DOI: 10.1038/nmat1476. An interfacial instability in a transient wetting layer leads to lateral phase separation in thin spin-cast polymer-blend films

An interfacial instability in a transient wetting layer leads to lateral phase separation in thin spin-cast polymer-blend films

10.1038/nmat1476

Crossref journal-article

Springer Science and Business Media LLC

Nature Materials (297)

Bibliography

Heriot, S. Y., & Jones, R. A. L. (2005). An interfacial instability in a transient wetting layer leads to lateral phase separation in thin spin-cast polymer-blend films. Nature Materials, 4(10), 782â786.

Authors 2

Sasha Y. Heriot (first)
Richard A. L. Jones (additional)

References 32 Referenced 358

Geoghegan, M. et al. Lamellar structure in a thin polymer blend film. Polymer 35, 2019–2027 (1994). (10.1016/0032-3861(94)90223-2) / Polymer by M Geoghegan (1994)
Geoghegan, M. & Krausch, G. Wetting at polymer surfaces and interfaces. Prog. Polym. Sci. 28, 261–302 (2003). (10.1016/S0079-6700(02)00080-1) / Prog. Polym. Sci. by M Geoghegan (2003)
Prosycevas, I., Tamulevicius, S. & Guobiene, A. The surface properties of PS/PMMA blends nanostructured polymeric layers. Thin Solid Films 453, 304–311 (2004). (10.1016/j.tsf.2003.11.090) / Thin Solid Films by I Prosycevas (2004)
Dekeyser, C. M., Biltresse, S., Marchand-Brynaert, J., Rouxhet, P. G. & Dupont-Gillain, C. C. Submicrometer-scale heterogeneous surfaces by PS-PMMA demixing. Polymer 45, 2211–2219 (2004). (10.1016/j.polymer.2004.01.045) / Polymer by CM Dekeyser (2004)
Li, X., Han, Y. C. & An, L. J. Surface morphology control of immiscible polymer-blend thin films. Polymer 44, 8155–8165 (2003). (10.1016/j.polymer.2003.10.012) / Polymer by X Li (2003)
Raczkowska, J. et al. Surface patterns in solvent-cast polymer blend films analyzed with an integral-geometry approach. Macromolecules 36, 2419–2427 (2003). (10.1021/ma020870w) / Macromolecules by J Raczkowska (2003)
Ton-That, C., Shard, A. G. & Bradley, R. H. Surface feature size of spin cast PS/PMMA blends. Polymer 43, 4973–4977 (2002). (10.1016/S0032-3861(02)00333-6) / Polymer by C Ton-That (2002)
Muller-Buschbaum, P., Gutmann, J. S. & Stamm, M. Control of surface morphology by the interplay between phase separation and dewetting. J. Macromol. Sci.-Phys. B 38, 577–592 (1999). (10.1080/00222349908248122) / J. Macromol. Sci.-Phys. B by P Muller-Buschbaum (1999)
Ade, H. et al. Phase segregation in polymer thin films: Elucidations by X-ray and scanning force microscopy. Europhys. Lett. 45, 526–532 (1999). (10.1209/epl/i1999-00198-7) / Europhys. Lett. by H Ade (1999)
DalnokiVeress, K., Forrest, J. A., Stevens, J. R. & Dutcher, J. R. Physica A 239, 87–94 (1997). (10.1016/S0378-4371(96)00471-2) / Physica A by K DalnokiVeress (1997)
Halls, J. J. M. et al. Efficient photodiodes from interpenetrating polymer networks. Nature 376, 498–500 (1995). (10.1038/376498a0) / Nature by JJM Halls (1995)
Peumans, P., Uchida, S. & Forrest, S. R. Efficient bulk heterojunction photovoltaic cells using small-molecular-weight organic thin films. Nature 425, 158–162 (2003). (10.1038/nature01949) / Nature by P Peumans (2003)
Morteani, A. C. et al. Barrier-free electron-hole capture in polymer blend heterojunction light-emitting diodes. Adv. Mater. 15, 1708–1712 (2003). (10.1002/adma.200305618) / Adv. Mater. by AC Morteani (2003)
Snaith, H. J. & Friend, R. H. Morphological dependence of charge generation and transport in blended polyfluorene photovoltaic devices. Thin Solid Films 451, 567–571 (2004). (10.1016/j.tsf.2003.11.046) / Thin Solid Films by HJ Snaith (2004)
Moons, E. Conjugated polymer blends: linking film morphology to performance of light emitting diodes and photodiodes. J. Phys. C 14, 12235–12260 (2002). / J. Phys. C by E Moons (2002)
Granstrom, M. et al. Laminated fabrication of polymeric photovoltaic diodes. Nature 395, 257–260 (1998). (10.1038/26183) / Nature by M Granstrom (1998)
Kim, J. S., Ho, P. K. H., Murphy, C. E. & Friend, R. H. Phase separation in polyfluorene-based conjugated polymer blends: Lateral and vertical analysis of blend spin-cast thin films. Macromolecules 37, 2861–2871 (2004). (10.1021/ma035750i) / Macromolecules by JS Kim (2004)
Chappell, J. et al. Correlating structure with fluorescence emission in phase-separated conjugated-polymer blends. Nature Mater. 2, 616–621 (2003). (10.1038/nmat959) / Nature Mater. by J Chappell (2003)
Corcoran, N., Arias, A. C., Kim, J. S., MacKenzie, J. D. & Friend, R. H. Increased efficiency in vertically segregated thin-film conjugated polymer blends for light-emitting diodes. Appl. Phys. Lett. 82, 299–301 (2003). (10.1063/1.1537049) / Appl. Phys. Lett. by N Corcoran (2003)
Arias, A. C. et al. Vertically segregated polymer-blend photovoltaic thin-film structures through surface-mediated solution processing. Appl. Phys. Lett. 80, 1695–1697 (2002). (10.1063/1.1456550) / Appl. Phys. Lett. by AC Arias (2002)
Boltau, M., Walheim, S., Mlynek, J., Krausch, G. & Steiner, U. Surface-induced structure formation of polymer blends on patterned substrates. Nature 391, 877–879 (1998). (10.1038/36075) / Nature by M Boltau (1998)
Walheim, S., Boltau, M., Mlynek, J., Krausch, G. & Steiner, U. Structure formation via polymer demixing in spin-cast films. Macromolecules 30, 4995–5003 (1997). (10.1021/ma9619288) / Macromolecules by S Walheim (1997)
Jukes, P. C., Heriot, S. Y., Sharp, J. S. & Jones, R. A. L. Time-resolved light scattering studies of phase separation in thin film semiconducting polymer blends during spin-coating. Macromolecules 38, 2030–2032 (2005). (10.1021/ma0477145) / Macromolecules by PC Jukes (2005)
Cahn, J. W. Phase separation by spinodal decomposition in isotropic systems. J. Chem. Phys. 42, 93–99 (1965). (10.1063/1.1695731) / J. Chem. Phys. by JW Cahn (1965)
Sferrazza, M. et al. Interfacial instability driven by dispersive forces: The early stages of spinodal dewetting of a thin polymer film on a polymer substrate. Phys. Rev. Lett. 81, 5173–5176 (1998). (10.1103/PhysRevLett.81.5173) / Phys. Rev. Lett. by M Sferrazza (1998)
Reiter, G. Dewetting of thin polymer-films. Phys. Rev. Lett. 68, 75–78 (1992). (10.1103/PhysRevLett.68.75) / Phys. Rev. Lett. by G Reiter (1992)
Nevot, L. & Croce, P. Caractérisation des surfaces par réflexion rasant de rayons x: application á l’étude du polissage de quelques verres silicates. Rev. Phys. Appl. 15, 761–779 (1980). (10.1051/rphysap:01980001503076100) / Rev. Phys. Appl. by L Nevot (1980)
Brochard-Wyart, F., Martin, P. & Redon, C. Liquid/liquid dewetting. Langmuir 9, 3682–3690 (1993). (10.1021/la00036a053) / Langmuir by F Brochard-Wyart (1993)
de Gennes, P. G. Instabilities during the evaporation of a film: Non-glassy polymer plus volatile solvent. Eur. Phys. J. E 6, 421–424 (2001). (10.1007/s10189-001-8055-3) / Eur. Phys. J. E by PG de Gennes (2001)
Broseta, D., Leibler, L., Kaddour, L. O. & Strazielle, C. A theoretical and experimental study of interfacial-tension of immiscible polymer blends in solution. J. Chem. Phys. 87, 7248–7256 (1987). (10.1063/1.453369) / J. Chem. Phys. by D Broseta (1987)
Bernasik, A. et al. Lamellar structures formed in spin-cast blends of insulating and conducting polymers. Synth. Met. 144, 253–257 (2004). (10.1016/j.synthmet.2004.03.009) / Synth. Met. by A Bernasik (2004)
Routh, A. F. & Russel, W. B. A process model for latex film formation: Limiting regimes for individual driving forces. Langmuir 15, 7762–7773 (1999). (10.1021/la9903090) / Langmuir by AF Routh (1999)

Dates

Type	When
Created	19 years, 11 months ago (Sept. 4, 2005, 1:42 p.m.)
Deposited	3 years, 1 month ago (July 6, 2022, 2:54 p.m.)
Indexed	2 weeks, 1 day ago (Aug. 6, 2025, 8:36 a.m.)
Issued	19 years, 11 months ago (Sept. 4, 2005)
Published	19 years, 11 months ago (Sept. 4, 2005)
Published Online	19 years, 11 months ago (Sept. 4, 2005)
Published Print	19 years, 10 months ago (Oct. 1, 2005)

Funders 0

None

BibTeX

@article{Heriot_2005, title={An interfacial instability in a transient wetting layer leads to lateral phase separation in thin spin-cast polymer-blend films}, volume={4}, ISSN={1476-4660}, url={http://dx.doi.org/10.1038/nmat1476}, DOI={10.1038/nmat1476}, number={10}, journal={Nature Materials}, publisher={Springer Science and Business Media LLC}, author={Heriot, Sasha Y. and Jones, Richard A. L.}, year={2005}, month=sep, pages={782–786} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        6
      ]
    ],
    "date-time": "2025-08-06T12:36:09Z",
    "timestamp": 1754483769809
  },
  "reference-count": 32,
  "publisher": "Springer Science and Business Media LLC",
  "issue": "10",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2005,
            9,
            4
          ]
        ],
        "date-time": "2005-09-04T00:00:00Z",
        "timestamp": 1125792000000
      },
      "content-version": "tdm",
      "delay-in-days": 0,
      "URL": "https://www.springer.com/tdm"
    },
    {
      "start": {
        "date-parts": [
          [
            2005,
            9,
            4
          ]
        ],
        "date-time": "2005-09-04T00:00:00Z",
        "timestamp": 1125792000000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "https://www.springer.com/tdm"
    }
  ],
  "content-domain": {
    "domain": [
      "link.springer.com"
    ],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2005,
        10,
        1
      ]
    ]
  },
  "DOI": "10.1038/nmat1476",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2005,
        9,
        4
      ]
    ],
    "date-time": "2005-09-04T17:42:00Z",
    "timestamp": 1125855720000
  },
  "page": "782-786",
  "update-policy": "http://dx.doi.org/10.1007/springer_crossmark_policy",
  "source": "Crossref",
  "is-referenced-by-count": 358,
  "title": "An interfacial instability in a transient wetting layer leads to lateral phase separation in thin spin-cast polymer-blend films",
  "prefix": "10.1038",
  "volume": "4",
  "author": [
    {
      "given": "Sasha Y.",
      "family": "Heriot",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Richard A. L.",
      "family": "Jones",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "297",
  "published-online": {
    "date-parts": [
      [
        2005,
        9,
        4
      ]
    ]
  },
  "reference": [
    {
      "key": "BFnmat1476_CR1",
      "doi-asserted-by": "publisher",
      "first-page": "2019",
      "DOI": "10.1016/0032-3861(94)90223-2",
      "volume": "35,",
      "author": "M Geoghegan",
      "year": "1994",
      "unstructured": "Geoghegan, M. et al. Lamellar structure in a thin polymer blend film. Polymer 35, 2019\u20132027 (1994).",
      "journal-title": "Polymer"
    },
    {
      "key": "BFnmat1476_CR2",
      "doi-asserted-by": "publisher",
      "first-page": "261",
      "DOI": "10.1016/S0079-6700(02)00080-1",
      "volume": "28,",
      "author": "M Geoghegan",
      "year": "2003",
      "unstructured": "Geoghegan, M. & Krausch, G. Wetting at polymer surfaces and interfaces. Prog. Polym. Sci. 28, 261\u2013302 (2003).",
      "journal-title": "Prog. Polym. Sci."
    },
    {
      "key": "BFnmat1476_CR3",
      "doi-asserted-by": "publisher",
      "first-page": "304",
      "DOI": "10.1016/j.tsf.2003.11.090",
      "volume": "453,",
      "author": "I Prosycevas",
      "year": "2004",
      "unstructured": "Prosycevas, I., Tamulevicius, S. & Guobiene, A. The surface properties of PS/PMMA blends nanostructured polymeric layers. Thin Solid Films 453, 304\u2013311 (2004).",
      "journal-title": "Thin Solid Films"
    },
    {
      "key": "BFnmat1476_CR4",
      "doi-asserted-by": "publisher",
      "first-page": "2211",
      "DOI": "10.1016/j.polymer.2004.01.045",
      "volume": "45,",
      "author": "CM Dekeyser",
      "year": "2004",
      "unstructured": "Dekeyser, C. M., Biltresse, S., Marchand-Brynaert, J., Rouxhet, P. G. & Dupont-Gillain, C. C. Submicrometer-scale heterogeneous surfaces by PS-PMMA demixing. Polymer 45, 2211\u20132219 (2004).",
      "journal-title": "Polymer"
    },
    {
      "key": "BFnmat1476_CR5",
      "doi-asserted-by": "publisher",
      "first-page": "8155",
      "DOI": "10.1016/j.polymer.2003.10.012",
      "volume": "44,",
      "author": "X Li",
      "year": "2003",
      "unstructured": "Li, X., Han, Y. C. & An, L. J. Surface morphology control of immiscible polymer-blend thin films. Polymer 44, 8155\u20138165 (2003).",
      "journal-title": "Polymer"
    },
    {
      "key": "BFnmat1476_CR6",
      "doi-asserted-by": "publisher",
      "first-page": "2419",
      "DOI": "10.1021/ma020870w",
      "volume": "36,",
      "author": "J Raczkowska",
      "year": "2003",
      "unstructured": "Raczkowska, J. et al. Surface patterns in solvent-cast polymer blend films analyzed with an integral-geometry approach. Macromolecules 36, 2419\u20132427 (2003).",
      "journal-title": "Macromolecules"
    },
    {
      "key": "BFnmat1476_CR7",
      "doi-asserted-by": "publisher",
      "first-page": "4973",
      "DOI": "10.1016/S0032-3861(02)00333-6",
      "volume": "43,",
      "author": "C Ton-That",
      "year": "2002",
      "unstructured": "Ton-That, C., Shard, A. G. & Bradley, R. H. Surface feature size of spin cast PS/PMMA blends. Polymer 43, 4973\u20134977 (2002).",
      "journal-title": "Polymer"
    },
    {
      "key": "BFnmat1476_CR8",
      "doi-asserted-by": "publisher",
      "first-page": "577",
      "DOI": "10.1080/00222349908248122",
      "volume": "38,",
      "author": "P Muller-Buschbaum",
      "year": "1999",
      "unstructured": "Muller-Buschbaum, P., Gutmann, J. S. & Stamm, M. Control of surface morphology by the interplay between phase separation and dewetting. J. Macromol. Sci.-Phys. B 38, 577\u2013592 (1999).",
      "journal-title": "J. Macromol. Sci.-Phys. B"
    },
    {
      "key": "BFnmat1476_CR9",
      "doi-asserted-by": "publisher",
      "first-page": "526",
      "DOI": "10.1209/epl/i1999-00198-7",
      "volume": "45,",
      "author": "H Ade",
      "year": "1999",
      "unstructured": "Ade, H. et al. Phase segregation in polymer thin films: Elucidations by X-ray and scanning force microscopy. Europhys. Lett. 45, 526\u2013532 (1999).",
      "journal-title": "Europhys. Lett."
    },
    {
      "key": "BFnmat1476_CR10",
      "doi-asserted-by": "publisher",
      "first-page": "87",
      "DOI": "10.1016/S0378-4371(96)00471-2",
      "volume": "239,",
      "author": "K DalnokiVeress",
      "year": "1997",
      "unstructured": "DalnokiVeress, K., Forrest, J. A., Stevens, J. R. & Dutcher, J. R. Physica A 239, 87\u201394 (1997).",
      "journal-title": "Physica A"
    },
    {
      "key": "BFnmat1476_CR11",
      "doi-asserted-by": "publisher",
      "first-page": "498",
      "DOI": "10.1038/376498a0",
      "volume": "376,",
      "author": "JJM Halls",
      "year": "1995",
      "unstructured": "Halls, J. J. M. et al. Efficient photodiodes from interpenetrating polymer networks. Nature 376, 498\u2013500 (1995).",
      "journal-title": "Nature"
    },
    {
      "key": "BFnmat1476_CR12",
      "doi-asserted-by": "publisher",
      "first-page": "158",
      "DOI": "10.1038/nature01949",
      "volume": "425,",
      "author": "P Peumans",
      "year": "2003",
      "unstructured": "Peumans, P., Uchida, S. & Forrest, S. R. Efficient bulk heterojunction photovoltaic cells using small-molecular-weight organic thin films. Nature 425, 158\u2013162 (2003).",
      "journal-title": "Nature"
    },
    {
      "key": "BFnmat1476_CR13",
      "doi-asserted-by": "publisher",
      "first-page": "1708",
      "DOI": "10.1002/adma.200305618",
      "volume": "15,",
      "author": "AC Morteani",
      "year": "2003",
      "unstructured": "Morteani, A. C. et al. Barrier-free electron-hole capture in polymer blend heterojunction light-emitting diodes. Adv. Mater. 15, 1708\u20131712 (2003).",
      "journal-title": "Adv. Mater."
    },
    {
      "key": "BFnmat1476_CR14",
      "doi-asserted-by": "publisher",
      "first-page": "567",
      "DOI": "10.1016/j.tsf.2003.11.046",
      "volume": "451,",
      "author": "HJ Snaith",
      "year": "2004",
      "unstructured": "Snaith, H. J. & Friend, R. H. Morphological dependence of charge generation and transport in blended polyfluorene photovoltaic devices. Thin Solid Films 451, 567\u2013571 (2004).",
      "journal-title": "Thin Solid Films"
    },
    {
      "key": "BFnmat1476_CR15",
      "first-page": "12235",
      "volume": "14,",
      "author": "E Moons",
      "year": "2002",
      "unstructured": "Moons, E. Conjugated polymer blends: linking film morphology to performance of light emitting diodes and photodiodes. J. Phys. C 14, 12235\u201312260 (2002).",
      "journal-title": "J. Phys. C"
    },
    {
      "key": "BFnmat1476_CR16",
      "doi-asserted-by": "publisher",
      "first-page": "257",
      "DOI": "10.1038/26183",
      "volume": "395,",
      "author": "M Granstrom",
      "year": "1998",
      "unstructured": "Granstrom, M. et al. Laminated fabrication of polymeric photovoltaic diodes. Nature 395, 257\u2013260 (1998).",
      "journal-title": "Nature"
    },
    {
      "key": "BFnmat1476_CR17",
      "doi-asserted-by": "publisher",
      "first-page": "2861",
      "DOI": "10.1021/ma035750i",
      "volume": "37,",
      "author": "JS Kim",
      "year": "2004",
      "unstructured": "Kim, J. S., Ho, P. K. H., Murphy, C. E. & Friend, R. H. Phase separation in polyfluorene-based conjugated polymer blends: Lateral and vertical analysis of blend spin-cast thin films. Macromolecules 37, 2861\u20132871 (2004).",
      "journal-title": "Macromolecules"
    },
    {
      "key": "BFnmat1476_CR18",
      "doi-asserted-by": "publisher",
      "first-page": "616",
      "DOI": "10.1038/nmat959",
      "volume": "2,",
      "author": "J Chappell",
      "year": "2003",
      "unstructured": "Chappell, J. et al. Correlating structure with fluorescence emission in phase-separated conjugated-polymer blends. Nature Mater. 2, 616\u2013621 (2003).",
      "journal-title": "Nature Mater."
    },
    {
      "key": "BFnmat1476_CR19",
      "doi-asserted-by": "publisher",
      "first-page": "299",
      "DOI": "10.1063/1.1537049",
      "volume": "82,",
      "author": "N Corcoran",
      "year": "2003",
      "unstructured": "Corcoran, N., Arias, A. C., Kim, J. S., MacKenzie, J. D. & Friend, R. H. Increased efficiency in vertically segregated thin-film conjugated polymer blends for light-emitting diodes. Appl. Phys. Lett. 82, 299\u2013301 (2003).",
      "journal-title": "Appl. Phys. Lett."
    },
    {
      "key": "BFnmat1476_CR20",
      "doi-asserted-by": "publisher",
      "first-page": "1695",
      "DOI": "10.1063/1.1456550",
      "volume": "80,",
      "author": "AC Arias",
      "year": "2002",
      "unstructured": "Arias, A. C. et al. Vertically segregated polymer-blend photovoltaic thin-film structures through surface-mediated solution processing. Appl. Phys. Lett. 80, 1695\u20131697 (2002).",
      "journal-title": "Appl. Phys. Lett."
    },
    {
      "key": "BFnmat1476_CR21",
      "doi-asserted-by": "publisher",
      "first-page": "877",
      "DOI": "10.1038/36075",
      "volume": "391,",
      "author": "M Boltau",
      "year": "1998",
      "unstructured": "Boltau, M., Walheim, S., Mlynek, J., Krausch, G. & Steiner, U. Surface-induced structure formation of polymer blends on patterned substrates. Nature 391, 877\u2013879 (1998).",
      "journal-title": "Nature"
    },
    {
      "key": "BFnmat1476_CR22",
      "doi-asserted-by": "publisher",
      "first-page": "4995",
      "DOI": "10.1021/ma9619288",
      "volume": "30,",
      "author": "S Walheim",
      "year": "1997",
      "unstructured": "Walheim, S., Boltau, M., Mlynek, J., Krausch, G. & Steiner, U. Structure formation via polymer demixing in spin-cast films. Macromolecules 30, 4995\u20135003 (1997).",
      "journal-title": "Macromolecules"
    },
    {
      "key": "BFnmat1476_CR23",
      "doi-asserted-by": "publisher",
      "first-page": "2030",
      "DOI": "10.1021/ma0477145",
      "volume": "38,",
      "author": "PC Jukes",
      "year": "2005",
      "unstructured": "Jukes, P. C., Heriot, S. Y., Sharp, J. S. & Jones, R. A. L. Time-resolved light scattering studies of phase separation in thin film semiconducting polymer blends during spin-coating. Macromolecules 38, 2030\u20132032 (2005).",
      "journal-title": "Macromolecules"
    },
    {
      "key": "BFnmat1476_CR24",
      "doi-asserted-by": "publisher",
      "first-page": "93",
      "DOI": "10.1063/1.1695731",
      "volume": "42,",
      "author": "JW Cahn",
      "year": "1965",
      "unstructured": "Cahn, J. W. Phase separation by spinodal decomposition in isotropic systems. J. Chem. Phys. 42, 93\u201399 (1965).",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "BFnmat1476_CR25",
      "doi-asserted-by": "publisher",
      "first-page": "5173",
      "DOI": "10.1103/PhysRevLett.81.5173",
      "volume": "81,",
      "author": "M Sferrazza",
      "year": "1998",
      "unstructured": "Sferrazza, M. et al. Interfacial instability driven by dispersive forces: The early stages of spinodal dewetting of a thin polymer film on a polymer substrate. Phys. Rev. Lett. 81, 5173\u20135176 (1998).",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "BFnmat1476_CR26",
      "doi-asserted-by": "publisher",
      "first-page": "75",
      "DOI": "10.1103/PhysRevLett.68.75",
      "volume": "68,",
      "author": "G Reiter",
      "year": "1992",
      "unstructured": "Reiter, G. Dewetting of thin polymer-films. Phys. Rev. Lett. 68, 75\u201378 (1992).",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "BFnmat1476_CR27",
      "doi-asserted-by": "publisher",
      "first-page": "761",
      "DOI": "10.1051/rphysap:01980001503076100",
      "volume": "15,",
      "author": "L Nevot",
      "year": "1980",
      "unstructured": "Nevot, L. & Croce, P. Caract\u00e9risation des surfaces par r\u00e9flexion rasant de rayons x: application \u00e1 l\u2019\u00e9tude du polissage de quelques verres silicates. Rev. Phys. Appl. 15, 761\u2013779 (1980).",
      "journal-title": "Rev. Phys. Appl."
    },
    {
      "key": "BFnmat1476_CR28",
      "doi-asserted-by": "publisher",
      "first-page": "3682",
      "DOI": "10.1021/la00036a053",
      "volume": "9,",
      "author": "F Brochard-Wyart",
      "year": "1993",
      "unstructured": "Brochard-Wyart, F., Martin, P. & Redon, C. Liquid/liquid dewetting. Langmuir 9, 3682\u20133690 (1993).",
      "journal-title": "Langmuir"
    },
    {
      "key": "BFnmat1476_CR29",
      "doi-asserted-by": "publisher",
      "first-page": "421",
      "DOI": "10.1007/s10189-001-8055-3",
      "volume": "6,",
      "author": "PG de Gennes",
      "year": "2001",
      "unstructured": "de Gennes, P. G. Instabilities during the evaporation of a film: Non-glassy polymer plus volatile solvent. Eur. Phys. J. E 6, 421\u2013424 (2001).",
      "journal-title": "Eur. Phys. J. E"
    },
    {
      "key": "BFnmat1476_CR30",
      "doi-asserted-by": "publisher",
      "first-page": "7248",
      "DOI": "10.1063/1.453369",
      "volume": "87,",
      "author": "D Broseta",
      "year": "1987",
      "unstructured": "Broseta, D., Leibler, L., Kaddour, L. O. & Strazielle, C. A theoretical and experimental study of interfacial-tension of immiscible polymer blends in solution. J. Chem. Phys. 87, 7248\u20137256 (1987).",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "BFnmat1476_CR31",
      "doi-asserted-by": "publisher",
      "first-page": "253",
      "DOI": "10.1016/j.synthmet.2004.03.009",
      "volume": "144,",
      "author": "A Bernasik",
      "year": "2004",
      "unstructured": "Bernasik, A. et al. Lamellar structures formed in spin-cast blends of insulating and conducting polymers. Synth. Met. 144, 253\u2013257 (2004).",
      "journal-title": "Synth. Met."
    },
    {
      "key": "BFnmat1476_CR32",
      "doi-asserted-by": "publisher",
      "first-page": "7762",
      "DOI": "10.1021/la9903090",
      "volume": "15,",
      "author": "AF Routh",
      "year": "1999",
      "unstructured": "Routh, A. F. & Russel, W. B. A process model for latex film formation: Limiting regimes for individual driving forces. Langmuir 15, 7762\u20137773 (1999).",
      "journal-title": "Langmuir"
    }
  ],
  "container-title": "Nature Materials",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://www.nature.com/articles/nmat1476.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://www.nature.com/articles/nmat1476",
      "content-type": "text/html",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://www.nature.com/articles/nmat1476.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2022,
        7,
        6
      ]
    ],
    "date-time": "2022-07-06T18:54:30Z",
    "timestamp": 1657133670000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://www.nature.com/articles/nmat1476"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2005,
        9,
        4
      ]
    ]
  },
  "references-count": 32,
  "journal-issue": {
    "issue": "10",
    "published-print": {
      "date-parts": [
        [
          2005,
          10,
          1
        ]
      ]
    }
  },
  "alternative-id": [
    "BFnmat1476"
  ],
  "URL": "http://dx.doi.org/10.1038/nmat1476",
  "relation": {},
  "ISSN": [
    "1476-1122",
    "1476-4660"
  ],
  "subject": [],
  "container-title-short": "Nature Mater",
  "published": {
    "date-parts": [
      [
        2005,
        9,
        4
      ]
    ]
  },
  "assertion": [
    {
      "value": "25 October 2004",
      "order": 1,
      "name": "received",
      "label": "Received",
      "group": {
        "name": "ArticleHistory",
        "label": "Article History"
      }
    },
    {
      "value": "2 August 2005",
      "order": 2,
      "name": "accepted",
      "label": "Accepted",
      "group": {
        "name": "ArticleHistory",
        "label": "Article History"
      }
    },
    {
      "value": "4 September 2005",
      "order": 3,
      "name": "first_online",
      "label": "First Online",
      "group": {
        "name": "ArticleHistory",
        "label": "Article History"
      }
    },
    {
      "value": "The authors declare no competing financial interests.",
      "order": 1,
      "name": "Ethics",
      "group": {
        "name": "EthicsHeading",
        "label": "Competing interests"
      }
    }
  ]
}