., Burdett, J. K. & Bosnich, B. Why are bis(pentamethylcyclopentadienyl) complexes, [MCp2*], of calcium, strontium, barium, samarium, europium, and ytterbium bent? Organometallics 12, 3385–3386 (1993).
(
10.1021/om00033a003
) / Organometallics by TK Hollis (1993) -
Timofeeva, T. V., Lii, J.-H. & Allinger, N. L. Molecular mechanics explanation of the metallocene bent sandwich structure. J. Am. Chem. Soc. 117, 7452–7459 (1995).
(
10.1021/ja00133a018
) / J. Am. Chem. Soc. by TV Timofeeva (1995) -
Rekken, B.-D. et al. Dispersion forces and counterintuitive steric effects in main group molecules: heavier group 14 (Si–Pb) dichalcogenolate carbene analogues with sub-90° interligand bond angles. J. Am. Chem. Soc. 135, 10134 (2013).
(
10.1021/ja403802a
) / J. Am. Chem. Soc. by B-D Rekken (2013) -
Eaborn, C. & Smith, J. D. Organometallic compounds containing tris(trimethylsilyl)methyl or related ligands. J. Chem. Soc., Dalton Trans. 1541–1552 (2001).
(
10.1039/b100741f
) -
Eaborn, C., Hitchcock, P. B., Smith, J. D. & Sullivan, A. C. Crystal structure of the tetrahydrofuran adduct of tris(trimethylsilyl)-methyl-lithium, [Li(thf)4][Li{C(SiMe3)3}2], an ate derivative of lithium. J. Chem. Soc., Chem. Commun. 827–828 (1983).
(
10.1039/c39830000827
) -
Buttrus, N. H. et al. The crystal structure of [(pmdeta)Li(μ-Cl)Li(pmdeta)][Li{C(SiMe3)3}2] [pmdeta = Me2N(CH2)2NMe(CH2)2NMe2]. A novel linear chlorine-centred cation. J. Chem. Soc., Chem. Commun. 969–970 (1986).
(
10.1039/C39860000969
) -
Al-Juaid, S. S. et al. Metalation of tris(trimethylsilyl)- and tris(dimethylphenylsilyl)methane with methylsodium: the first dialkylsodate. Angew. Chem. Int. Ed. 33, 1268–1270 (1994).
(
10.1002/anie.199412681
) / Angew. Chem. Int. Ed. by SS Al-Juaid (1994) -
Al-Juaid, S. S. et al. Crystal structures of organometallic compounds of lithium and magnesium containing the bulky ligands C(SiMe3)2(SiMe2X) X = Me, Ph, NMe2, or C5H4N-2. J. Organomet. Chem. 631, 76–86 (2001).
(
10.1016/S0022-328X(01)01032-4
) / J. Organomet. Chem. by SS Al-Juaid (2001) -
Eaborn, C., Hitchcock, P. B., Smith, J. D. & Sullivan, A. C. A novel monomeric alkyl–lithium compound. Crystal structure of [Li{C(SiMe2Ph)3}(tetrahydrofuran)]. J. Chem. Soc., Chem. Commun. 1390–1391 (1983).
(
10.1039/c39830001390
) -
Eaborn, C., Hitchcock, P. B., Smith, J. D. & Sullivan, A. C. Preparation and crystal structure of the tetrahydrofuran adduct of lithium bis [tris(trimethylsilyl)methyl]cuprate, [Li(THF)4] [Cu{C(SiMe3)3}2]. The first structural characterization of a Gilman reagent. J. Organomet. Chem. 263, c23–c25 (1984).
(
10.1016/S0022-328X(00)99192-7
) / J. Organomet. Chem. by C Eaborn (1984) -
Al-Juaid, S. S., Eaborn, C., Hitchcock, P. B., McGeary, C. A. & Smith, J. D. The crystal structure of bis{tris(trimethylsilyl)methyl}magnesium: an example of two-co-ordinate magnesium in the solid state. J. Chem. Soc., Chem. Commun. 1989, 273–274 (1989).
(
10.1039/c39890000273
) / J. Chem. Soc., Chem. Commun. by SS Al-Juaid (1989) -
Al-Juaid, S. S. et al. Preparation, crystal structure, and reactivity of bis {tris(trimethylsilyl) methyl} magnesium. J. Organomet. Chem. 480, 199–203 (1994).
(
10.1016/0022-328X(94)87119-1
) / J. Organomet. Chem. by SS Al-Juaid (1994) -
Eaborn, C. & Hitchcock, P. B. The first structurally characterised solvent-free ς-bonded diorganocalcium, Ca[C(SiMe3)3]2 . Chem. Commun. 1961–1962 (1997).
(
10.1039/a703972g
) -
Westerhausen, M., Rademacher, B. & Poll, W. Trimethylsilyl-substituierte Derivate des Dimethylzinks — Synthese, spektroskopische Charakterisierung und Struktur. J. Organomet. Chem. 421, 175–188 (in German) (1991).
(
10.1016/0022-328X(91)86402-C
) -
Eaborn, C., Jones, K. L., Smith, J. D. & Tavakkoli, K. The remarkable thermal stability of benzyl[tris(dimethylphenylsily)methyl]mercury. How can a bulky ligand stabilize an organometallic compound towards unimolecular dissociation? J. Chem. Soc., Chem. Commun. 1201–1202 (1989).
(
10.1039/c39890001201
) -
Al-Juaid, S. S., Eaborn, C., Lickiss, P. D., Smith, J. Davis, Tavakkoli, K. & Webb, A. D. Preparation, spectroscopic properties and thermal stabilities of organomercury compounds containing the bulky ligand (Me3Si)3C or (PhMe2Si)3C. J. Organomet. Chem. 510, 143–151 (1996).
(
10.1016/0022-328X(95)05866-N
) / J. Organomet. Chem. by SS Al-Juaid (1996) - Ghotra, J. S., Hursthouse, M. B. & Welch, A. J. Three-co-ordinate scandium(iii) and europium(iii); crystal and molecular structures of their trishexamethyldisilylamides. J. Chem. Soc., Chem. Commun. 6, 9–670 (1973). / J. Chem. Soc., Chem. Commun. by JS Ghotra (1973)
-
Evans, W. J., Hughes, L. A. & Hanusa, T. P. Synthesis and crystallographic characterization of an unsolvated, monomeric samarium bis(pentamethylcyclopentadienyl) organolanthanide complex, (C5Me5)2Sm. J. Am. Chem. Soc. 106, 4270–4272 (1984).
(
10.1021/ja00327a037
) / J. Am. Chem. Soc. by WJ Evans (1984) -
Evans, W. J., Forrestal, K. J. & Ziller, J. W. Reaction chemistry of sterically crowded tris(pentamethylcyclopentadienyl)samarium. J. Am. Chem. Soc. 120, 9273–9282 (1998).
(
10.1021/ja9809859
) / J. Am. Chem. Soc. by WJ Evans (1998) -
Evans, W. J., Hughes, L. A. & Hanusa, T. P. Synthesis and X-ray crystal structure of bis(pentamethylcyclopentadienyl) complexes of samarium and europium: (C5Me5)2Sm and (C5Me5)2Eu. Organometallics 5, 1285–1288 (1986).
(
10.1021/om00138a001
) / Organometallics by WJ Evans (1986) -
Evans, W. J., Gonzales, S. L. & Ziller, J. W. Synthesis and X-ray crystal structure of the first tris(pentamethylcyclopentadienyl)metal complex: (η5-C5Me5)3Sm. J. Am. Chem. Soc. 113, 7423–7424 (1991).
(
10.1021/ja00019a050
) / J. Am. Chem. Soc. by WJ Evans (1991) -
Ahlquist, M. S. G. & Norrby, P.-O. Dispersion and back-donation gives tetracoordinate [Pd(PPh3)4]. Angew. Chem. Int. Ed. 50, 11794–11797 (2011).
(
10.1002/anie.201105928
) / Angew. Chem. Int. Ed. by MSG Ahlquist (2011) -
Lyngvi, E., Sanhueza, I. A. & Schoenebeck, F. Dispersion makes the difference: bisligated transition states found for the oxidative addition of Pd(PtBu3)2 to Ar-OSO2R and dispersion-controlled chemoselectivity in reactions with Pd[P(iPr)(tBu2)]2 . Organometallics 34, 805–812 (2015).
(
10.1021/om501199t
) / Organometallics by E Lyngvi (2015) -
Maseras, F. & Eisenstein, O. Opposing steric and electronic contributions in OsCl2H2(PPr3i)2. A theoretical study of an unusual structure. New J. Chem. 22, 5–9 (1998).
(
10.1039/a706748h
) / New J. Chem. by F Maseras (1998) -
Minenkov, Y., Occhipinti, G., Heyndrickx, W. & Jensen, V. R. The nature of the barrier to phosphane dissociation from grubbs olefin metathesis catalysts. Eur. J. Inorg. Chem. 1507–1516 (2012).
(
10.1002/ejic.201100932
) -
Minenkov, Y., Singstad, A., Occhipinti, G. & Jensen, V. R. The accuracy of DFT-optimized geometries of functional transition metal compounds: a validation study of catalysts for olefin metathesis and other reactions in the homogeneous phase. Dalton Trans. 41, 5526–5541 (2012).
(
10.1039/c2dt12232d
) / Dalton Trans. by Y Minenkov (2012) -
Wolters, L. P., Koekkoek, R. & Bickelhaupt, F. M. Role of steric attraction and bite-angle flexibility in metal-mediated C–H bond activation. ACS Catal. 5, 5766–5775 (2015).
(
10.1021/acscatal.5b01354
) / ACS Catal. by LP Wolters (2015) -
Wolstenholme, D. J., Dobson, J. L. & McGrady, G. S. Homopolar dihydrogen bonding in main group hydrides: discovery, consequences, and applications. Dalton Trans. 44, 9718–9731 (2015).
(
10.1039/C5DT00221D
) / Dalton Trans. by DJ Wolstenholme (2015) -
Ndambuki, S. & Ziegler, T. Analysis of the putative Cr–Cr quintuple bond in Ar′CrCrAr′ (Ar′ = C6H3-2,6(C6H3-2,6-Pri2)2 based on the combined natural orbitals for chemical valence and extended transition state method. Inorg. Chem. 51, 7794–7800 (2012).
(
10.1021/ic300824u
) / Inorg. Chem. by S Ndambuki (2012) -
Nguyen, T. et al. Synthesis of a stable compound with fivefold bonding between two chromium(i) centers. Science 310, 844–861 (2005).
(
10.1126/science.1116789
) / Science by T Nguyen (2005) -
Power, P. P. Stable two-coordinate, open-shell (d1–d9) transition metal complexes. Chem. Rev. 112, 3482–3507 (2012).
(
10.1021/cr2004647
) / Chem. Rev. by PP Power (2012) -
Wagner, C. L. et al. Dispersion-force-assisted disproportionation: a stable two-coordinate copper(ii) complex. Angew. Chem. Int. Ed. 55, 10444–10447 (2016).
(
10.1002/anie.201605061
) / Angew. Chem. Int. Ed. by CL Wagner (2016) -
Boynton, J. N. et al. Linear and nonlinear two-coordinate vanadium complexes: synthesis, characterization, and magnetic properties of V(ii) amides. J. Am. Chem. Soc. 135, 10720–10728 (2013).
(
10.1021/ja403244w
) / J. Am. Chem. Soc. by JN Boynton (2013) -
Lin, C.-Y. et al. Dispersion force stabilized two-coordinate transition metal–amido complexes of the –N(SiMe3)Dipp (Dipp = C6H3-2,6-Pri2) ligand: structural, spectroscopic, magnetic, and computational studies. Inorg. Chem. 52, 13584–13593 (2013).
(
10.1021/ic402105m
) / Inorg. Chem. by C-Y Lin (2013) -
Faust, M. et al. The instability of Ni{N(SiMe3)2}2: a fifty year old transition metal silylamide mystery. Angew. Chem. Int. Ed. 54, 12914–12917 (2015).
(
10.1002/anie.201505518
) / Angew. Chem. Int. Ed. by M Faust (2015) -
Bower, B. K. & Tennent, H. G. Transition metal bicyclo[2.2.1]hept-1-yls. J. Am. Chem. Soc. 94, 2512–2518 (1972).
(
10.1021/ja00762a056
) / J. Am. Chem. Soc. by BK Bower (1972) -
Liptrot, D. J., Guo, J.-D., Nagase, S. & Power, P. P. Dispersion forces, disproportionation and stable high-valent late transition metal alkyls. Angew. Chem. Int. Ed. 55, 13655–13659 (2016).
(
10.1002/anie.201607360
) / Angew. Chem. Int. Ed. by DJ Liptrot (2016) -
Lewis, R. A. et al. Reactivity and Mössbauer spectroscopic characterization of an Fe(iv) ketimide complex and reinvestigation of an Fe(iv) norbornyl complex. Inorg. Chem. 52, 8218–8227 (2013).
(
10.1021/ic401096p
) / Inorg. Chem. by RA Lewis (2013) -
Byrne, E. K. & Theopold, K. H. Redox chemistry of tetrakis(1-norbornyl)cobalt. Synthesis and characterization of a cobalt(v) alkyl and self-exchange rate of a Co(iii)/Co(iv) couple. J. Am. Chem. Soc. 193, 1282–1283 (1987).
(
10.1021/ja00238a066
) / J. Am. Chem. Soc. by EK Byrne (1987) -
Ruspic, C., Moss, J. R., Schürmann, M. & Harder, S. Remarkable stability of metallocenes with superbulky ligands: spontaneous reduction of SmIII to Smii. Angew. Chem. Int. Ed. 47, 2121–2126 (2008).
(
10.1002/anie.200705001
) / Angew. Chem. Int. Ed. by C Ruspic (2008)
Dates
Type | When |
---|---|
Created | 8 years, 7 months ago (Jan. 11, 2017, 6:27 a.m.) |
Deposited | 1 year, 2 months ago (June 21, 2024, 2:56 p.m.) |
Indexed | 5 days, 18 hours ago (Aug. 20, 2025, 8:54 a.m.) |
Issued | 8 years, 7 months ago (Jan. 11, 2017) |
Published | 8 years, 7 months ago (Jan. 11, 2017) |
Published Online | 8 years, 7 months ago (Jan. 11, 2017) |
@article{Liptrot_2017, title={London dispersion forces in sterically crowded inorganic and organometallic molecules}, volume={1}, ISSN={2397-3358}, url={http://dx.doi.org/10.1038/s41570-016-0004}, DOI={10.1038/s41570-016-0004}, number={1}, journal={Nature Reviews Chemistry}, publisher={Springer Science and Business Media LLC}, author={Liptrot, David J. and Power, Philip P.}, year={2017}, month=jan }