DOI: 10.1038/nmat1582. Entropy-driven segregation of nanoparticles to cracks in multilayered composite polymer structures

Entropy-driven segregation of nanoparticles to cracks in multilayered composite polymer structures

10.1038/nmat1582

Crossref journal-article

Springer Science and Business Media LLC

Nature Materials (297)

Bibliography

Gupta, S., Zhang, Q., Emrick, T., Balazs, A. C., & Russell, T. P. (2006). Entropy-driven segregation of nanoparticles to cracks in multilayered composite polymer structures. Nature Materials, 5(3), 229â233.

Authors 5

Suresh Gupta (first)
Qingling Zhang (additional)
Todd Emrick (additional)
Anna C. Balazs (additional)
Thomas P. Russell (additional)

References 18 Referenced 330

White, S. R. et al. Autonomic healing of polymer composites. Nature 409, 794–797 (2001). (10.1038/35057232) / Nature by SR White (2001)
Trau, M., Saville, D. A. & Aksay, I. A. Assembly of colloidal crystals at electrode interfaces. Langmuir 13, 6375–6381 (1997). (10.1021/la970568u) / Langmuir by M Trau (1997)
Chen, X. X. et al. A thermally re-mendable cross-linked polymeric material. Science 295, 1698–1702 (2002). (10.1126/science.1065879) / Science by XX Chen (2002)
Chiu, J. J., Kim, B. J., Kramer, E. J. & Pine, D. J. Control of nanoparticle location in block copolymers. J. Am. Chem. Soc. 127, 5036–5037 (2005). (10.1021/ja050376i) / J. Am. Chem. Soc. by JJ Chiu (2005)
Bockstaller, M. R. & Thomas, E. L. Proximity effects in self-organized binary particle-block copolymer blends. Phys. Rev. Lett. 93, 166106 (2004). (10.1103/PhysRevLett.93.166106) / Phys. Rev. Lett. by MR Bockstaller (2004)
Buxton, G. A., Lee, J. Y. & Balazs, A. C. Computer simulation of morphologies and optical properties of filled diblock copolymers. Macromolecules 36, 9631–9637 (2003). (10.1021/ma034322+) / Macromolecules by GA Buxton (2003)
Thompson, R. B., Ginzburg, V. V., Matsen, M. W. & Balazs, A. C. Predicting the mesophases of copolymer-nanoparticle composites. Science 292, 2469–2472 (2001). (10.1126/science.1060585) / Science by RB Thompson (2001)
Lin, Y. et al. Self-directed self-assembly of nanoparticle/copolymer mixtures. Nature 434, 55–59 (2005). (10.1038/nature03310) / Nature by Y Lin (2005)
Lee, J. Y., Shou, Z. & Balazs, A. C. Modeling the self-assembly of copolymer/nanoparticle mixtures confined between solid surfaces. Phys. Rev. Lett. 91, 136103–136107 (2003). (10.1103/PhysRevLett.91.136103) / Phys. Rev. Lett. by JY Lee (2003)
Lee, J. Y., Buxton, G. A. & Balazs, A. C. Using nanoparticles to create self-healing composites. J. Chem. Phys. 121, 5531–5540 (2004). (10.1063/1.1784432) / J. Chem. Phys. by JY Lee (2004)
Tyagi, S., Lee, J. Y., Buxton, G. A. & Balazs, A. C. Using nanocomposite coatings to heal surface defects. Macromolecules 37, 9160–9168 (2004). (10.1021/ma048773l) / Macromolecules by S Tyagi (2004)
McGuigan, A. P., Briggs, G. A. D., Burlakov, V., Yanaka, M. & Tsukahara, Y. An elastic-plastic shear lag model for fracture of layered coatings. Thin Solid Films 424, 219–223 (2003). (10.1016/S0040-6090(02)01124-0) / Thin Solid Films by AP McGuigan (2003)
Suo, Z., Prevost, J. H. & Liang, J. Kinetics of crack initiation and growth in organic-containing integrated structures. J. Mech. Phys. Solids 51, 2169–2190 (2003). (10.1016/j.jmps.2003.09.022) / J. Mech. Phys. Solids by Z Suo (2003)
Ito, H., Russell, T. P. & Wignall, G. D. Interactions in mixtures of poly(ethylene oxide) and poly(methyl methacrylate). Macromolecules 20, 2213–2220 (1987). (10.1021/ma00175a028) / Macromolecules by H Ito (1987)
Kim, J. U. & O’Shaughnessy, B. Morphology selection of nanoparticle dispersions by polymer media. Phys. Rev. Lett. 89, 238301 (2002). (10.1103/PhysRevLett.89.238301) / Phys. Rev. Lett. by JU Kim (2002)
Krausch, G. Dewetting at the interface between two immiscible polymers. J. Phys. Condens. Matter 9, 7741–7752 (1997). (10.1088/0953-8984/9/37/007) / J. Phys. Condens. Matter by G Krausch (1997)
Lin, Y. et al. Nanoparticle assembly at fluid interfaces: structure and dynamics. Langmuir 21, 191–194 (2005). (10.1021/la048000q) / Langmuir by Y Lin (2005)
Chen, Y. F., Ji, T. H. & Rosenzweig, Z. Synthesis of glyconanospheres containing luminescent CdSe-ZnS quantum dots. Nano Lett. 3, 581–584 (2003). (10.1021/nl034086g) / Nano Lett. by YF Chen (2003)

Dates

Type	When
Created	19 years, 6 months ago (Feb. 12, 2006, 2:27 p.m.)
Deposited	3 years, 1 month ago (July 6, 2022, 2:24 p.m.)
Indexed	5 hours, 14 minutes ago (Sept. 3, 2025, 6:26 a.m.)
Issued	19 years, 6 months ago (Feb. 12, 2006)
Published	19 years, 6 months ago (Feb. 12, 2006)
Published Online	19 years, 6 months ago (Feb. 12, 2006)
Published Print	19 years, 6 months ago (March 1, 2006)

Funders 0

None

BibTeX

@article{Gupta_2006, title={Entropy-driven segregation of nanoparticles to cracks in multilayered composite polymer structures}, volume={5}, ISSN={1476-4660}, url={http://dx.doi.org/10.1038/nmat1582}, DOI={10.1038/nmat1582}, number={3}, journal={Nature Materials}, publisher={Springer Science and Business Media LLC}, author={Gupta, Suresh and Zhang, Qingling and Emrick, Todd and Balazs, Anna C. and Russell, Thomas P.}, year={2006}, month=feb, pages={229–233} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        9,
        3
      ]
    ],
    "date-time": "2025-09-03T10:26:38Z",
    "timestamp": 1756895198937
  },
  "reference-count": 18,
  "publisher": "Springer Science and Business Media LLC",
  "issue": "3",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2006,
            2,
            12
          ]
        ],
        "date-time": "2006-02-12T00:00:00Z",
        "timestamp": 1139702400000
      },
      "content-version": "tdm",
      "delay-in-days": 0,
      "URL": "https://www.springer.com/tdm"
    },
    {
      "start": {
        "date-parts": [
          [
            2006,
            2,
            12
          ]
        ],
        "date-time": "2006-02-12T00:00:00Z",
        "timestamp": 1139702400000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "https://www.springer.com/tdm"
    }
  ],
  "content-domain": {
    "domain": [
      "link.springer.com"
    ],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2006,
        3,
        1
      ]
    ]
  },
  "DOI": "10.1038/nmat1582",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2006,
        2,
        12
      ]
    ],
    "date-time": "2006-02-12T19:27:23Z",
    "timestamp": 1139772443000
  },
  "page": "229-233",
  "update-policy": "http://dx.doi.org/10.1007/springer_crossmark_policy",
  "source": "Crossref",
  "is-referenced-by-count": 330,
  "title": "Entropy-driven segregation of nanoparticles to cracks in multilayered composite polymer structures",
  "prefix": "10.1038",
  "volume": "5",
  "author": [
    {
      "given": "Suresh",
      "family": "Gupta",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Qingling",
      "family": "Zhang",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Todd",
      "family": "Emrick",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Anna C.",
      "family": "Balazs",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Thomas P.",
      "family": "Russell",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "297",
  "published-online": {
    "date-parts": [
      [
        2006,
        2,
        12
      ]
    ]
  },
  "reference": [
    {
      "key": "BFnmat1582_CR1",
      "doi-asserted-by": "publisher",
      "first-page": "794",
      "DOI": "10.1038/35057232",
      "volume": "409,",
      "author": "SR White",
      "year": "2001",
      "unstructured": "White, S. R. et al. Autonomic healing of polymer composites. Nature 409, 794\u2013797 (2001).",
      "journal-title": "Nature"
    },
    {
      "key": "BFnmat1582_CR2",
      "doi-asserted-by": "publisher",
      "first-page": "6375",
      "DOI": "10.1021/la970568u",
      "volume": "13,",
      "author": "M Trau",
      "year": "1997",
      "unstructured": "Trau, M., Saville, D. A. & Aksay, I. A. Assembly of colloidal crystals at electrode interfaces. Langmuir 13, 6375\u20136381 (1997).",
      "journal-title": "Langmuir"
    },
    {
      "key": "BFnmat1582_CR3",
      "doi-asserted-by": "publisher",
      "first-page": "1698",
      "DOI": "10.1126/science.1065879",
      "volume": "295,",
      "author": "XX Chen",
      "year": "2002",
      "unstructured": "Chen, X. X. et al. A thermally re-mendable cross-linked polymeric material. Science 295, 1698\u20131702 (2002).",
      "journal-title": "Science"
    },
    {
      "key": "BFnmat1582_CR4",
      "doi-asserted-by": "publisher",
      "first-page": "5036",
      "DOI": "10.1021/ja050376i",
      "volume": "127,",
      "author": "JJ Chiu",
      "year": "2005",
      "unstructured": "Chiu, J. J., Kim, B. J., Kramer, E. J. & Pine, D. J. Control of nanoparticle location in block copolymers. J. Am. Chem. Soc. 127, 5036\u20135037 (2005).",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "BFnmat1582_CR5",
      "doi-asserted-by": "publisher",
      "first-page": "166106",
      "DOI": "10.1103/PhysRevLett.93.166106",
      "volume": "93,",
      "author": "MR Bockstaller",
      "year": "2004",
      "unstructured": "Bockstaller, M. R. & Thomas, E. L. Proximity effects in self-organized binary particle-block copolymer blends. Phys. Rev. Lett. 93, 166106 (2004).",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "BFnmat1582_CR6",
      "doi-asserted-by": "publisher",
      "first-page": "9631",
      "DOI": "10.1021/ma034322+",
      "volume": "36,",
      "author": "GA Buxton",
      "year": "2003",
      "unstructured": "Buxton, G. A., Lee, J. Y. & Balazs, A. C. Computer simulation of morphologies and optical properties of filled diblock copolymers. Macromolecules 36, 9631\u20139637 (2003).",
      "journal-title": "Macromolecules"
    },
    {
      "key": "BFnmat1582_CR7",
      "doi-asserted-by": "publisher",
      "first-page": "2469",
      "DOI": "10.1126/science.1060585",
      "volume": "292,",
      "author": "RB Thompson",
      "year": "2001",
      "unstructured": "Thompson, R. B., Ginzburg, V. V., Matsen, M. W. & Balazs, A. C. Predicting the mesophases of copolymer-nanoparticle composites. Science 292, 2469\u20132472 (2001).",
      "journal-title": "Science"
    },
    {
      "key": "BFnmat1582_CR8",
      "doi-asserted-by": "publisher",
      "first-page": "55",
      "DOI": "10.1038/nature03310",
      "volume": "434,",
      "author": "Y Lin",
      "year": "2005",
      "unstructured": "Lin, Y. et al. Self-directed self-assembly of nanoparticle/copolymer mixtures. Nature 434, 55\u201359 (2005).",
      "journal-title": "Nature"
    },
    {
      "key": "BFnmat1582_CR9",
      "doi-asserted-by": "publisher",
      "first-page": "136103",
      "DOI": "10.1103/PhysRevLett.91.136103",
      "volume": "91,",
      "author": "JY Lee",
      "year": "2003",
      "unstructured": "Lee, J. Y., Shou, Z. & Balazs, A. C. Modeling the self-assembly of copolymer/nanoparticle mixtures confined between solid surfaces. Phys. Rev. Lett. 91, 136103\u2013136107 (2003).",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "BFnmat1582_CR10",
      "doi-asserted-by": "publisher",
      "first-page": "5531",
      "DOI": "10.1063/1.1784432",
      "volume": "121,",
      "author": "JY Lee",
      "year": "2004",
      "unstructured": "Lee, J. Y., Buxton, G. A. & Balazs, A. C. Using nanoparticles to create self-healing composites. J.\u00a0Chem. Phys. 121, 5531\u20135540 (2004).",
      "journal-title": "J.\u00a0Chem. Phys."
    },
    {
      "key": "BFnmat1582_CR11",
      "doi-asserted-by": "publisher",
      "first-page": "9160",
      "DOI": "10.1021/ma048773l",
      "volume": "37,",
      "author": "S Tyagi",
      "year": "2004",
      "unstructured": "Tyagi, S., Lee, J. Y., Buxton, G. A. & Balazs, A. C. Using nanocomposite coatings to heal surface defects. Macromolecules 37, 9160\u20139168 (2004).",
      "journal-title": "Macromolecules"
    },
    {
      "key": "BFnmat1582_CR12",
      "doi-asserted-by": "publisher",
      "first-page": "219",
      "DOI": "10.1016/S0040-6090(02)01124-0",
      "volume": "424,",
      "author": "AP McGuigan",
      "year": "2003",
      "unstructured": "McGuigan, A. P., Briggs, G. A. D., Burlakov, V., Yanaka, M. & Tsukahara, Y. An elastic-plastic shear lag model for fracture of layered coatings. Thin Solid Films 424, 219\u2013223 (2003).",
      "journal-title": "Thin Solid Films"
    },
    {
      "key": "BFnmat1582_CR13",
      "doi-asserted-by": "publisher",
      "first-page": "2169",
      "DOI": "10.1016/j.jmps.2003.09.022",
      "volume": "51,",
      "author": "Z Suo",
      "year": "2003",
      "unstructured": "Suo, Z., Prevost, J. H. & Liang, J. Kinetics of crack initiation and growth in organic-containing integrated structures. J. Mech. Phys. Solids 51, 2169\u20132190 (2003).",
      "journal-title": "J. Mech. Phys. Solids"
    },
    {
      "key": "BFnmat1582_CR14",
      "doi-asserted-by": "publisher",
      "first-page": "2213",
      "DOI": "10.1021/ma00175a028",
      "volume": "20,",
      "author": "H Ito",
      "year": "1987",
      "unstructured": "Ito, H., Russell, T. P. & Wignall, G. D. Interactions in mixtures of poly(ethylene oxide) and poly(methyl methacrylate). Macromolecules 20, 2213\u20132220 (1987).",
      "journal-title": "Macromolecules"
    },
    {
      "key": "BFnmat1582_CR15",
      "doi-asserted-by": "publisher",
      "first-page": "238301",
      "DOI": "10.1103/PhysRevLett.89.238301",
      "volume": "89,",
      "author": "JU Kim",
      "year": "2002",
      "unstructured": "Kim, J. U. & O\u2019Shaughnessy, B. Morphology selection of nanoparticle dispersions by polymer media. Phys. Rev. Lett. 89, 238301 (2002).",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "BFnmat1582_CR16",
      "doi-asserted-by": "publisher",
      "first-page": "7741",
      "DOI": "10.1088/0953-8984/9/37/007",
      "volume": "9,",
      "author": "G Krausch",
      "year": "1997",
      "unstructured": "Krausch, G. Dewetting at the interface between two immiscible polymers. J. Phys. Condens. Matter 9, 7741\u20137752 (1997).",
      "journal-title": "J. Phys. Condens. Matter"
    },
    {
      "key": "BFnmat1582_CR17",
      "doi-asserted-by": "publisher",
      "first-page": "191",
      "DOI": "10.1021/la048000q",
      "volume": "21,",
      "author": "Y Lin",
      "year": "2005",
      "unstructured": "Lin, Y. et al. Nanoparticle assembly at fluid interfaces: structure and dynamics. Langmuir 21, 191\u2013194 (2005).",
      "journal-title": "Langmuir"
    },
    {
      "key": "BFnmat1582_CR18",
      "doi-asserted-by": "publisher",
      "first-page": "581",
      "DOI": "10.1021/nl034086g",
      "volume": "3,",
      "author": "YF Chen",
      "year": "2003",
      "unstructured": "Chen, Y. F., Ji, T. H. & Rosenzweig, Z. Synthesis of glyconanospheres containing luminescent CdSe-ZnS quantum dots. Nano Lett. 3, 581\u2013584 (2003).",
      "journal-title": "Nano Lett."
    }
  ],
  "container-title": "Nature Materials",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://www.nature.com/articles/nmat1582.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://www.nature.com/articles/nmat1582",
      "content-type": "text/html",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://www.nature.com/articles/nmat1582.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2022,
        7,
        6
      ]
    ],
    "date-time": "2022-07-06T18:24:51Z",
    "timestamp": 1657131891000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://www.nature.com/articles/nmat1582"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2006,
        2,
        12
      ]
    ]
  },
  "references-count": 18,
  "journal-issue": {
    "issue": "3",
    "published-print": {
      "date-parts": [
        [
          2006,
          3,
          1
        ]
      ]
    }
  },
  "alternative-id": [
    "BFnmat1582"
  ],
  "URL": "http://dx.doi.org/10.1038/nmat1582",
  "relation": {},
  "ISSN": [
    "1476-1122",
    "1476-4660"
  ],
  "subject": [],
  "container-title-short": "Nature Mater",
  "published": {
    "date-parts": [
      [
        2006,
        2,
        12
      ]
    ]
  },
  "assertion": [
    {
      "value": "19 July 2005",
      "order": 1,
      "name": "received",
      "label": "Received",
      "group": {
        "name": "ArticleHistory",
        "label": "Article History"
      }
    },
    {
      "value": "19 December 2005",
      "order": 2,
      "name": "accepted",
      "label": "Accepted",
      "group": {
        "name": "ArticleHistory",
        "label": "Article History"
      }
    },
    {
      "value": "12 February 2006",
      "order": 3,
      "name": "first_online",
      "label": "First Online",
      "group": {
        "name": "ArticleHistory",
        "label": "Article History"
      }
    },
    {
      "value": "The authors declare no competing financial interests.",
      "order": 1,
      "name": "Ethics",
      "group": {
        "name": "EthicsHeading",
        "label": "Competing interests"
      }
    }
  ]
}