Highly stable Pt monolayer on PdAu nanoparticle electrocatalysts for the oxygen reduction reaction
10.1038/ncomms2124
Crossref journal-article
Springer Science and Business Media LLC
Nature Communications (297)
Bibliography

Sasaki, K., Naohara, H., Choi, Y., Cai, Y., Chen, W.-F., Liu, P., & Adzic, R. R. (2012). Highly stable Pt monolayer on PdAu nanoparticle electrocatalysts for the oxygen reduction reaction. Nature Communications, 3(1).

Authors 7
  1. Kotaro Sasaki (first)
  2. Hideo Naohara (additional)
  3. YongMan Choi (additional)
  4. Yun Cai (additional)
  5. Wei-Fu Chen (additional)
  6. Ping Liu (additional)
  7. Radoslav R. Adzic (additional)
References 42 Referenced 395
  1. Gasteiger, H. A., Kocha, S. S., Sompalli, B. & Wagner, F. T. Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCs. Appl. Catal. B Environ. 56, 9–35 (2005). (10.1016/j.apcatb.2004.06.021) / Appl. Catal. B Environ. by HA Gasteiger (2005)
  2. Ferreira, P. J. et al. Instability of Pt/C electrocatalysts in proton exchange membrane fuel cells. J. Electrochem. Soc. 152, A2256–A2271 (2005). (10.1149/1.2050347) / J. Electrochem. Soc. by PJ Ferreira (2005)
  3. Yasuda, K., Taniguchi, A., Akita, T., Ioroi, T. & Siroma, Z. platinum dissolution and deposition in the polymer electrolyte membrane of a PEM fuel cell as studied by potential cycling. Phys. Chem. Chem. Phys. 8, 746–752 (2006). (10.1039/B514342J) / Phys. Chem. Chem. Phys. by K Yasuda (2006)
  4. Sasaki, K., Shao, M. & Adzic, R. R. in Polymer Electrolyte Fuel Cell Durability— Dissolution and Stability of Platinum in Oxygen Cathodes, (eds Büchi, N., Inaba, M. & Schmidt, T.J.) 7–27 (Springer, 2009). (10.1007/978-0-387-85536-3_2)
  5. Debe, M. K. Electrocatalyst approaches and challenges for automotive fuel cells. Nature 486, 43–51 (2012). (10.1038/nature11115) / Nature by MK Debe (2012)
  6. Sasaki, K. et al. Core-protected platinum monolayer shell high-stability electrocatalysts for fuel-cell cathodes. Angew. Chem. Int. Ed. 49, 8602–8607 (2010). (10.1002/anie.201004287) / Angew. Chem. Int. Ed. by K Sasaki (2010)
  7. Zhang, J., Vukmirovic, M. B., Xu, Y., Mavrikakis, M. & Adzic, R. R. Controlling the catalytic activity of platinum-monolayer electrocatalysts for oxygen reduction with different substrates. Angew. Chem. Int. Ed. 44, 2132–2135 (2005). (10.1002/anie.200462335) / Angew. Chem. Int. Ed. by J Zhang (2005)
  8. Adzic, R. R. et al. Platinum monolayer fuel cell electrocatalysts. Top. Catal. 46, 249–262 (2007). (10.1007/s11244-007-9003-x) / Top. Catal. by RR Adzic (2007)
  9. Adzic, R. R. in Electrocatalysis, (eds Lipkowski J. & Ross, P.N.) Vol. 5, 197 (VCH Publishers, New York, 1998). / Electrocatalysis by RR Adzic (1998)
  10. Anderson, A. B. O2 reduction and CO oxidation at the Pt-electrolyte interface. The role of H2O and OH adsorption bond strengths. Electrochim. Acta 47, 3759–3763 (2002). (10.1016/S0013-4686(02)00346-8) / Electrochim. Acta by AB Anderson (2002)
  11. Hansen, M. in Constitution of Binary Alloys (2nd edn) 224 (McGraw Hill Book Company, New York, 1958).
  12. Rodriguez, J. A. et al. Gold nanoparticles on ceria: importance of O vacancies in the activation of gold. Top. Catal. 44, 73–81 (2007). (10.1007/s11244-007-0280-1) / Top. Catal. by JA Rodriguez (2007)
  13. Schwartz, V. et al. XAS study of Au supported on TiO2: influence of oxidation state and particle size on catalytic activity. J. Phys. Chem. B 108, 15782–15790 (2004). (10.1021/jp048076v) / J. Phys. Chem. B by V Schwartz (2004)
  14. Frenkel, A. I. [Solving the 3D structure of metal nanoparticles]. Z. Kristallogr. 222, 605–611 (2007). (10.1524/zkri.2007.222.11.605) / Z. Kristallogr. by AI Frenkel (2007)
  15. The US Department of Energy (DOE). Energy Efficiency and Renewable Energy (EERE). http://www1.eere.energy.gov/hydrogenandfuelcells/mypp/pdfs/fuel_cells.pdf (2012).
  16. Wang, J. X. et al. Kirkendall effect and lattice concentration in nanoparticles: a new strategy to enhance sustainable activity. J. Am. Chem. Soc. 133, 13551–13557 (2011). (10.1021/ja204518x) / J. Am. Chem. Soc. by JX Wang (2011)
  17. Cai, Y., Ma, C., Zhu, Y., Wang, J. X. & Adzic, R. R. Low-coordinate sites in oxygen-reduction electrocatalysis: their roles and methods for removal. Langmuir 27, 8540–8547 (2011). (10.1021/la200753z) / Langmuir by Y Cai (2011)
  18. Kuttiyiel, K. A. et al. Bimetallic IrNi core platinum monolayer shell electrocatalysts for the oxygen reduction reaction. Energy Environ. Sci. 5, 5297–5304 (2012). (10.1039/C1EE02067F) / Energy Environ. Sci. by KA Kuttiyiel (2012)
  19. Zhang, H., Watanabe, T., Okumura, M., Haruta, M. & Toshima, N. Catalytically highly active top gold atom on palladium nanocluster. Nat. Mater. 11, 49–52 (2012). (10.1038/nmat3143) / Nat. Mater. by H Zhang (2012)
  20. Reiser, C. A. et al. A reverse-current decay mechanism for fuel cells. Electrochem. Solid State Lett. 8, A273–A276 (2005). (10.1149/1.1896466) / Electrochem. Solid State Lett. by CA Reiser (2005)
  21. Stuve, E. M. & Gastaiger, H. PEMFC Short Course, 210th Meeting of The Electrochemical Society, Cancun, Mexico (2006).
  22. The DOE–EERE Durability Working Group (DWG). DOE–EERE Durability Working Group (DWG) Meeting, Boston, MA. http://www1.eere.energy.gov/hydrogenandfuelcells/pdfs/durability_working_group_minutes_oct_2011.pdf (2011).
  23. Fang, Y. -L. et al. Structural analysis of palladium-decorated gold nanoparticles as colloidal bimetallic catalysts. Catal. Today 160, 96–102 (2011). (10.1016/j.cattod.2010.08.010) / Catal. Today by Y-L Fang (2011)
  24. Fang, Y. -L., Heck, K. N., Alvarez, P. J. J. & Wong, M. S. Kinetics analysis of palladium/gold nanoparticles as colloidal hydrodechlorination catalysts. ACS Catal. 1, 128–138 (2010). (10.1021/cs100067k) / ACS Catal. by Y-L Fang (2010)
  25. Maroun, F., Ozanam, F., Magnussen, O. M. & Behm, R. J. The role of atomic ensembles in the reactivity of bimetallic electrocatalysts. Science 293, 1811–1814 (2001). (10.1126/science.1061696) / Science by F Maroun (2001)
  26. Liu, F., Wechsler, D. & Zhang, P. Alloy-structure-dependent electronic behavior and surface properties of Au-Pd nanoparticles. Chem. Phys. Lett. 461, 254–259 (2008). (10.1016/j.cplett.2008.07.029) / Chem. Phys. Lett. by F Liu (2008)
  27. Ambrosio, R. C. & Ticianelli, E. A. Studies on the influence of palladium coatings on the electrochemcial and structural properties of a metal hydride alloy. Surf. Coat. Tech. 197, 215–222 (2005). (10.1016/j.surfcoat.2004.07.087) / Surf. Coat. Tech. by RC Ambrosio (2005)
  28. Muller, J. E., Jepsen, O., Andersen, O. K. & Wilkins, J. W. Systematic structure in the K-edge photoabsorption spectra of teh 4d transition metals: theory. Phys. Rev. Lett. 40, 720–722 (1978). (10.1103/PhysRevLett.40.720) / Phys. Rev. Lett. by JE Muller (1978)
  29. Davis, R. J., Landry, S. M., Horsley, J. A. & Boudart, M. X-ray-adsorption study of the interation of hydrogen with clusters of supported palladium. Phys. Rev. B 30, 10580–10583 (1989). (10.1103/PhysRevB.39.10580) / Phys. Rev. B by RJ Davis (1989)
  30. Nahm, T.- U. et al. Electronic structure of disordered Au-Pd alloys studied by electron spectroscopies. Phys. Rev. B 58, 9817–9825 (1998). (10.1103/PhysRevB.58.9817) / Phys. Rev. B by T-U Nahm (1998)
  31. Cook, S. C., Padmos, J. D. & Zhang, P. Surface structural characteristics and tunable electronic properties of wet-chemically prepared Pd nanoparticles. J. Chem. Phys. 128, 154705 (2008). (10.1063/1.2901034) / J. Chem. Phys. by SC Cook (2008)
  32. Zhang, J., Sasaki, K., Sutter, E. & Adzic, R. R. Stabilization of platinum oxygen-reduction electrocatalysts using gold clusters. Science 315, 220–222 (2007). (10.1126/science.1134569) / Science by J Zhang (2007)
  33. Wang, L., Roudgar, A. & Eikerling, M. Ab initio study of stability and site-specific oxygen adsorption energies of Pt nanoparticles. J. Phys. Chem. C 113, 17989–17996 (2009). (10.1021/jp900965q) / J. Phys. Chem. C by L Wang (2009)
  34. Rinaldo, S. G., Strumper, J. & Eikerling, M. Physical theory of platinum nanoparticle dissolution in polymer electrolyte fuel cells. J. Phys. Chem. C 114, 5775–5785 (2010). (10.1021/jp9101509) / J. Phys. Chem. C by SG Rinaldo (2010)
  35. Brankovic, S. R., Wang, J. X. & Adzic, R. R. Metal monolayer deposition by replacement of metal adlayers on electrode surfaces. Surf. Sci. 477, L173–L179 (2001). (10.1016/S0039-6028(00)01103-1) / Surf. Sci. by SR Brankovic (2001)
  36. Zhang, J. et al. Platinum monolayer electrocatalysts for O2 reduction: Pt monolayer on Pd(111) and on carbon-supported Pd nanoparticles. J. Phys. Chem. B 108, 10955–10964 (2004). (10.1021/jp0379953) / J. Phys. Chem. B by J Zhang (2004)
  37. Sasaki, K. et al. Recent advances in platinum monolayer electrocatalysts for oxygen reduction reaction: scale-up synthesis, structure and activity of Pt shells on Pd cores. Electrochim. Acta 55, 2645–2652 (2010). (10.1016/j.electacta.2009.11.106) / Electrochim. Acta by K Sasaki (2010)
  38. McBreen, J., O'Grady, W. E., Pandya, K. I., Hoffman, R. W. & Sayers, D. E. EXAFS study of the nickel-oxide electrode. Langmuir 3, 428–433 (1987). (10.1021/la00075a027) / Langmuir by J McBreen (1987)
  39. Ravel, B. & Newville, M. ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT. J. Synchrotron Radiat. 12, 537–541 (2005). (10.1107/S0909049505012719) / J. Synchrotron Radiat. by B Ravel (2005)
  40. Kresse, G. & Furthmuller, J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. Phys. Rev. B 54, 11169–11186 (1996). (10.1103/PhysRevB.54.11169) / Phys. Rev. B by G Kresse (1996)
  41. Blöchl, P. E. Projector augmented-wave method. Phys. Rev. B 50, 17953–17979 (1994). (10.1103/PhysRevB.50.17953) / Phys. Rev. B by PE Blöchl (1994)
  42. Hammer, B., Hansen, L. B. & Nørskov, J. K. Improved adsorption energies within density-functional theory using revised Perdew-Burke-Erzerhof functionals. Phys. Rev. B 59, 7413–7421 (1999). (10.1103/PhysRevB.59.7413) / Phys. Rev. B by B Hammer (1999)
Dates
Type When
Created 12 years, 10 months ago (Oct. 9, 2012, 5:35 a.m.)
Deposited 2 years, 7 months ago (Jan. 5, 2023, 7:21 p.m.)
Indexed 19 hours, 14 minutes ago (Sept. 3, 2025, 6:24 a.m.)
Issued 12 years, 10 months ago (Oct. 9, 2012)
Published 12 years, 10 months ago (Oct. 9, 2012)
Published Online 12 years, 10 months ago (Oct. 9, 2012)
Funders 0

None

@article{Sasaki_2012, title={Highly stable Pt monolayer on PdAu nanoparticle electrocatalysts for the oxygen reduction reaction}, volume={3}, ISSN={2041-1723}, url={http://dx.doi.org/10.1038/ncomms2124}, DOI={10.1038/ncomms2124}, number={1}, journal={Nature Communications}, publisher={Springer Science and Business Media LLC}, author={Sasaki, Kotaro and Naohara, Hideo and Choi, YongMan and Cai, Yun and Chen, Wei-Fu and Liu, Ping and Adzic, Radoslav R.}, year={2012}, month=oct }