DOI: 10.1038/nature06044. Vitrification of a monatomic metallic liquid

Vitrification of a monatomic metallic liquid

10.1038/nature06044

Crossref journal-article

Springer Science and Business Media LLC

Nature (297)

Bibliography

Bhat, M. H., Molinero, V., Soignard, E., Solomon, V. C., Sastry, S., Yarger, J. L., & Angell, C. A. (2007). Vitrification of a monatomic metallic liquid. Nature, 448(7155), 787â790.

Authors 7

M. H. Bhat (first)
V. Molinero (additional)
E. Soignard (additional)
V. C. Solomon (additional)
S. Sastry (additional)
J. L. Yarger (additional)
C. A. Angell (additional)

References 36 Referenced 203

Privalko, Y. Excess entropies and related quantities in glass-forming liquids. J. Phys. Chem. 84, 3307–3312 (1980) (10.1021/j100461a034) / J. Phys. Chem. by Y Privalko (1980)
Martinez, L. M. & Angell, C. A. A thermodynamic connection to the fragility of glass-forming liquids. Nature 410, 663–667 (2001) (10.1038/35070517) / Nature by LM Martinez (2001)
Johnson, W. L. Bulk glass-forming metallic alloys: science and technology. Mater. Res. Soc. Bull. 24, 42–50 (1999) (10.1557/S0883769400053252) / Mater. Res. Soc. Bull. by WL Johnson (1999)
Wang, W. H., Lewandowski, J. J. & Greer, A. L. Understanding the glass-forming ability of Cu50Zr50 alloys in terms of a metastable eutectic. J. Mater. Res. 20, 2307–2313 (2005) (10.1557/jmr.2005.0302) / J. Mater. Res. by WH Wang (2005)
Molinero, V., Sastry, S. & Angell, C. A. Tuning of tetrahedrality in a silicon potential yields a series of monatomic (metal-like) glasse formers of very high fragility. Phys. Rev. Lett. 97, 075701 (2006) (10.1103/PhysRevLett.97.075701) / Phys. Rev. Lett. by V Molinero (2006)
Cohen, M. H. & Turnbull, D. Composition requirements for glass formation in metallic and ionic systems. Nature 189, 131–132 (1961) (10.1038/189131b0) / Nature by MH Cohen (1961)
van Ketel, W., Das, C. & Frenkel, D. Structural arrest in an ideal gas. Phys. Rev. Lett. 94, 135703 (2005) (10.1103/PhysRevLett.94.135703) / Phys. Rev. Lett. by W van Ketel (2005)
Hilsch, R. in Non-Crystalline Solids (ed. Frechette, V. D.) 348 (J. Wiley and Sons, New York, 1960) / Non-Crystalline Solids by R Hilsch (1960)
Chathoth, S. M., Meyer, A., Koza, M. M. & Juranyi, F. Atomic diffusion in liquid Ni, NiP, PdNiP, and PdNiCuP alloys. Appl. Phys. Lett. 85, 4881–4883 (2004) (10.1063/1.1825617) / Appl. Phys. Lett. by SM Chathoth (2004)
Wachtel, E. et al. Magnetic-susceptibility and DSC study of the crystallization of melt-quenched Ni-P amorphous-alloys. Mater. Sci. Eng. A 133, 196–199 (1991) (10.1016/0921-5093(91)90048-R) / Mater. Sci. Eng. A by E Wachtel (1991)
Stillinger, F. H. & Weber, T. A. Computer-simulation of local order in condensed phases of silicon. Phys. Rev. B 31, 5262–5271 (1985) (10.1103/PhysRevB.31.5262) / Phys. Rev. B by FH Stillinger (1985)
Angell, C. A., Borick, S. & Grabow, M. Glass transitions and first order liquid-metal-to-semiconductor transitions in 4–5–6 covalent systems. J. Non-Cryst. Solids 207, 463–471 (1996) (10.1016/S0022-3093(96)00261-X) / J. Non-Cryst. Solids by CA Angell (1996)
Brazhkin, V. V., Larchev, V. I., Popova, S. V. & Skrotskaya, G. G. The influence of high pressure on the disordering of the crystal structure of solids rapidly quenched from the melt. Phys. Scr. 39, 338–340 (1989) (10.1088/0031-8949/39/3/012) / Phys. Scr. by VV Brazhkin (1989)
Tanaka, H. Simple view of waterlike anomalies of atomic liquids with directional bonding. Phys. Rev. B 66, 064202 (2002) (10.1103/PhysRevB.66.064202) / Phys. Rev. B by H Tanaka (2002)
Koga, J., Nishio, K., Yamaguchi, T. & Yonezawa, F. Tight-binding molecular dynamics study on the structural change of amorphous germanium with the increase of density. J. Phys. Soc. Jpn 73, 388–396 (2004) (10.1143/JPSJ.73.388) / J. Phys. Soc. Jpn by J Koga (2004)
Schnydersy, H. S. & Van Zytveldz, J. B. Electrical resistivity and thermopower of liquid Ge and Si. J. Phys. Condens. Matter 8, 10875–10883 (1996) (10.1088/0953-8984/8/50/013) / J. Phys. Condens. Matter by HS Schnydersy (1996)
Zhang, F. X. & Wang, W. K. Microstructure of germanium quenched from the undercooled melt at high-pressures. Appl. Phys. Lett. 67, 617–619 (1995) (10.1063/1.115407) / Appl. Phys. Lett. by FX Zhang (1995)
Brazhkin, V. V., Lyapin, A. G., Popova, S. V. & Voloshin, R. N. Non-equilibrium phase transitions and amorphization in Si, Si/GaAs, Ge, and Ge/GaSb at the decompression of high-pressure phases. Phys. Rev. B 51, 7549–7554 (1995) (10.1103/PhysRevB.51.7549) / Phys. Rev. B by VV Brazhkin (1995)
Salmon, P. S. A. Neutron-diffraction study on the structure of liquid germanium. J. Phys. F 18, 2345–2352 (1988) (10.1088/0305-4608/18/11/007) / J. Phys. F by PSA Salmon (1988)
Ankele, J., Mayer, J., Lamparter, P. & Steeb, S. Structure factor of amorphous-germanium by quantitative electron-diffraction. J. Non-Cryst. Solids 193, 679–682 (1995) (10.1016/0022-3093(95)00423-8) / J. Non-Cryst. Solids by J Ankele (1995)
Etherington, G. et al. A neutron-diffraction study of the structure of evaporated amorphous-germanium. J. Non-Cryst. Solids 48, 265–289 (1982) (10.1016/0022-3093(82)90165-X) / J. Non-Cryst. Solids by G Etherington (1982)
Benmore, C. J. et al. Intermediate range chemical ordering in amorphous and liquid water, Si, and Ge. Phys. Rev. B 72, 132201(4) (2005) (10.1103/PhysRevB.72.132201) / Phys. Rev. B by CJ Benmore (2005)
Aptekar, L. I. Phase transitions in non-crystalline germanium and silicon. Sov. Phys. Dokl. 24, 993–995 (1979) / Sov. Phys. Dokl. by LI Aptekar (1979)
Voronin, G. A. et al. In situ X-ray diffraction study of germanium at pressures up to 11 GPa and temperatures up to 950 K. J. Phys. Chem. Solids 64, 2113–2119 (2003) (10.1016/S0022-3697(03)00278-6) / J. Phys. Chem. Solids by GA Voronin (2003)
Li, D. & Herbach, D. M. Containerless solidification of germanium by electromagnetic levitiatioins and in a drop-tube. J. Mater. Sci. 32, 1437–1442 (1997) (10.1023/A:1018593615171) / J. Mater. Sci. by D Li (1997)
Sastry, S. & Angell, C. A. Liquid–liquid phase transition in supercooled liquid silicon. Nature Mater. 2, 739–743 (2003) (10.1038/nmat994) / Nature Mater. by S Sastry (2003)
Ponyatovsky, G. G. A thermodynamic approach to T-P phase diagrams of substances in liquid and amorphous states. J. Phys. Condens. Matter 15, 6123–6141 (2003) (10.1088/0953-8984/15/36/304) / J. Phys. Condens. Matter by GG Ponyatovsky (2003)
Mishima, O. Reversible transition between two H2O amorphs at ∼0.2 GPa and ∼135 K. J. Chem. Phys. 100, 5910–5919 (1991) (10.1063/1.467103) / J. Chem. Phys. by O Mishima (1991)
Aasland, S. & McMillan, P. F. Density-driven liquid–liquid phase-separation in the system Al2O3–Y2O3 . Nature 369, 633–636 (1994) (10.1038/369633a0) / Nature by S Aasland (1994)
Kurita, R. & Tanaka, H. Critical-like phenomena associated with liquid-liquid transition in a molecular liquid. Science 306, 845–848 (2004) (10.1126/science.1103073) / Science by R Kurita (2004)
Spaepen, F. & Turnbull, D. in Laser-Solid Interactions and Laser Processing 1978 (eds Ferris, S. D., Leamy, H. J. & Poate, J.). AIP Conf. Proc. 50, 73–83 (1979) / Laser-Solid Interactions and Laser Processing 1978 by F Spaepen (1979)
Stanley, H. E. et al. The puzzling behavior of water at very low temperature. Phys. Chem. Chem. Phys. 2, 1551–1558 (2000) (10.1039/b000058m) / Phys. Chem. Chem. Phys. by HE Stanley (2000)
Rez, D., Rez, P. & Grant, I. Dirac-Fock calculations of X-ray scattering factors and contributions to the mean inner potential for electron scattering. Acta Crystallogr. A 50, 481–497 (1994) (10.1107/S0108767393013200) / Acta Crystallogr. A by D Rez (1994)
Plimpton, S. Fast parallel algorithms for short-range molecular-dynamics. J. Comput. Phys. 117, 1–19 (1995) (10.1006/jcph.1995.1039) / J. Comput. Phys. by S Plimpton (1995)
Grabow, M. H. & Gilmer, G. H. Thin-film growth modes, wetting and cluster nucleation. Surf. Sci. 194, 333–346 (1988) (10.1016/0039-6028(88)90858-8) / Surf. Sci. by MH Grabow (1988)
Yu, W. B. & Stroud, D. Molecular-dynamics study of surface segregation in liquid semiconductor alloys. Phys. Rev. B 56, 12243–12249 (1997) (10.1103/PhysRevB.56.12243) / Phys. Rev. B by WB Yu (1997)

Dates

Type	When
Created	18 years ago (Aug. 15, 2007, 1:09 p.m.)
Deposited	3 years, 4 months ago (April 12, 2022, 7:11 a.m.)
Indexed	20 hours, 41 minutes ago (Aug. 20, 2025, 8:59 a.m.)
Issued	18 years ago (Aug. 16, 2007)
Published	18 years ago (Aug. 16, 2007)
Published Online	18 years ago (Aug. 16, 2007)
Published Print	18 years ago (Aug. 16, 2007)

Funders 0

None

BibTeX

@article{Bhat_2007, title={Vitrification of a monatomic metallic liquid}, volume={448}, ISSN={1476-4687}, url={http://dx.doi.org/10.1038/nature06044}, DOI={10.1038/nature06044}, number={7155}, journal={Nature}, publisher={Springer Science and Business Media LLC}, author={Bhat, M. H. and Molinero, V. and Soignard, E. and Solomon, V. C. and Sastry, S. and Yarger, J. L. and Angell, C. A.}, year={2007}, month=aug, pages={787–790} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        20
      ]
    ],
    "date-time": "2025-08-20T12:59:42Z",
    "timestamp": 1755694782771
  },
  "reference-count": 36,
  "publisher": "Springer Science and Business Media LLC",
  "issue": "7155",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2007,
            8,
            16
          ]
        ],
        "date-time": "2007-08-16T00:00:00Z",
        "timestamp": 1187222400000
      },
      "content-version": "tdm",
      "delay-in-days": 0,
      "URL": "https://www.springer.com/tdm"
    },
    {
      "start": {
        "date-parts": [
          [
            2007,
            8,
            16
          ]
        ],
        "date-time": "2007-08-16T00:00:00Z",
        "timestamp": 1187222400000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "https://www.springer.com/tdm"
    }
  ],
  "content-domain": {
    "domain": [
      "link.springer.com"
    ],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2007,
        8,
        16
      ]
    ]
  },
  "DOI": "10.1038/nature06044",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2007,
        8,
        15
      ]
    ],
    "date-time": "2007-08-15T17:09:06Z",
    "timestamp": 1187197746000
  },
  "page": "787-790",
  "update-policy": "http://dx.doi.org/10.1007/springer_crossmark_policy",
  "source": "Crossref",
  "is-referenced-by-count": 203,
  "title": "Vitrification of a monatomic metallic liquid",
  "prefix": "10.1038",
  "volume": "448",
  "author": [
    {
      "given": "M. H.",
      "family": "Bhat",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "V.",
      "family": "Molinero",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "E.",
      "family": "Soignard",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "V. C.",
      "family": "Solomon",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "S.",
      "family": "Sastry",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "J. L.",
      "family": "Yarger",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "C. A.",
      "family": "Angell",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "297",
  "published-online": {
    "date-parts": [
      [
        2007,
        8,
        16
      ]
    ]
  },
  "reference": [
    {
      "key": "BFnature06044_CR1",
      "doi-asserted-by": "publisher",
      "first-page": "3307",
      "DOI": "10.1021/j100461a034",
      "volume": "84",
      "author": "Y Privalko",
      "year": "1980",
      "unstructured": "Privalko, Y. Excess entropies and related quantities in glass-forming liquids. J. Phys. Chem. 84, 3307\u20133312 (1980)",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "BFnature06044_CR2",
      "doi-asserted-by": "publisher",
      "first-page": "663",
      "DOI": "10.1038/35070517",
      "volume": "410",
      "author": "LM Martinez",
      "year": "2001",
      "unstructured": "Martinez, L. M. & Angell, C. A. A thermodynamic connection to the fragility of glass-forming liquids. Nature 410, 663\u2013667 (2001)",
      "journal-title": "Nature"
    },
    {
      "key": "BFnature06044_CR3",
      "doi-asserted-by": "publisher",
      "first-page": "42",
      "DOI": "10.1557/S0883769400053252",
      "volume": "24",
      "author": "WL Johnson",
      "year": "1999",
      "unstructured": "Johnson, W. L. Bulk glass-forming metallic alloys: science and technology. Mater. Res. Soc. Bull. 24, 42\u201350 (1999)",
      "journal-title": "Mater. Res. Soc. Bull."
    },
    {
      "key": "BFnature06044_CR4",
      "doi-asserted-by": "publisher",
      "first-page": "2307",
      "DOI": "10.1557/jmr.2005.0302",
      "volume": "20",
      "author": "WH Wang",
      "year": "2005",
      "unstructured": "Wang, W. H., Lewandowski, J. J. & Greer, A. L. Understanding the glass-forming ability of Cu50Zr50 alloys in terms of a metastable eutectic. J. Mater. Res. 20, 2307\u20132313 (2005)",
      "journal-title": "J. Mater. Res."
    },
    {
      "key": "BFnature06044_CR5",
      "doi-asserted-by": "publisher",
      "first-page": "075701",
      "DOI": "10.1103/PhysRevLett.97.075701",
      "volume": "97",
      "author": "V Molinero",
      "year": "2006",
      "unstructured": "Molinero, V., Sastry, S. & Angell, C. A. Tuning of tetrahedrality in a silicon potential yields a series of monatomic (metal-like) glasse formers of very high fragility. Phys. Rev. Lett. 97, 075701 (2006)",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "BFnature06044_CR6",
      "doi-asserted-by": "publisher",
      "first-page": "131",
      "DOI": "10.1038/189131b0",
      "volume": "189",
      "author": "MH Cohen",
      "year": "1961",
      "unstructured": "Cohen, M. H. & Turnbull, D. Composition requirements for glass formation in metallic and ionic systems. Nature 189, 131\u2013132 (1961)",
      "journal-title": "Nature"
    },
    {
      "key": "BFnature06044_CR7",
      "doi-asserted-by": "publisher",
      "first-page": "135703",
      "DOI": "10.1103/PhysRevLett.94.135703",
      "volume": "94",
      "author": "W van Ketel",
      "year": "2005",
      "unstructured": "van Ketel, W., Das, C. & Frenkel, D. Structural arrest in an ideal gas. Phys. Rev. Lett. 94, 135703 (2005)",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "BFnature06044_CR8",
      "first-page": "348",
      "volume-title": "Non-Crystalline Solids",
      "author": "R Hilsch",
      "year": "1960",
      "unstructured": "Hilsch, R. in Non-Crystalline Solids (ed. Frechette, V. D.) 348 (J. Wiley and Sons, New York, 1960)"
    },
    {
      "key": "BFnature06044_CR9",
      "doi-asserted-by": "publisher",
      "first-page": "4881",
      "DOI": "10.1063/1.1825617",
      "volume": "85",
      "author": "SM Chathoth",
      "year": "2004",
      "unstructured": "Chathoth, S. M., Meyer, A., Koza, M. M. & Juranyi, F. Atomic diffusion in liquid Ni, NiP, PdNiP, and PdNiCuP alloys. Appl. Phys. Lett. 85, 4881\u20134883 (2004)",
      "journal-title": "Appl. Phys. Lett."
    },
    {
      "key": "BFnature06044_CR10",
      "doi-asserted-by": "publisher",
      "first-page": "196",
      "DOI": "10.1016/0921-5093(91)90048-R",
      "volume": "133",
      "author": "E Wachtel",
      "year": "1991",
      "unstructured": "Wachtel, E. et al. Magnetic-susceptibility and DSC study of the crystallization of melt-quenched Ni-P amorphous-alloys. Mater. Sci. Eng. A 133, 196\u2013199 (1991)",
      "journal-title": "Mater. Sci. Eng. A"
    },
    {
      "key": "BFnature06044_CR11",
      "doi-asserted-by": "publisher",
      "first-page": "5262",
      "DOI": "10.1103/PhysRevB.31.5262",
      "volume": "31",
      "author": "FH Stillinger",
      "year": "1985",
      "unstructured": "Stillinger, F. H. & Weber, T. A. Computer-simulation of local order in condensed phases of silicon. Phys. Rev. B 31, 5262\u20135271 (1985)",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "BFnature06044_CR12",
      "doi-asserted-by": "publisher",
      "first-page": "463",
      "DOI": "10.1016/S0022-3093(96)00261-X",
      "volume": "207",
      "author": "CA Angell",
      "year": "1996",
      "unstructured": "Angell, C. A., Borick, S. & Grabow, M. Glass transitions and first order liquid-metal-to-semiconductor transitions in 4\u20135\u20136 covalent systems. J. Non-Cryst. Solids 207, 463\u2013471 (1996)",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "BFnature06044_CR13",
      "doi-asserted-by": "publisher",
      "first-page": "338",
      "DOI": "10.1088/0031-8949/39/3/012",
      "volume": "39",
      "author": "VV Brazhkin",
      "year": "1989",
      "unstructured": "Brazhkin, V. V., Larchev, V. I., Popova, S. V. & Skrotskaya, G. G. The influence of high pressure on the disordering of the crystal structure of solids rapidly quenched from the melt. Phys. Scr. 39, 338\u2013340 (1989)",
      "journal-title": "Phys. Scr."
    },
    {
      "key": "BFnature06044_CR14",
      "doi-asserted-by": "publisher",
      "first-page": "064202",
      "DOI": "10.1103/PhysRevB.66.064202",
      "volume": "66",
      "author": "H Tanaka",
      "year": "2002",
      "unstructured": "Tanaka, H. Simple view of waterlike anomalies of atomic liquids with directional bonding. Phys. Rev. B 66, 064202 (2002)",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "BFnature06044_CR15",
      "doi-asserted-by": "publisher",
      "first-page": "388",
      "DOI": "10.1143/JPSJ.73.388",
      "volume": "73",
      "author": "J Koga",
      "year": "2004",
      "unstructured": "Koga, J., Nishio, K., Yamaguchi, T. & Yonezawa, F. Tight-binding molecular dynamics study on the structural change of amorphous germanium with the increase of density. J. Phys. Soc. Jpn 73, 388\u2013396 (2004)",
      "journal-title": "J. Phys. Soc. Jpn"
    },
    {
      "key": "BFnature06044_CR16",
      "doi-asserted-by": "publisher",
      "first-page": "10875",
      "DOI": "10.1088/0953-8984/8/50/013",
      "volume": "8",
      "author": "HS Schnydersy",
      "year": "1996",
      "unstructured": "Schnydersy, H. S. & Van Zytveldz, J. B. Electrical resistivity and thermopower of liquid Ge and Si. J. Phys. Condens. Matter 8, 10875\u201310883 (1996)",
      "journal-title": "J. Phys. Condens. Matter"
    },
    {
      "key": "BFnature06044_CR17",
      "doi-asserted-by": "publisher",
      "first-page": "617",
      "DOI": "10.1063/1.115407",
      "volume": "67",
      "author": "FX Zhang",
      "year": "1995",
      "unstructured": "Zhang, F. X. & Wang, W. K. Microstructure of germanium quenched from the undercooled melt at high-pressures. Appl. Phys. Lett. 67, 617\u2013619 (1995)",
      "journal-title": "Appl. Phys. Lett."
    },
    {
      "key": "BFnature06044_CR18",
      "doi-asserted-by": "publisher",
      "first-page": "7549",
      "DOI": "10.1103/PhysRevB.51.7549",
      "volume": "51",
      "author": "VV Brazhkin",
      "year": "1995",
      "unstructured": "Brazhkin, V. V., Lyapin, A. G., Popova, S. V. & Voloshin, R. N. Non-equilibrium phase transitions and amorphization in Si, Si/GaAs, Ge, and Ge/GaSb at the decompression of high-pressure phases. Phys. Rev. B 51, 7549\u20137554 (1995)",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "BFnature06044_CR19",
      "doi-asserted-by": "publisher",
      "first-page": "2345",
      "DOI": "10.1088/0305-4608/18/11/007",
      "volume": "18",
      "author": "PSA Salmon",
      "year": "1988",
      "unstructured": "Salmon, P. S. A. Neutron-diffraction study on the structure of liquid germanium. J. Phys. F 18, 2345\u20132352 (1988)",
      "journal-title": "J. Phys. F"
    },
    {
      "key": "BFnature06044_CR20",
      "doi-asserted-by": "publisher",
      "first-page": "679",
      "DOI": "10.1016/0022-3093(95)00423-8",
      "volume": "193",
      "author": "J Ankele",
      "year": "1995",
      "unstructured": "Ankele, J., Mayer, J., Lamparter, P. & Steeb, S. Structure factor of amorphous-germanium by quantitative electron-diffraction. J. Non-Cryst. Solids 193, 679\u2013682 (1995)",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "BFnature06044_CR21",
      "doi-asserted-by": "publisher",
      "first-page": "265",
      "DOI": "10.1016/0022-3093(82)90165-X",
      "volume": "48",
      "author": "G Etherington",
      "year": "1982",
      "unstructured": "Etherington, G. et al. A neutron-diffraction study of the structure of evaporated amorphous-germanium. J. Non-Cryst. Solids 48, 265\u2013289 (1982)",
      "journal-title": "J. Non-Cryst. Solids"
    },
    {
      "key": "BFnature06044_CR22",
      "doi-asserted-by": "publisher",
      "first-page": "132201(4)",
      "DOI": "10.1103/PhysRevB.72.132201",
      "volume": "72",
      "author": "CJ Benmore",
      "year": "2005",
      "unstructured": "Benmore, C. J. et al. Intermediate range chemical ordering in amorphous and liquid water, Si, and Ge. Phys. Rev. B 72, 132201(4) (2005)",
      "journal-title": "Phys. Rev. B"
    },
    {
      "key": "BFnature06044_CR23",
      "first-page": "993",
      "volume": "24",
      "author": "LI Aptekar",
      "year": "1979",
      "unstructured": "Aptekar, L. I. Phase transitions in non-crystalline germanium and silicon. Sov. Phys. Dokl. 24, 993\u2013995 (1979)",
      "journal-title": "Sov. Phys. Dokl."
    },
    {
      "key": "BFnature06044_CR24",
      "doi-asserted-by": "publisher",
      "first-page": "2113",
      "DOI": "10.1016/S0022-3697(03)00278-6",
      "volume": "64",
      "author": "GA Voronin",
      "year": "2003",
      "unstructured": "Voronin, G. A. et al. In situ X-ray diffraction study of germanium at pressures up to 11 GPa and temperatures up to 950 K. J. Phys. Chem. Solids 64, 2113\u20132119 (2003)",
      "journal-title": "J. Phys. Chem. Solids"
    },
    {
      "key": "BFnature06044_CR25",
      "doi-asserted-by": "publisher",
      "first-page": "1437",
      "DOI": "10.1023/A:1018593615171",
      "volume": "32",
      "author": "D Li",
      "year": "1997",
      "unstructured": "Li, D. & Herbach, D. M. Containerless solidification of germanium by electromagnetic levitiatioins and in a drop-tube. J. Mater. Sci. 32, 1437\u20131442 (1997)",
      "journal-title": "J. Mater. Sci."
    },
    {
      "key": "BFnature06044_CR26",
      "doi-asserted-by": "publisher",
      "first-page": "739",
      "DOI": "10.1038/nmat994",
      "volume": "2",
      "author": "S Sastry",
      "year": "2003",
      "unstructured": "Sastry, S. & Angell, C. A. Liquid\u2013liquid phase transition in supercooled liquid silicon. Nature Mater. 2, 739\u2013743 (2003)",
      "journal-title": "Nature Mater."
    },
    {
      "key": "BFnature06044_CR27",
      "doi-asserted-by": "publisher",
      "first-page": "6123",
      "DOI": "10.1088/0953-8984/15/36/304",
      "volume": "15",
      "author": "GG Ponyatovsky",
      "year": "2003",
      "unstructured": "Ponyatovsky, G. G. A thermodynamic approach to T-P phase diagrams of substances in liquid and amorphous states. J. Phys. Condens. Matter 15, 6123\u20136141 (2003)",
      "journal-title": "J. Phys. Condens. Matter"
    },
    {
      "key": "BFnature06044_CR28",
      "doi-asserted-by": "publisher",
      "first-page": "5910",
      "DOI": "10.1063/1.467103",
      "volume": "100",
      "author": "O Mishima",
      "year": "1991",
      "unstructured": "Mishima, O. Reversible transition between two H2O amorphs at \u223c0.2 GPa and \u223c135 K. J. Chem. Phys. 100, 5910\u20135919 (1991)",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "BFnature06044_CR29",
      "doi-asserted-by": "publisher",
      "first-page": "633",
      "DOI": "10.1038/369633a0",
      "volume": "369",
      "author": "S Aasland",
      "year": "1994",
      "unstructured": "Aasland, S. & McMillan, P. F. Density-driven liquid\u2013liquid phase-separation in the system Al2O3\u2013Y2O3 . Nature 369, 633\u2013636 (1994)",
      "journal-title": "Nature"
    },
    {
      "key": "BFnature06044_CR30",
      "doi-asserted-by": "publisher",
      "first-page": "845",
      "DOI": "10.1126/science.1103073",
      "volume": "306",
      "author": "R Kurita",
      "year": "2004",
      "unstructured": "Kurita, R. & Tanaka, H. Critical-like phenomena associated with liquid-liquid transition in a molecular liquid. Science 306, 845\u2013848 (2004)",
      "journal-title": "Science"
    },
    {
      "key": "BFnature06044_CR31",
      "first-page": "73",
      "volume-title": "Laser-Solid Interactions and Laser Processing 1978",
      "author": "F Spaepen",
      "year": "1979",
      "unstructured": "Spaepen, F. & Turnbull, D. in Laser-Solid Interactions and Laser Processing 1978 (eds Ferris, S. D., Leamy, H. J. & Poate, J.). AIP Conf. Proc. 50, 73\u201383 (1979)"
    },
    {
      "key": "BFnature06044_CR32",
      "doi-asserted-by": "publisher",
      "first-page": "1551",
      "DOI": "10.1039/b000058m",
      "volume": "2",
      "author": "HE Stanley",
      "year": "2000",
      "unstructured": "Stanley, H. E. et al. The puzzling behavior of water at very low temperature. Phys. Chem. Chem. Phys. 2, 1551\u20131558 (2000)",
      "journal-title": "Phys. Chem. Chem. Phys."
    },
    {
      "key": "BFnature06044_CR33",
      "doi-asserted-by": "publisher",
      "first-page": "481",
      "DOI": "10.1107/S0108767393013200",
      "volume": "50",
      "author": "D Rez",
      "year": "1994",
      "unstructured": "Rez, D., Rez, P. & Grant, I. Dirac-Fock calculations of X-ray scattering factors and contributions to the mean inner potential for electron scattering. Acta Crystallogr. A 50, 481\u2013497 (1994)",
      "journal-title": "Acta Crystallogr. A"
    },
    {
      "key": "BFnature06044_CR34",
      "doi-asserted-by": "publisher",
      "first-page": "1",
      "DOI": "10.1006/jcph.1995.1039",
      "volume": "117",
      "author": "S Plimpton",
      "year": "1995",
      "unstructured": "Plimpton, S. Fast parallel algorithms for short-range molecular-dynamics. J. Comput. Phys. 117, 1\u201319 (1995)",
      "journal-title": "J. Comput. Phys."
    },
    {
      "key": "BFnature06044_CR35",
      "doi-asserted-by": "publisher",
      "first-page": "333",
      "DOI": "10.1016/0039-6028(88)90858-8",
      "volume": "194",
      "author": "MH Grabow",
      "year": "1988",
      "unstructured": "Grabow, M. H. & Gilmer, G. H. Thin-film growth modes, wetting and cluster nucleation. Surf. Sci. 194, 333\u2013346 (1988)",
      "journal-title": "Surf. Sci."
    },
    {
      "key": "BFnature06044_CR36",
      "doi-asserted-by": "publisher",
      "first-page": "12243",
      "DOI": "10.1103/PhysRevB.56.12243",
      "volume": "56",
      "author": "WB Yu",
      "year": "1997",
      "unstructured": "Yu, W. B. & Stroud, D. Molecular-dynamics study of surface segregation in liquid semiconductor alloys. Phys. Rev. B 56, 12243\u201312249 (1997)",
      "journal-title": "Phys. Rev. B"
    }
  ],
  "container-title": "Nature",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://www.nature.com/articles/nature06044",
      "content-type": "text/html",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://www.nature.com/articles/nature06044.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://www.nature.com/articles/nature06044.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2022,
        4,
        12
      ]
    ],
    "date-time": "2022-04-12T11:11:46Z",
    "timestamp": 1649761906000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://www.nature.com/articles/nature06044"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2007,
        8,
        16
      ]
    ]
  },
  "references-count": 36,
  "journal-issue": {
    "issue": "7155",
    "published-print": {
      "date-parts": [
        [
          2007,
          8,
          16
        ]
      ]
    }
  },
  "alternative-id": [
    "BFnature06044"
  ],
  "URL": "http://dx.doi.org/10.1038/nature06044",
  "relation": {},
  "ISSN": [
    "0028-0836",
    "1476-4687"
  ],
  "subject": [],
  "container-title-short": "Nature",
  "published": {
    "date-parts": [
      [
        2007,
        8,
        16
      ]
    ]
  },
  "assertion": [
    {
      "value": "5 February 2007",
      "order": 1,
      "name": "received",
      "label": "Received",
      "group": {
        "name": "ArticleHistory",
        "label": "Article History"
      }
    },
    {
      "value": "21 June 2007",
      "order": 2,
      "name": "accepted",
      "label": "Accepted",
      "group": {
        "name": "ArticleHistory",
        "label": "Article History"
      }
    },
    {
      "value": "16 August 2007",
      "order": 3,
      "name": "first_online",
      "label": "First Online",
      "group": {
        "name": "ArticleHistory",
        "label": "Article History"
      }
    },
    {
      "value": "Reprints and permissions information is available at ExternalRef removed. The authors declare no competing financial interests.",
      "order": 1,
      "name": "Ethics",
      "group": {
        "name": "EthicsHeading",
        "label": "Competing interests"
      }
    }
  ]
}