DOI: 10.1038/416155a. Formation of isomorphic Ir3+ and Ir4+ octamers and spin dimerization in the spinel CuIr2S4

Formation of isomorphic Ir3+ and Ir4+ octamers and spin dimerization in the spinel CuIr2S4

10.1038/416155a

Crossref journal-article

Springer Science and Business Media LLC

Nature (297)

Bibliography

Radaelli, P. G., Horibe, Y., Gutmann, M. J., Ishibashi, H., Chen, C. H., Ibberson, R. M., Koyama, Y., Hor, Y.-S., Kiryukhin, V., & Cheong, S.-W. (2002). Formation of isomorphic Ir3+ and Ir4+ octamers and spin dimerization in the spinel CuIr2S4. Nature, 416(6877), 155â158.

Authors 10

Paolo G. Radaelli (first)
Y. Horibe (additional)
Matthias J. Gutmann (additional)
Hiroki Ishibashi (additional)
C. H. Chen (additional)
Richard M. Ibberson (additional)
Y. Koyama (additional)
Yew-San Hor (additional)
Valery Kiryukhin (additional)
Sang-Wook Cheong (additional)

References 23 Referenced 336

Bragg, W. H. The structure of magnetite and the spinels. Nature 95, 561–561 (1915). (10.1038/095561a0) / Nature by WH Bragg (1915)
Iizumi, M. et al. Structure of magnetite (Fe3O4) below the Verwey transition temperature. Acta Crystallogr. 38, 2121–2133 (1982). (10.1107/S0567740882008176) / Acta Crystallogr. by M Iizumi (1982)
Furubayashi, T., Matsumoto, T., Hagino, T. & Nagata, S. Structural and magnetic studies of metal-insulator transition in thiospinel CuIr2S4. J. Phys. Soc. Jpn 63, 3333–3339 (1994). (10.1143/JPSJ.63.3333) / J. Phys. Soc. Jpn by T Furubayashi (1994)
Matsuno, J. et al. Photoemission study of the metal-insulator transition in CuIr2S4. Phys. Rev. B 55, R15979–R15982 (1997). (10.1103/PhysRevB.55.R15979) / Phys. Rev. B by J Matsuno (1997)
Nagata, S. et al. Metal-insulator transition in the spinel-type CuIr2(S1-xSex)4 system. Phys. Rev. B 58, 6844–6854 (1998). (10.1103/PhysRevB.58.6844) / Phys. Rev. B by S Nagata (1998)
Matsumoto, N., Endoh, R., Nagata, S., Furubayashi, T. & Matsumoto, T. Metal-insulator transition and superconductivity in the spinel-type Cu(Ir1-xRhx)2S4 system. Phys. Rev. B 60, 5258–5265 (1999). (10.1103/PhysRevB.60.5258) / Phys. Rev. B by N Matsumoto (1999)
Burkov, A. T. et al. Anomalous resistivity and thermopower of the spinel-type compounds CuIr2S4 and CuIr2Se4. Phys. Rev. B 61, 10049–10056 (2000). (10.1103/PhysRevB.61.10049) / Phys. Rev. B by AT Burkov (2000)
Bray, J. W. et al. Observation of a spin-Peierls transition in a Heisenberg antiferromagnetic linear-chain system. Phys. Rev. Lett. 35, 744–747 (1975). (10.1103/PhysRevLett.35.744) / Phys. Rev. Lett. by JW Bray (1975)
Jacobs, I. S. et al. Spin-Peierls transitions in magnetic donor-acceptor compounds of tetrathiafulvalene (TTF) with bisdithiolene metal complexes. Phys. Rev. B 14, 3036–3051 (1976). (10.1103/PhysRevB.14.3036) / Phys. Rev. B by IS Jacobs (1976)
Bray, J. W., Interrante, I. V., Jacobs, I. S. & Bonner, J. C. Extended Linear Chain Compounds (ed. Miller, J. S.) (Plenum, New York, 1983). / Extended Linear Chain Compounds by JW Bray (1983)
Ishibashi, H., Sakai, T. & Nakahigashi, K. X-ray diffraction study on spinel compound CuIr2S4 with metal-insulator transition. J. Magn. Magn. Mater. 226–230, 233–234 (2001). (10.1016/S0304-8853(00)00638-7) / J. Magn. Magn. Mater. by H Ishibashi (2001)
Billinge, S. J. L. & Egami, T. Short-range atomic structure of Nd2-xCexCuO4-y determined by real-space refinement of neutron-powder-diffraction data. Phys. Rev. B 47, 14386–14406 (1993). (10.1103/PhysRevB.47.14386) / Phys. Rev. B by SJL Billinge (1993)
Kumagai, K., Kakuyanagi, K., Endoh, R. & Nagata, S. NMR study on the metal-insulator transition of (Cu1-xNix)Ir2S4. Physica C 341, 741–742 (2000). (10.1016/S0921-4534(00)00670-5) / Physica C by K Kumagai (2000)
Hase, M., Terasaki, I. & Uchinokura, K. Observation of the spin-Peierls transition in linear Cu2+ (spin-1/2) chains in an inorganic compound CuGeO3. Phys. Rev. Lett. 70, 3651–3654 (1993). (10.1103/PhysRevLett.70.3651) / Phys. Rev. Lett. by M Hase (1993)
Hirota, K. et al. Dimerization of CuGeO3 in the Spin-Peierls state. Phys. Rev. Lett. 73, 736–739 (1994). (10.1103/PhysRevLett.73.736) / Phys. Rev. Lett. by K Hirota (1994)
Lüdecke, J. et al. Acentric low-temperature superstructure of NaV2O5. Phys. Rev. Lett. 82, 3633–3636 (1999). (10.1103/PhysRevLett.82.3633) / Phys. Rev. Lett. by J Lüdecke (1999)
Marezio, M., McWhan, D. B., Derniew, P. D. & Remeika, J. P. Charge localization at metal-insulator transitions in Ti4O7. Phys. Rev. Lett. 28, 1390–1393 (1972). (10.1103/PhysRevLett.28.1390) / Phys. Rev. Lett. by M Marezio (1972)
Anderson, P. W. Ordering and antiferromagnetism in ferrites. Phys. Rev. 102, 1008–1013 (1956). (10.1103/PhysRev.102.1008) / Phys. Rev. by PW Anderson (1956)
Rodríguez-Carvajal, J., Rousse, G., Masquelier, C. & Hervieu, M. Electronic crystallization in a lithium battery material: columnar ordering of electrons and holes in the spinel LiMn2O4. Phys. Rev. Lett. 81, 4660–4663 (1998). (10.1103/PhysRevLett.81.4660) / Phys. Rev. Lett. by J Rodríguez-Carvajal (1998)
Stokes, H. T. & Hatch, D. M. Isotropy Subgroups of the 230 Crystallographic Space Groups (World Scientific, Singapore, 1988). / Isotropy Subgroups of the 230 Crystallographic Space Groups by HT Stokes (1988)
Larson, A. C. & von Dreele, R. B. (The Regents of the University of California, Los Alamos, 1985).
Peterson, P. F., Gutmann, M., Proffen, T. & Billinge, S. J. L. PDFgetN: a user-friendly program to extract the total scattering structure factor and the pair distribution function from neutron powder diffraction data. J. Appl. Crystallogr. 33, 1192 (2000). (10.1107/S0021889800007123) / J. Appl. Crystallogr. by PF Peterson (2000)
Proffen, T. & Billinge, S. J. L. PDFFIT, a program for full profile structural refinement of the atomic pair distribution function. J. Appl. Crystallogr. 32, 572–575 (1999). (10.1107/S0021889899003532) / J. Appl. Crystallogr. by T Proffen (1999)

Dates

Type	When
Created	23 years ago (July 26, 2002, 4:31 a.m.)
Deposited	2 years, 3 months ago (May 17, 2023, 8:27 p.m.)
Indexed	2 weeks, 4 days ago (Aug. 6, 2025, 8:54 a.m.)
Issued	23 years, 5 months ago (March 1, 2002)
Published	23 years, 5 months ago (March 1, 2002)
Published Print	23 years, 5 months ago (March 1, 2002)

Funders 0

None

BibTeX

@article{Radaelli_2002, title={Formation of isomorphic Ir3+ and Ir4+ octamers and spin dimerization in the spinel CuIr2S4}, volume={416}, ISSN={1476-4687}, url={http://dx.doi.org/10.1038/416155a}, DOI={10.1038/416155a}, number={6877}, journal={Nature}, publisher={Springer Science and Business Media LLC}, author={Radaelli, Paolo G. and Horibe, Y. and Gutmann, Matthias J. and Ishibashi, Hiroki and Chen, C. H. and Ibberson, Richard M. and Koyama, Y. and Hor, Yew-San and Kiryukhin, Valery and Cheong, Sang-Wook}, year={2002}, month=mar, pages={155–158} }

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