Mesostructured thin films as electrocatalysts with tunable composition and surface morphology
10.1038/nmat3457
Crossref journal-article
Springer Science and Business Media LLC
Nature Materials (297)
Bibliography

van der Vliet, D. F., Wang, C., Tripkovic, D., Strmcnik, D., Zhang, X. F., Debe, M. K., Atanasoski, R. T., Markovic, N. M., & Stamenkovic, V. R. (2012). Mesostructured thin films as electrocatalysts with tunable composition and surface morphology. Nature Materials, 11(12), 1051–1058.

Authors 9
  1. Dennis F. van der Vliet (first)
  2. Chao Wang (additional)
  3. Dusan Tripkovic (additional)
  4. Dusan Strmcnik (additional)
  5. Xiao Feng Zhang (additional)
  6. Mark K. Debe (additional)
  7. Radoslav T. Atanasoski (additional)
  8. Nenad M. Markovic (additional)
  9. Vojislav R. Stamenkovic (additional)
References 48 Referenced 336
  1. Borup, R. et al. Scientific aspects of polymer electrolyte fuel cell durability and degradation. Chem. Rev. 107, 3904–3951 (2007). (10.1021/cr050182l) / Chem. Rev. by R Borup (2007)
  2. Wagner, F. T., Lakshmanan, B. & Mathias, M. F. Electrochemistry and the future of the automobile. J. Phys. Chem. Lett. 1, 2204–2219 (2010). (10.1021/jz100553m) / J. Phys. Chem. Lett. by FT Wagner (2010)
  3. Adzic, R. R. et al. Platinum monolayer fuel cell electrocatalysts. Top. Catal. 46, 249–262 (2007). (10.1007/s11244-007-9003-x) / Top. Catal. by RR Adzic (2007)
  4. Bruce, P. G., Freunberger, S. A., Hardwick, L. J. & Tarascon, J. M. Li-O2 and Li-S batteries with high energy storage. Nature Mater. 11, 19–29 (2012). (10.1038/nmat3191) / Nature Mater. by PG Bruce (2012)
  5. Gasteiger, H. A., Kocha, S. S., Sompalli, B. & Wagner, F. T. Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs. Appl. Catal. B-Environ. 56, 9–35 (2005). (10.1016/j.apcatb.2004.06.021) / Appl. Catal. B-Environ. by HA Gasteiger (2005)
  6. Arico, A. S., Bruce, P., Scrosati, B., Tarascon, J. M. & Van Schalkwijk, W. Nanostructured materials for advanced energy conversion and storage devices. Nature Mater. 4, 366–377 (2005). (10.1038/nmat1368) / Nature Mater. by AS Arico (2005)
  7. Strasser, P. et al. Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts. Nature Chem. 2, 454–460 (2010). (10.1038/nchem.623) / Nature Chem. by P Strasser (2010)
  8. Greeley, J. et al. Alloys of platinum and early transition metals as oxygen reduction electrocatalysts. Nature Chem. 1, 552–556 (2009). (10.1038/nchem.367) / Nature Chem. by J Greeley (2009)
  9. Zhang, J., Sasaki, K., Sutter, E. & Adzic, R. R. Stabilization of platinum oxygen-reduction electrocatalysts using gold clusters. Science 315, 220–222 (2007). (10.1126/science.1134569) / Science by J Zhang (2007)
  10. Nilekar, A. et al. Bimetallic and ternary alloys for improved oxygen reduction catalysis. Top. Catal. 46, 276–284 (2007). (10.1007/s11244-007-9001-z) / Top. Catal. by A Nilekar (2007)
  11. Gorlin, Y. & Jaramillo, T. F. A bifunctional nonprecious metal catalyst for oxygen reduction and water oxidation. J. Am. Chem. Soc. 132, 13612–13614 (2010). (10.1021/ja104587v) / J. Am. Chem. Soc. by Y Gorlin (2010)
  12. Debe, M. K. Electrocatalyst approaches and challenges for automotive fuel cells. Nature 486, 43–51 (2012). (10.1038/nature11115) / Nature by MK Debe (2012)
  13. Snyder, J., Fujita, T., Chen, M. W. & Erlebacher, J. Oxygen reduction in nanoporous metal-ionic liquid composite electrocatalysts. Nature Mater. 9, 904–907 (2010). (10.1038/nmat2878) / Nature Mater. by J Snyder (2010)
  14. Wang, C. et al. Design and synthesis of bimetallic electrocatalyst with multilayered Pt-skin surfaces. J. Am. Chem. Soc. 133, 14396–14403 (2011). (10.1021/ja2047655) / J. Am. Chem. Soc. by C Wang (2011)
  15. Wang, C. et al. Multimetallic Au/FePt3 nanoparticles as highly durable electrocatalyst. Nano Lett. 11, 919–926 (2010). (10.1021/nl102369k) / Nano Lett. by C Wang (2010)
  16. Ferreira, P. J. et al. Instability of Pt/C electrocatalysts in proton exchange membrane fuel cells—A mechanistic investigation. J. Electrochem. Soc. 152, A2256–A2271 (2005). (10.1149/1.2050347) / J. Electrochem. Soc. by PJ Ferreira (2005)
  17. Stamenkovic, V. R. et al. Improved oxygen reduction activity on Pt3Ni(111) via increased surface site availability. Science 315, 493–497 (2007). (10.1126/science.1135941) / Science by VR Stamenkovic (2007)
  18. Stamenkovic, V. R. et al. Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces. Nature Mater. 6, 241–247 (2007). (10.1038/nmat1840) / Nature Mater. by VR Stamenkovic (2007)
  19. Stamenkovic, V., Schmidt, T. J., Ross, P. N. & Markovic, N. M. Surface composition effects in electrocatalysis: Kinetics of oxygen reduction on well-defined Pt3Ni and Pt3Co alloy surfaces. J. Phys. Chem. B 106, 11970–11979 (2002). (10.1021/jp021182h) / J. Phys. Chem. B by V Stamenkovic (2002)
  20. Stamenkovic, V. R., Mun, B. S., Mayrhofer, K. J. J., Ross, P. N. & Markovic, N. M. Effect of surface composition on electronic structure, stability, and electrocatalytic properties of Pt-transition metal alloys: Pt-skin versus Pt-skeleton surfaces. J. Am. Chem. Soc. 128, 8813–8819 (2006). (10.1021/ja0600476) / J. Am. Chem. Soc. by VR Stamenkovic (2006)
  21. Koh, S. & Strasser, P. Electrocatalysis on bimetallic surfaces: Modifying catalytic reactivity for oxygen reduction by voltammetric surface dealloying. J. Am. Chem. Soc. 129, 12624–12625 (2007). (10.1021/ja0742784) / J. Am. Chem. Soc. by S Koh (2007)
  22. Zhang, J. L., Vukmirovic, M. B., Xu, Y., Mavrikakis, M. & Adzic, R. R. Controlling the catalytic activity of platinum-monolayer electrocatalysts for oxygen reduction with different substrates. Angew. Chem. Int. Ed. 44, 2132–2135 (2005). (10.1002/anie.200462335) / Angew. Chem. Int. Ed. by JL Zhang (2005)
  23. Mukerjee, S. & Srinivasan, S. Enhanced electrocatalysis of oxygen reduction on platinum alloys in proton-exchange membrane fuel-cells. J. Electroanal. Chem. 357, 201–224 (1993). (10.1016/0022-0728(93)80380-Z) / J. Electroanal. Chem. by S Mukerjee (1993)
  24. Toda, T., Igarashi, H., Uchida, H. & Watanabe, M. Enhancement of the electroreduction of oxygen on Pt alloys with Fe, Ni, and Co. J. Electrochem. Soc. 146, 3750–3756 (1999). (10.1149/1.1392544) / J. Electrochem. Soc. by T Toda (1999)
  25. Mavrikakis, M. Computational methods: A search engine for catalysts. Nature Mater. 5, 847–848 (2006). (10.1038/nmat1767) / Nature Mater. by M Mavrikakis (2006)
  26. Mani, P., Srivastava, R. & Strasser, P. Dealloyed Pt–Cu core–shell nanoparticle electrocatalysts for use in PEM fuel cell cathodes. J. Phys. Chem. C 112, 2770–2778 (2008). (10.1021/jp0776412) / J. Phys. Chem. C by P Mani (2008)
  27. Wang, C. et al. Monodisperse Pt3Co nanoparticles as a catalyst for the oxygen reduction reaction: Size-dependent activity. J. Phys. Chem. C 113, 19365–19368 (2009). (10.1021/jp908203p) / J. Phys. Chem. C by C Wang (2009)
  28. Wang, C. et al. Monodisperse Pt3Co nanoparticles as electrocatalyst: The effects of particle size and pretreatment on electrocatalytic reduction of oxygen. Phys. Chem. Chem. Phys. 12, 6933–6939 (2010). (10.1039/c000822b) / Phys. Chem. Chem. Phys. by C Wang (2010)
  29. Van der Vliet, D. et al. Platinum-alloy nanostructured thin film catalysts for the oxygen reduction reaction. Electrochim. Acta 56, 8695–8699 (2011). (10.1016/j.electacta.2011.07.063) / Electrochim. Acta by D Van der Vliet (2011)
  30. Zeis, R., Mathur, A., Fritz, G., Lee, J. & Erlebacher, J. Platinum-plated nanoporous gold: An efficient, low Pt loading electrocatalyst for PEM fuel cells. J. Power Sources 165, 65–72 (2007). (10.1016/j.jpowsour.2006.12.007) / J. Power Sources by R Zeis (2007)
  31. Habas, S. E., Lee, H., Radmilovic, V., Somorjai, G. A. & Yang, P. Shaping binary metal nanocrystals through epitaxial seeded growth. Nature Mater. 6, 692–697 (2007). (10.1038/nmat1957) / Nature Mater. by SE Habas (2007)
  32. Tao, F. et al. Reaction-driven restructuring of Rh–Pd and Pt–Pd core–shell nanoparticles. Science 322, 932–934 (2008). (10.1126/science.1164170) / Science by F Tao (2008)
  33. Inaba, M. et al. Controlled growth and shape formation of platinum nanoparticles and their electrochemical properties. Electrochim. Acta 52, 1632–1638 (2006). (10.1016/j.electacta.2006.03.094) / Electrochim. Acta by M Inaba (2006)
  34. Paulus, U. A. et al. Oxygen reduction on carbon-supported Pt–Ni and Pt–Co alloy catalysts. J. Phys. Chem. B 106, 4181–4191 (2002). (10.1021/jp013442l) / J. Phys. Chem. B by UA Paulus (2002)
  35. Antonietti, M. & Ozin, G. A. Promises and problems of mesoscale materials chemistry or why meso? Chem. Eur. J. 10, 28–41 (2004). (10.1002/chem.200305009) / Chem. Eur. J. by M Antonietti (2004)
  36. Mukerjee, S., Srinivasan, S., Soriaga, M. P. & Mcbreen, J. Role of structural and electronic-properties of Pt and Pt alloys on electrocatalysis of oxygen reduction—an in-situ XANES and EXAFS investigation. J. Electrochem. Soc. 142, 1409–1422 (1995). (10.1149/1.2048590) / J. Electrochem. Soc. by S Mukerjee (1995)
  37. Debe, M. K. & Drube, A. R. Structural characteristics of a uniquely nanostructured organic thin-film. J. Vacuum Sci. Technol. B 13, 1236–1241 (1995). (10.1116/1.588243) / J. Vacuum Sci. Technol. B by MK Debe (1995)
  38. Debe, M. K. & Poirier, R. J. Postdeposition growth of a uniquely nanostructured organic film by vacuum annealing. J. Vacuum Sci. Tech. A 12, 2017–2022 (1994). (10.1116/1.578999) / J. Vacuum Sci. Tech. A by MK Debe (1994)
  39. Debe, M. K., Schmoeckel, A. K., Vernstrom, G. D. & Atanasoski, R. High voltage stability of nanostructured thin film catalysts for PEM fuel cells. J. Power Sources 161, 1002–1011 (2006). (10.1016/j.jpowsour.2006.05.033) / J. Power Sources by MK Debe (2006)
  40. Debe, M. K. in Handbook of Fuel Cells– Fundamentals, Technology and Applications (eds Vielstich, W., Lamm, A. & Gasteiger, H. A.) Ch. 45 (Wiley, 2003). / Handbook of Fuel Cells– Fundamentals, Technology and Applications by MK Debe (2003)
  41. Debe, M. K. et al. Extraordinary oxygen reduction activity of Pt3Ni7 . J. Electrochem. Soc. 158, B910–B918 (2011). (10.1149/1.3595748) / J. Electrochem. Soc. by MK Debe (2011)
  42. Somorjai, G. A. Surface science and catalysis. Science 227, 902–908 (1985). (10.1126/science.227.4689.902) / Science by GA Somorjai (1985)
  43. Tao, A. R., Habas, S. & Yang, P. D. Shape control of colloidal metal nanocrystals. Small 4, 310–325 (2008). (10.1002/smll.200701295) / Small by AR Tao (2008)
  44. Lai, S. C. S. & Koper, M. T. M. The influence of surface structure on selectivity in the ethanol electro-oxidation reaction on platinum. J. Phys. Chem. Lett. 1, 1122–1125 (2010). (10.1021/jz100272f) / J. Phys. Chem. Lett. by SCS Lai (2010)
  45. Wadayama, T. et al. Oxygen reduction reaction activities of Ni/Pt(111) model catalysts fabricated by molecular beam epitaxy. Electrochem. Commun. 12, 1112–1115 (2010). (10.1016/j.elecom.2010.05.042) / Electrochem. Commun. by T Wadayama (2010)
  46. Gancs, L., Kobayashi, T., Debe, M. K., Atanasoski, R. & Wieckowski, A. Crystallographic characteristics of nanostructured thin-film fuel cell electrocatalysts: A HRTEM study. Chem. Mater. 20, 2444–2454 (2008). (10.1021/cm702992b) / Chem. Mater. by L Gancs (2008)
  47. Subbaraman, R., Strmcnik, D., Paulikas, A. P., Stamenkovic, V. R. & Markovic, N. M. Oxygen reduction reaction at three-phase interfaces. ChemPhysChem 11, 2825–2833 (2010). (10.1002/cphc.201000190) / ChemPhysChem by R Subbaraman (2010)
  48. Debe, M. K. et al. Nanostructured thin film catalysts for PEM fuel cells by vacuum web coating. (Society of Vacuum Coaters—50th Annual Technical Conference Proceedings, 2007).
Dates
Type When
Created 12 years, 9 months ago (Nov. 11, 2012, 2:33 p.m.)
Deposited 3 years, 1 month ago (July 6, 2022, 2:15 p.m.)
Indexed 1 day, 4 hours ago (Aug. 26, 2025, 3 a.m.)
Issued 12 years, 9 months ago (Nov. 11, 2012)
Published 12 years, 9 months ago (Nov. 11, 2012)
Published Online 12 years, 9 months ago (Nov. 11, 2012)
Published Print 12 years, 8 months ago (Dec. 1, 2012)
Funders 0

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@article{van_der_Vliet_2012, title={Mesostructured thin films as electrocatalysts with tunable composition and surface morphology}, volume={11}, ISSN={1476-4660}, url={http://dx.doi.org/10.1038/nmat3457}, DOI={10.1038/nmat3457}, number={12}, journal={Nature Materials}, publisher={Springer Science and Business Media LLC}, author={van der Vliet, Dennis F. and Wang, Chao and Tripkovic, Dusan and Strmcnik, Dusan and Zhang, Xiao Feng and Debe, Mark K. and Atanasoski, Radoslav T. and Markovic, Nenad M. and Stamenkovic, Vojislav R.}, year={2012}, month=nov, pages={1051–1058} }