DOI: 10.1029/97gl00093. Reactive uptake and hydration experiments on amorphous carbon treated with NO2, SO2, O3, HNO3, and H2SO4

Reactive uptake and hydration experiments on amorphous carbon treated with NO2, SO2, O3, HNO3, and H2SO4

10.1029/97gl00093

Crossref journal-article

American Geophysical Union (AGU)

Geophysical Research Letters (13)

Abstract

The reactivity and hydration properties of amorphous carbon were studied in a low‐pressure Knudsen cell reactor at room temperature (298 K). Reactions of NO2 (γ=0.11±0.04) and HNO3 (γ=0.038±0.008) were observed and may be important for nitrogen partitioning in the atmosphere. Water uptake was measured before and after exposure to various gases. Treating the amorphous carbon with NO2 and O3 does not alter the H2O uptake, while treatment with SO2, HNO3, and H2SO4 significantly increases the H2O uptake. The experimental results support current assumptions in jet aircraft plume models that sulfuric acid condensation is involved in the activation of soot particles as condensation nuclei.

Bibliography

Rogaski, C. A., Golden, D. M., & Williams, L. R. (1997). Reactive uptake and hydration experiments on amorphous carbon treated with NO2, SO2, O3, HNO3, and H2SO4. Geophysical Research Letters, 24(4), 381â384. Portico.

Authors 3

C. A. Rogaski (first)
D. M. Golden (additional)
L. R. Williams (additional)

References 28 Referenced 139

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10.1029/94JD03118
10.1029/96JD01918
{'key': 'e_1_2_1_5_1', 'article-title': 'Effect of aircraft exhaust sulfur emissions on near field plume aerosols', 'author': 'Brown R. C.', 'year': '1996', 'journal-title': 'Geophys. Res. Lett.'} / Geophys. Res. Lett. / Effect of aircraft exhaust sulfur emissions on near field plume aerosols by Brown R. C. (1996)
10.1029/95JD01882
{'key': 'e_1_2_1_7_1', 'volume-title': 'Pigment blacks for printing inks, coatings and plastics, Technical Document', 'author': 'Degussa Corporation', 'year': '1994'} / Pigment blacks for printing inks, coatings and plastics, Technical Document by Degussa Corporation (1994)
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{'key': 'e_1_2_1_11_1', 'first-page': '187', 'article-title': 'Applications of chemical kinetics', 'volume': '1', 'author': 'Golden D. M.', 'year': '1992', 'journal-title': 'Advances in Chemical Kinetics and Dynamics'} / Advances in Chemical Kinetics and Dynamics / Applications of chemical kinetics by Golden D. M. (1992)
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{'issue': '1', 'key': 'e_1_2_1_25_1', 'first-page': '103', 'article-title': 'An FT‐IR study of the effect of simulated solar radiation and various particulates on the oxidation of SO2', 'volume': '43', 'author': 'Smith D. M.', 'year': '1989', 'journal-title': 'Appl. Opt.'} / Appl. Opt. / An FT‐IR study of the effect of simulated solar radiation and various particulates on the oxidation of SO2 by Smith D. M. (1989)
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Dates

Type	When
Created	21 years, 6 months ago (Feb. 3, 2004, 10:24 p.m.)
Deposited	1 year, 9 months ago (Nov. 21, 2023, 11:16 p.m.)
Indexed	2 months ago (June 27, 2025, 9:45 a.m.)
Issued	28 years, 6 months ago (Feb. 15, 1997)
Published	28 years, 6 months ago (Feb. 15, 1997)
Published Online	28 years, 6 months ago (Feb. 15, 1997)
Published Print	28 years, 6 months ago (Feb. 15, 1997)

Funders 0

None

BibTeX

@article{Rogaski_1997, title={Reactive uptake and hydration experiments on amorphous carbon treated with NO2, SO2, O3, HNO3, and H2SO4}, volume={24}, ISSN={1944-8007}, url={http://dx.doi.org/10.1029/97gl00093}, DOI={10.1029/97gl00093}, number={4}, journal={Geophysical Research Letters}, publisher={American Geophysical Union (AGU)}, author={Rogaski, C. A. and Golden, D. M. and Williams, L. R.}, year={1997}, month=feb, pages={381–384} }

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