DOI: 10.1029/96jd01868. Nonmethane hydrocarbon measurements during the Tropospheric OH Photochemistry Experiment

Nonmethane hydrocarbon measurements during the Tropospheric OH Photochemistry Experiment

10.1029/96jd01868

Crossref journal-article

American Geophysical Union (AGU)

Journal of Geophysical Research: Atmospheres (13)

Abstract

In the rural troposphere, the nonmethane hydrocarbon compounds (NMHCs) play a significant role in establishing the absolute, as well as, the relative concentration of the odd‐hydrogen radicals. In order to provide data which could be used to estimate OH reactive loss rates with hydrocarbons directly, and to broaden our understanding of the production of biogenic NMHCs in and the transport of anthropogenic NMHCs into the Colorado mountains, in situ hydrocarbon measurements were made during the Tropospheric OH Photochemistry Experiment in the fall of 1993. NMHC measurements were made using an automated gas chromatographic system that was capable of quantifying alkanes C3 (propane) through C10 (decane), alkenes C4 (butene) through C10 (decene), light alcohols from C1 (methanol) through C5 (pentanol), light ketones from C3 (acetone) through C5 (pentanone), aromatics from C6 (benzene) through C9 (trimethylbenzenes), C10 monoterpenes, and acetaldehyde. During periods of influx of urban air masses, the NMHCs appeared to be the dominant sink for OH radicals.

Bibliography

Goldan, P. D., Kuster, W. C., & Fehsenfeld, F. C. (1997). Nonmethane hydrocarbon measurements during the Tropospheric OH Photochemistry Experiment. Journal of Geophysical Research: Atmospheres, 102(D5), 6315â6324. Portico.

Authors 3

Paul D. Goldan (first)
William C. Kuster (additional)
Fred C. Fehsenfeld (additional)

References 30 Referenced 51

10.1016/0960-1686(90)90438-S
10.1029/96JD03251
10.1029/JD092iD04p04208
10.1029/RG021i004p00921
10.1029/94JD00740
10.1029/96JD01580
10.1016/0004-6981(86)90154-X
10.1029/93GL00247
10.1029/95JD01369
10.1029/95JD02607
10.1029/JD089iD03p04767
10.1016/1352-2310(94)90297-6
10.1021/es00054a013
10.1016/0004-6981(87)90108-9
{'key': 'e_1_2_1_16_1', 'first-page': '419', 'volume-title': 'Our Changing Atmosphere, Proceedings of the 28th Liege International Astrophysical Colloquium', 'author': 'Liu S. C.', 'year': '1989'} / Our Changing Atmosphere, Proceedings of the 28th Liege International Astrophysical Colloquium by Liu S. C. (1989)
10.1029/JC086iC08p07210
10.1021/es00150a005
10.1016/0960-1686(93)90233-O
10.1029/JD095iD06p07493
10.1029/93GL02527
10.1104/pp.108.4.1359
10.1029/92JD01242
10.1016/0004-6981(84)90012-X
10.1021/j100032a021
{'key': 'e_1_2_1_26_1', 'first-page': '177', 'volume-title': 'Gaseous Pollutants: Characterization and Cycling', 'author': 'Singh H. B.', 'year': '1992'} / Gaseous Pollutants: Characterization and Cycling by Singh H. B. (1992)
10.1029/93JD00764
10.1029/JD092iD10p11879
10.1029/96JD03252
10.1029/JD093iD02p01407
10.1021/es00173a015

Dates

Type	When
Created	21 years, 7 months ago (Feb. 3, 2004, 8:49 p.m.)
Deposited	1 year, 11 months ago (Sept. 22, 2023, 1:11 a.m.)
Indexed	1 month, 3 weeks ago (July 13, 2025, 10:38 p.m.)
Issued	28 years, 6 months ago (March 1, 1997)
Published	28 years, 6 months ago (March 1, 1997)
Published Online	28 years, 6 months ago (March 1, 1997)
Published Print	28 years, 5 months ago (March 20, 1997)

Funders 0

None

BibTeX

@article{Goldan_1997, title={Nonmethane hydrocarbon measurements during the Tropospheric OH Photochemistry Experiment}, volume={102}, ISSN={0148-0227}, url={http://dx.doi.org/10.1029/96jd01868}, DOI={10.1029/96jd01868}, number={D5}, journal={Journal of Geophysical Research: Atmospheres}, publisher={American Geophysical Union (AGU)}, author={Goldan, Paul D. and Kuster, William C. and Fehsenfeld, Fred C.}, year={1997}, month=mar, pages={6315–6324} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        14
      ]
    ],
    "date-time": "2025-07-14T02:38:44Z",
    "timestamp": 1752460724991
  },
  "reference-count": 30,
  "publisher": "American Geophysical Union (AGU)",
  "issue": "D5",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            1997,
            3,
            1
          ]
        ],
        "date-time": "1997-03-01T00:00:00Z",
        "timestamp": 857174400000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1997,
        3,
        20
      ]
    ]
  },
  "abstract": "<jats:p>In the rural troposphere, the nonmethane hydrocarbon compounds (NMHCs) play a significant role in establishing the absolute, as well as, the relative concentration of the odd\u2010hydrogen radicals. In order to provide data which could be used to estimate OH reactive loss rates with hydrocarbons directly, and to broaden our understanding of the production of biogenic NMHCs in and the transport of anthropogenic NMHCs into the Colorado mountains, in situ hydrocarbon measurements were made during the Tropospheric OH Photochemistry Experiment in the fall of 1993. NMHC measurements were made using an automated gas chromatographic system that was capable of quantifying alkanes C<jats:sub>3</jats:sub> (propane) through C<jats:sub>10</jats:sub> (decane), alkenes C<jats:sub>4</jats:sub> (butene) through C<jats:sub>10</jats:sub> (decene), light alcohols from C<jats:sub>1</jats:sub> (methanol) through C<jats:sub>5</jats:sub> (pentanol), light ketones from C<jats:sub>3</jats:sub> (acetone) through C<jats:sub>5</jats:sub> (pentanone), aromatics from C<jats:sub>6</jats:sub> (benzene) through C<jats:sub>9</jats:sub> (trimethylbenzenes), C<jats:sub>10</jats:sub> monoterpenes, and acetaldehyde. During periods of influx of urban air masses, the NMHCs appeared to be the dominant sink for OH radicals.</jats:p>",
  "DOI": "10.1029/96jd01868",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2004,
        2,
        4
      ]
    ],
    "date-time": "2004-02-04T01:49:11Z",
    "timestamp": 1075859351000
  },
  "page": "6315-6324",
  "source": "Crossref",
  "is-referenced-by-count": 51,
  "title": "Nonmethane hydrocarbon measurements during the Tropospheric OH Photochemistry Experiment",
  "prefix": "10.1029",
  "volume": "102",
  "author": [
    {
      "given": "Paul D.",
      "family": "Goldan",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "William C.",
      "family": "Kuster",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Fred C.",
      "family": "Fehsenfeld",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "13",
  "published-online": {
    "date-parts": [
      [
        1997,
        3
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_1_2_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0960-1686(90)90438-S"
    },
    {
      "key": "e_1_2_1_3_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/96JD03251"
    },
    {
      "key": "e_1_2_1_4_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/JD092iD04p04208"
    },
    {
      "key": "e_1_2_1_5_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/RG021i004p00921"
    },
    {
      "key": "e_1_2_1_6_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/94JD00740"
    },
    {
      "key": "e_1_2_1_7_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/96JD01580"
    },
    {
      "key": "e_1_2_1_8_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0004-6981(86)90154-X"
    },
    {
      "key": "e_1_2_1_9_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/93GL00247"
    },
    {
      "key": "e_1_2_1_10_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/95JD01369"
    },
    {
      "key": "e_1_2_1_11_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/95JD02607"
    },
    {
      "key": "e_1_2_1_12_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/JD089iD03p04767"
    },
    {
      "key": "e_1_2_1_13_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/1352-2310(94)90297-6"
    },
    {
      "key": "e_1_2_1_14_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es00054a013"
    },
    {
      "key": "e_1_2_1_15_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0004-6981(87)90108-9"
    },
    {
      "key": "e_1_2_1_16_1",
      "first-page": "419",
      "volume-title": "Our Changing Atmosphere, Proceedings of the 28th Liege International Astrophysical Colloquium",
      "author": "Liu S. C.",
      "year": "1989"
    },
    {
      "key": "e_1_2_1_17_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/JC086iC08p07210"
    },
    {
      "key": "e_1_2_1_18_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es00150a005"
    },
    {
      "key": "e_1_2_1_19_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0960-1686(93)90233-O"
    },
    {
      "key": "e_1_2_1_20_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/JD095iD06p07493"
    },
    {
      "key": "e_1_2_1_21_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/93GL02527"
    },
    {
      "key": "e_1_2_1_22_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1104/pp.108.4.1359"
    },
    {
      "key": "e_1_2_1_23_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/92JD01242"
    },
    {
      "key": "e_1_2_1_24_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0004-6981(84)90012-X"
    },
    {
      "key": "e_1_2_1_25_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100032a021"
    },
    {
      "key": "e_1_2_1_26_1",
      "first-page": "177",
      "volume-title": "Gaseous Pollutants: Characterization and Cycling",
      "author": "Singh H. B.",
      "year": "1992"
    },
    {
      "key": "e_1_2_1_27_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/93JD00764"
    },
    {
      "key": "e_1_2_1_28_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/JD092iD10p11879"
    },
    {
      "key": "e_1_2_1_29_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/96JD03252"
    },
    {
      "key": "e_1_2_1_30_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/JD093iD02p01407"
    },
    {
      "key": "e_1_2_1_31_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/es00173a015"
    }
  ],
  "container-title": "Journal of Geophysical Research: Atmospheres",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1029%2F96JD01868",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/96JD01868",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        9,
        22
      ]
    ],
    "date-time": "2023-09-22T05:11:06Z",
    "timestamp": 1695359466000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://agupubs.onlinelibrary.wiley.com/doi/10.1029/96JD01868"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1997,
        3
      ]
    ]
  },
  "references-count": 30,
  "journal-issue": {
    "issue": "D5",
    "published-print": {
      "date-parts": [
        [
          1997,
          3,
          20
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1029/96JD01868"
  ],
  "URL": "http://dx.doi.org/10.1029/96JD01868",
  "relation": {},
  "ISSN": [
    "0148-0227"
  ],
  "subject": [],
  "container-title-short": "J. Geophys. Res.",
  "published": {
    "date-parts": [
      [
        1997,
        3
      ]
    ]
  }
}