DOI: 10.1038/ncomms1843. Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries

Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries

10.1038/ncomms1843

Crossref journal-article

Springer Science and Business Media LLC

Nature Communications (297)

Bibliography

Hayashi, A., Noi, K., Sakuda, A., & Tatsumisago, M. (2012). Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries. Nature Communications, 3(1).

Authors 4

Akitoshi Hayashi (first)
Kousuke Noi (additional)
Atsushi Sakuda (additional)
Masahiro Tatsumisago (additional)

References 31 Referenced 926

Delmas, C., Braconnier, J. J, Fouassier, C. & Hagenmuller, P. Electrochemical intercalation of sodium in NaxCoO2 bronzes. Solid State Ionics 3-4, 165–169 (1981). (10.1016/0167-2738(81)90076-X) / Solid State Ionics by C Delmas (1981)
Komaba, S., Takei, C., Nakayama, T., Ogata, A. & Yabuuchi, N. Electrochemical intercalation activity of layered NaCrO2 versus LiCrO2 . Electrochem. Commun. 12, 355–358 (2010). (10.1016/j.elecom.2009.12.033) / Electrochem. Commun. by S Komaba (2010)
Nishijima, M., Gocheva, I. D., Okada, S., Doi, T., Yamaki, J. I. & Nishida, T. Cathode properties of metal trifluorides in Li and Na secondary batteries. J. Power Sources 190, 558–562 (2009). (10.1016/j.jpowsour.2009.01.051) / J. Power Sources by M Nishijima (2009)
Park, C. W., Ryu, H. S., Kim, K. W., Ahn, J.- H., Lee, J. Y. & Ahn, H. J. Discharge properties of all-solid sodium-sulfur battery using poly (ethylene oxide) electrolyte. J. Power Sources 165, 450–454 (2007). (10.1016/j.jpowsour.2006.11.083) / J. Power Sources by CW Park (2007)
Lu, X., Xia, G., Lemmon, J. P & Yang, Z. Advanced materials for sodium-beta alumina batteries: status, challenges and perspectives. J. Power Sources 195, 2431–2422 (2010). (10.1016/j.jpowsour.2009.11.120) / J. Power Sources by X Lu (2010)
Armand, M. & Tarascon, J.- M. Building better batteries. Nature 451, 652–657 (2008). (10.1038/451652a) / Nature by M Armand (2008)
Tarascon, J.- M. & Armand, M. Issues and challenges facing rechargeable lithium batteries. Nature, 414, 359–367 (2001). (10.1038/35104644) / Nature, by J-M Tarascon (2001)
Kamaya, N. &, et al. A lithium superionic conductor. Nat. Mater. 10, 682–686 (2011). (10.1038/nmat3066) / Nat. Mater. by N Kamaya (2011)
Ribes, M., Barrau, B. & Souquet, J. L. Sulfide glasses: glass forming region, structure and ionic conduction of glasses in Na2S-XS2 (X=Si; Ge), Na2S-P2S5 and Li2S-GeS2 systems. J. Non-Cryst. Solids 38&39, 271–276 (1980). (10.1016/0022-3093(80)90430-5) / J. Non-Cryst. Solids by M Ribes (1980)
Susman, S., Boehm, L., Volin, K. J. & Delbecq, C. J. A new method for the preparation of fast-conducting, reactive glass systems. Solid State Ionics 5, 667–670 (1981). (10.1016/0167-2738(81)90342-8) / Solid State Ionics by S Susman (1981)
Yao, W. & Martin,, S. W. Ionic conductivity of glasses in the MI+M2S+(0.1Ga2S3+0.9GeS2) system (M=Li, Na, K and Cs). Solid State Ionics 178, 1777–1784 (2008). (10.1016/j.ssi.2007.10.011) / Solid State Ionics by W Yao (2008)
Jansen, M. & Henseler, U. Synthesis, structure determination, and ionic conductivity of sodium tetrathiophoshate. J. Solid State Chem. 99, 110–119 (1992). (10.1016/0022-4596(92)90295-7) / J. Solid State Chem. by M Jansen (1992)
Hooper, A. A study of the electrical properties of single-crystal and polycrystalline β-alumina using complex plane analysis. J. Phys. D: Appl. Phys., 10, 1487–1496 (1977). (10.1088/0022-3727/10/11/013) / J. Phys. D: Appl. Phys., by A Hooper (1977)
Bohnke, O., Ronchetti, S. & Mazza, D. Conductivity measurements on nasicon and nasicon-modified materials. Solid State Ionics 122, 127–136 (1999). (10.1016/S0167-2738(99)00062-4) / Solid State Ionics by O Bohnke (1999)
Coors, W. G., Gordon, J. H. & Menzer, S. G. Electrochemical cell comprising ionically conductive membrane and porous multiphase electrode. US patent US2010/0297537A1 (2010).
Mizuno, F., Hayashi, A., Tadanaga, K. & Tatsumisago, M. New, highly ion-conductive crystals precipitated from Li2S-P2S5 glasses. Adv. Mater. 17, 918–921 (2005). (10.1002/adma.200401286) / Adv. Mater. by F Mizuno (2005)
Hayashi, A., Miami, K., Ujiie, S. & Tatsumisago, M. Preparation and ionic conductivity of Li7P3S11−z glass-ceramic electrolytes. J. Non-Cryst. Solids 356, 2670–2673 (2010). (10.1016/j.jnoncrysol.2010.04.048) / J. Non-Cryst. Solids by A Hayashi (2010)
Minami, T., Hayashi, A. & Tatsumisago, M. Recent progress of glass and glass-ceramics as solid electrolytes for lithium secondary batteries. Solid State Ionics 177, 2715–2720 (2006). (10.1016/j.ssi.2006.07.017) / Solid State Ionics by T Minami (2006)
Ohta, N., Takada, K., Zhang, L., Ma, R., Osada, M. & Sasaki, T. Enhancement of the high-rate capability of solid-state lithium batteries by nanoscale interfacial modification. Adv. Mater. 18, 2226–2229 (2006). (10.1002/adma.200502604) / Adv. Mater. by N Ohta (2006)
Tatsumsiago, M. & Hayashi, A. All-solid-state lithium secondary batteries using sulfide-based glass ceramic electrolytes. Funct. Mater. Lett. 1, 31–36 (2008). (10.1142/S1793604708000071) / Funct. Mater. Lett. by M Tatsumsiago (2008)
Sakuda, A., Hayashi, A. & Tatsumisago, M. Interfacial observation between LiCoO2 electrode and Li2S-P2S5 solid electrolytes of all-solid-state lithium secondary batteries using transmission electron microscopy. Chem. Mater. 22, 949–956 (2010). (10.1021/cm901819c) / Chem. Mater. by A Sakuda (2010)
Tachez, M., Malugani, J. P., Mercier, R. & Robert, G. Ionic conductivity and phase transition in lithium thiophosphate Li3PS4 . Solid State Ionics 14, 181–185 (1984). (10.1016/0167-2738(84)90097-3) / Solid State Ionics by M Tachez (1984)
Whittingham, M. S. Chemistry of intercalation compounds: metal guests in chalcogenide hosts. Prog. Solid State Chem. 12, 41–99 (1978). (10.1016/0079-6786(78)90003-1) / Prog. Solid State Chem. by MS Whittingham (1978)
Inoue, T., Kanai, K., Itaya, M. & Fujimoto, M. Negative electrode and non-aqueous electrolyte secondary battery with it (in Japanese). JP Patent 2006-244976 (2006).
Tatsumisago, M., Shinkuma, Y. & Minami, T. Stabilization of superionic α-AgI at room temperature in a glass matrix. Nature 354, 217–218 (1991). (10.1038/354217a0) / Nature by M Tatsumisago (1991)
Tatsumsiago, M., Saito, T. & Minami, T. Stabilization of superionic α-AgI at room temperature by heating of AgI-Ag2O-MoO3 glasses. Chem. Lett. 790–791 (2001). (10.1246/cl.2001.790)
Mizuno, F., Hayashi, A., Tadanaga, K. & Tatsumisago, M. Effects of conductive additives in composite positive electrodes on charge-discharge behaviors of all-solid-state lithium secondary batteries. J. Electrochem. Soc. 152, A1499–A1503 (2005). (10.1149/1.1939633) / J. Electrochem. Soc. by F Mizuno (2005)
Kitaura, H., Hayashi, A., Ohtomo, T., Hama, S. & Tatsumisago, M. Fabrication of electrode-electrolyte interfaces in all-solid-state rechargeable lithium batteries by using a supercooled liquid state of the glassy electrolytes. J. Mater. Chem. 21, 118–124 (2011). (10.1039/C0JM01090A) / J. Mater. Chem. by H Kitaura (2011)
Minami, K., Hayashi, A., Ujiie, S. & Tatsumisago, M. Electrical and electrochemical properties of glass-ceramic electrolytes in the systems Li2S-P2S5-P2S3 and Li2S-P2S5-P2O5 . Solid State Ionics 192, 122–125 (2011). (10.1016/j.ssi.2010.06.018) / Solid State Ionics by K Minami (2011)
Hayashi, A., Ohtomo, T., Mizuno, F., Tadanaga, K. & Tatsumisago, M. All-solid-state Li/S batteries with highly conductive glass-ceramic electrolytes. Electrochem. Commun. 5, 701–705 (2003). (10.1016/S1388-2481(03)00167-X) / Electrochem. Commun. by A Hayashi (2003)
Nagao, M., Hayashi, A. & Tatsumisago, M. Sulfur-carbon composite electrode for all-solid-state Li/S battery with Li2S-P2S5 solid electrolyte. Electrochim. Acta 56, 6055–6059 (2011). (10.1016/j.electacta.2011.04.084) / Electrochim. Acta by M Nagao (2011)

Dates

Type	When
Created	13 years, 3 months ago (May 22, 2012, 5:40 a.m.)
Deposited	2 years, 7 months ago (Jan. 5, 2023, 7:34 p.m.)
Indexed	19 hours, 25 minutes ago (Aug. 23, 2025, 9:56 p.m.)
Issued	13 years, 3 months ago (May 22, 2012)
Published	13 years, 3 months ago (May 22, 2012)
Published Online	13 years, 3 months ago (May 22, 2012)

Funders 0

None

BibTeX

@article{Hayashi_2012, title={Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries}, volume={3}, ISSN={2041-1723}, url={http://dx.doi.org/10.1038/ncomms1843}, DOI={10.1038/ncomms1843}, number={1}, journal={Nature Communications}, publisher={Springer Science and Business Media LLC}, author={Hayashi, Akitoshi and Noi, Kousuke and Sakuda, Atsushi and Tatsumisago, Masahiro}, year={2012}, month=may }

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