Cation-induced kinetic trapping and enhanced hydrogen adsorption in a modulated anionic metal–organic framework
10.1038/nchem.333
Crossref journal-article
Springer Science and Business Media LLC
Nature Chemistry (297)
Bibliography

Yang, S., Lin, X., Blake, A. J., Walker, G. S., Hubberstey, P., Champness, N. R., & Schröder, M. (2009). Cation-induced kinetic trapping and enhanced hydrogen adsorption in a modulated anionic metal–organic framework. Nature Chemistry, 1(6), 487–493.

Authors 7
  1. Sihai Yang (first)
  2. Xiang Lin (additional)
  3. Alexander J. Blake (additional)
  4. Gavin S. Walker (additional)
  5. Peter Hubberstey (additional)
  6. Neil R. Champness (additional)
  7. Martin Schröder (additional)
References 39 Referenced 385
  1. Schlapbach, L. & Züttel, A. Hydrogen-storage materials for mobile applications. Nature 414, 353–358 (2001). (10.1038/35104634) / Nature by L Schlapbach (2001)
  2. Rosi, N. L. et al. Hydrogen storage in microporous metal–organic frameworks. Science 300, 1127–1130 (2003). (10.1126/science.1083440) / Science by NL Rosi (2003)
  3. Lin, X., Jia, J., Hubberstey, P., Schröder, M. & Champness, N. R. Hydrogen storage in metal–organic frameworks. CrystEngComm. 9, 438–448 (2007). (10.1039/B706207A) / CrystEngComm. by X Lin (2007)
  4. Férey, G. et al. A chromium terephthalate-based solid with unusually large pore volumes and surface area. Science 309, 2040–2042 (2005); correction 310, 1119 (2005). (10.1126/science.1116275) / Science by G Férey (2005)
  5. Bhatia, S. K. & Myers, A. L. Optimum conditions for adsorptive storage. Langmuir 22, 1688–1700 (2006). (10.1021/la0523816) / Langmuir by SK Bhatia (2006)
  6. Chun, H., Dybtsev, D. N., Kim, H. & Kim, K. Synthesis, X-ray crystal structures, and gas sorption properties of pillared square grid nets based on paddle-wheel motifs: Implications for hydrogen storage in porous materials. Chem. Eur. J. 11, 3521–3529 (2005). (10.1002/chem.200401201) / Chem. Eur. J. by H Chun (2005)
  7. Luo, J. et al. Hydrogen adsorption in a highly stable porous rare-earth metal–organic framework: sorption properties and neutron diffraction studies. J. Am. Chem. Soc. 130, 9626–9297 (2008). (10.1021/ja801411f) / J. Am. Chem. Soc. by J Luo (2008)
  8. Lin, X. et al. High H2 adsorption by coordination-framework materials. Angew. Chem. Int. Ed. 45, 7358–7364 (2006). (10.1002/anie.200601991) / Angew. Chem. Int. Ed. by X Lin (2006)
  9. Dincă, M. et al. Observation of Cu2+-H2 interactions in a fully desolvated sodalite-type metal–organic framework. Angew. Chem. Int. Ed. 46, 1419–1422 (2007). (10.1002/anie.200604362) / Angew. Chem. Int. Ed. by M Dincă (2007)
  10. Lin, X. et al. High capacity hydrogen adsorption in Cu(ii) tetracarboxylate framework materials: the role of pore size, ligand functionalization, and exposed metal sites. J. Am. Chem. Soc. 131, 2159–2171 (2009). (10.1021/ja806624j) / J. Am. Chem. Soc. by X Lin (2009)
  11. Zhao, X. et al. Hysteretic adsorption and desorption of hydrogen by nanoporous metal–organic frameworks. Science 306, 1012–1015 (2004). (10.1126/science.1101982) / Science by X Zhao (2004)
  12. Choi, H. J., Dincă, M. & Long, J. R. Broadly hysteretic H2 adsorption in the microporous metal–organic framework Co(1, 4-benzenedipyrazolate). J. Am. Chem. Soc. 130, 7848–7850 (2008). (10.1021/ja8024092) / J. Am. Chem. Soc. by HJ Choi (2008)
  13. Férey, G. et al. Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M(OH)(O2C-C6H4-CO2) (M = Al3+, Cr3+), MIL-53. Chem. Commun. 2976–2977 (2003). (10.1039/B308903G)
  14. Yang, C., Wang, X. & Omary, M. A. Fluorous metal–organic frameworks for high-density gas adsorption. J. Am. Chem. Soc., 129, 15454–15455 (2007). (10.1021/ja0775265) / J. Am. Chem. Soc. by C Yang (2007)
  15. Mulfort, K. L. & Hupp, J. T. Chemical reduction of metal–organic framework materials as a method to enhance gas uptake and binding. J. Am. Chem. Soc. 129, 9604–9605 (2007). (10.1021/ja0740364) / J. Am. Chem. Soc. by KL Mulfort (2007)
  16. Mulfort, K. L. & Hupp, J. T. Alkali metal cation effects on hydrogen uptake and binding in metal–organic frameworks. Inorg. Chem. 47, 7936–7938 (2008). (10.1021/ic800700h) / Inorg. Chem. by KL Mulfort (2008)
  17. Blomqvist, A., Araújo, C. M., Srepusharawoot, P. & Ahuja, R. Li-decorated metal–organic framework 5: a route to achieving a suitable hydrogen storage medium. Proc. Natl Acad. Sci. USA 104, 20173–20176 (2007). (10.1073/pnas.0708603104) / Proc. Natl Acad. Sci. USA by A Blomqvist (2007)
  18. Han, S. S. & Goddard, W. A. Lithium-doped metal–organic frameworks for reversible H2 storage at ambient temperature. J. Am. Chem. Soc. 129, 8422–8423 (2007). (10.1021/ja072599+) / J. Am. Chem. Soc. by SS Han (2007)
  19. Han, S. S. & Goddard, W. A. High H2 storage of hexagonal metal–organic frameworks from first-principles-based grand canonical Monte carlo simulations. J. Phys Chem. C. 112, 13431–13436 (2008). (10.1021/jp800832b) / J. Phys Chem. C. by SS Han (2008)
  20. Klontzas, E., Mavrandonakis, A., Tylianakis, E. & Froudakis, G. E. Improving hydrogen storage capacity of MOF by functionalization of the organic linker with lithium atoms. Nano Lett. 8, 1572–1576 (2008). (10.1021/nl072941g) / Nano Lett. by E Klontzas (2008)
  21. Mavrandonakis, A., Tylianakis, E., Stubos, A. K. & Froudakis, G. E. Why Li doping in MOFs enhances H2 storage capacity? a multi-scale theoretical study. J. Phys. Chem. C. 112, 7290–7294 (2008). (10.1021/jp7102098) / J. Phys. Chem. C. by A Mavrandonakis (2008)
  22. Dalach, P., Frost, H., Snurr, R. Q. & Ellis, D. E. Enhanced hydrogen uptake and the electronic structure of lithium-doped metal–organic frameworks. J. Phys. Chem. C. 112, 9278–9284 (2008). (10.1021/jp801008d) / J. Phys. Chem. C. by P Dalach (2008)
  23. Cao, D., Lan, J., Wang, W. & Smit, B. Lithium-doped 3D covalent organic frameworks: high-capacity hydrogen storage materials. Angew. Chem. Int. Ed. 48, 4730–4733 (2009). (10.1002/anie.200900960) / Angew. Chem. Int. Ed. by D Cao (2009)
  24. Spek, A. L. Single-crystal structure validation with the program PLATON. J. Appl. Crystallogr. 36, 7–13 (2003). (10.1107/S0021889802022112) / J. Appl. Crystallogr. by AL Spek (2003)
  25. Yang, T., Yang, S., Liao, F. & Lin, J. Two isotypic diphosphates LiM2H3(P2O7)2 (M = Ni, Co) containing ferromagnetic zigzag MO6 chains. J. Solid State Chem. 181, 1347–1353 (2006). (10.1016/j.jssc.2008.03.006) / J. Solid State Chem. by T Yang (2006)
  26. Fuentes-Cabrera, M., Nicholson, D. M. & Sumpter, B. G. Electronic structure and properties of isoreticular metal–organic frameworks: the case of M-IRMOF1 (M = Zn, Cd, Be, Mg, and Ca). J. Chem. Phys. 123, 124713–124718 (2005). (10.1063/1.2037587) / J. Chem. Phys. by M Fuentes-Cabrera (2005)
  27. Düren, T., Millange, F., Férey, G., Walton K. S. & Snurr R. Q. Calculating geometric surface areas as a characterization tool for metal–organic frameworks. J. Phys. Chem. C. 111, 15350–15356 (2007). (10.1021/jp074723h) / J. Phys. Chem. C. by T Düren (2007)
  28. Rappé, A. K., Casewit, C. J., Colwell, K. S., Goddard, W. A. & Skid, W. M. UFF, a full periodic table force field for molecular mechanics and molecular dynamics simulations. J. Am. Chem. Soc. 114, 10024–10035 (1992). (10.1021/ja00051a040) / J. Am. Chem. Soc. by AK Rappé (1992)
  29. Hirschfelder, J. O., Curtiss, C. F. & Bird, R. B. Molecular Theory of Gases and Liquids 2nd edn (Wiley, 1964). / Molecular Theory of Gases and Liquids by JO Hirschfelder (1964)
  30. Fletcher, A. J., Cussen, E. J., Bradshaw, D., Rosseinsky, M. J. & Thomas, K. M. Adsorption of gases and vapors on nanoporous Ni2(4,4′-Bipyridine)3(NO3)4 metal–organic framework materials templated with methanol and ethanol: structural effects in adsorption kinetics. J. Am. Chem. Soc. 126, 9750–9759 (2004). (10.1021/ja0490267) / J. Am. Chem. Soc. by AJ Fletcher (2004)
  31. Chen, B. et al. Surface interactions and quantum kinetic molecular sieving for H2 and D2 adsorption on a mixed metal–organic framework material. J. Am. Chem. Soc. 130, 6411–6423 (2008). (10.1021/ja710144k) / J. Am. Chem. Soc. by B Chen (2008)
  32. Jhi, S. H. A theoretical study of nanoporous organic molecules for hydrogen storage. Microporous Mesoporous Mater. 89, 138–142 (2006). (10.1016/j.micromeso.2005.10.007) / Microporous Mesoporous Mater. by SH Jhi (2006)
  33. Anil Kumar, A. V., Jobic, H. & Bhatia, S. K. Quantum effect induced kinetic molecular sieving of hydrogen and deuterium in microporous materials. Adsorption 13, 501–508 (2007). (10.1007/s10450-007-9022-8) / Adsorption by AV Anil Kumar (2007)
  34. CRC Handbook of Chemistry and Physics 74th edn (CRC, 1993).
  35. Yang, S. et al. Enhancement of H2 adsorption in Li+-exchanged coordination framework materials. Chem. Commun. 6108–6110 (2008). (10.1039/b814155j)
  36. Hafizovic, J. et al. The inconsistency in adsorption properties and powder XRD data of MOF-5 is rationalized by framework interpenetration and the presence of organic and inorganic species in the nanocavities. J. Am. Chem. Soc. 129, 3612–3620 (2007). (10.1021/ja0675447) / J. Am. Chem. Soc. by J Hafizovic (2007)
  37. Cole, J. H. et al. Thermodynamics of high temperature adsorption of some permanent gases by porous carbons. J. Chem. Soc. Faraday Trans. 70, 2154–2169 (1974). (10.1039/f19747002154) / J. Chem. Soc. Faraday Trans. by JH Cole (1974)
  38. Nouar, F, Eckert, J., Eubank, J. F., Forster, P. & Eddaoudi, M. Zeolite-like metal–organic frameworks (ZMOFs) as hydrogen storage platform: lithium and magnesium ion-exchange and H2-(rho-ZMOF) interaction studies. J. Am. Chem. Soc. 131, 2864–2870 (2009). (10.1021/ja807229a) / J. Am. Chem. Soc. by F Nouar (2009)
  39. Himsl, D., Wallacher, D. & Hartmann, M. Improving the hydrogen-adsorption properties of a hydroxy-modified MIL-53(Al) structural analogue by lithium doping. Angew. Chem. Int. Ed. 48, 4639–4642 (2009). (10.1002/anie.200806203) / Angew. Chem. Int. Ed. by D Himsl (2009)
Dates
Type When
Created 15 years, 11 months ago (Aug. 24, 2009, 3:59 a.m.)
Deposited 2 years, 3 months ago (May 18, 2023, 3:21 p.m.)
Indexed 2 weeks, 2 days ago (Aug. 5, 2025, 8:19 a.m.)
Issued 15 years, 11 months ago (Aug. 24, 2009)
Published 15 years, 11 months ago (Aug. 24, 2009)
Published Online 15 years, 11 months ago (Aug. 24, 2009)
Published Print 15 years, 11 months ago (Sept. 1, 2009)
Funders 0

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@article{Yang_2009, title={Cation-induced kinetic trapping and enhanced hydrogen adsorption in a modulated anionic metal–organic framework}, volume={1}, ISSN={1755-4349}, url={http://dx.doi.org/10.1038/nchem.333}, DOI={10.1038/nchem.333}, number={6}, journal={Nature Chemistry}, publisher={Springer Science and Business Media LLC}, author={Yang, Sihai and Lin, Xiang and Blake, Alexander J. and Walker, Gavin S. and Hubberstey, Peter and Champness, Neil R. and Schröder, Martin}, year={2009}, month=aug, pages={487–493} }