DOI: 10.1029/2003gl017021. From Nanodots to Nanorods: Oriented aggregation and magnetic evolution of nanocrystalline goethite

From Nanodots to Nanorods: Oriented aggregation and magnetic evolution of nanocrystalline goethite

10.1029/2003gl017021

Crossref journal-article

American Geophysical Union (AGU)

Geophysical Research Letters (13)

Abstract

Goethite is a common iron oxyhydroxide and an important mineral in the biogeochemical cycle of iron at the Earth's surface. However, environmental controls on its formation and alteration have been difficult to quantify. Perhaps this is because past studies have traditionally used needle‐shaped goethite particles that are substantially larger than the goethite nanoparticles commonly observed in nature. High‐resolution transmission electron microscopy and low‐temperature magnetometry of synthetic goethite nanocrystals show that when aqueous suspensions are aged at 90°C, the nanocrystals grow almost exclusively by oriented aggregation of 3–4 nm primary nanocrystals. These primary particles are superparamagnetic above about 35 K, as shown by variations of magnetic susceptibility with temperature. At low temperature (<300 K), both remanent and induced magnetizations of primary nanoparticles are about an order of magnitude larger than for micron‐sized goethite and can act as magnetic signatures of nanophase in controlled environments.

Bibliography

Guyodo, Y., Mostrom, A., Lee Penn, R., & Banerjee, S. K. (2003). From Nanodots to Nanorods: Oriented aggregation and magnetic evolution of nanocrystalline goethite. Geophysical Research Letters, 30(10). Portico.

Authors 4

Yohan Guyodo (first)
Alison Mostrom (additional)
R. Lee Penn (additional)
Subir K. Banerjee (additional)

References 21 Referenced 108

10.1126/science.289.5480.751
10.1111/j.1365-246X.1989.tb00504.x
10.1111/j.1365-246X.1989.tb00505.x
10.1029/92JB01026
10.1002/9780470141571.ch4
10.1016/S0038-1098(01)00147-8
D. J. Dunlop Ö. Özdemir 1997 Cambridge University Press Cambridge
10.1016/0022-1902(74)80119-3
10.1016/S0304-8853(99)00347-9
10.1006/qres.1995.1083
10.1016/S0016-7037(00)00427-0
{'key': 'e_1_2_6_13_1', 'first-page': '99', 'article-title': 'Théorie du traînage magnétique des ferromagnétiques en grains fins avec applications aux terres cuites', 'volume': '5', 'author': 'Néel L.', 'year': '1949', 'journal-title': 'Annales de Géophysique'} / Annales de Géophysique / Théorie du traînage magnétique des ferromagnétiques en grains fins avec applications aux terres cuites by Néel L. (1949)
{'key': 'e_1_2_6_14_1', 'first-page': '676', 'article-title': 'Propriétés Magnétiques des Grains Fins Antiferro magnétiques: Superparamagnétisme et Superantiferromagnétisme', 'volume': '17', 'author': 'Néel L.', 'year': '1962', 'journal-title': 'J. Phys. Soc. Jap.'} / J. Phys. Soc. Jap. / Propriétés Magnétiques des Grains Fins Antiferro magnétiques: Superparamagnétisme et Superantiferromagnétisme by Néel L. (1962)
10.1029/96GL00904
10.1016/S0016-7037(99)00037-X
10.1130/0091-7613(2001)029<0843:IOCOSG>2.0.CO;2
10.1006/jcis.1999.6106 / J. Colloid Interface Sci. / Mechanism of formation of monodispersed colloids by aggregation of nanosize precursors by Privman V. (1999)
10.1515/9781501508783-011 / Nanoparticles and the Environment by Rancourt D. G. (2001)
10.1029/GL016i008p00851
10.1007/978-94-009-4007-9_11
U. Schwertmann R. M. Cornell 1991 VCH Publishers New York

Dates

Type	When
Created	22 years, 3 months ago (May 23, 2003, 2:26 p.m.)
Deposited	1 year, 10 months ago (Oct. 31, 2023, 4:07 p.m.)
Indexed	1 month, 1 week ago (July 30, 2025, 6:25 a.m.)
Issued	22 years, 3 months ago (May 15, 2003)
Published	22 years, 3 months ago (May 15, 2003)
Published Online	22 years, 3 months ago (May 22, 2003)
Published Print	22 years, 3 months ago (May 15, 2003)

Funders 0

None

BibTeX

@article{Guyodo_2003, title={From Nanodots to Nanorods: Oriented aggregation and magnetic evolution of nanocrystalline goethite}, volume={30}, ISSN={1944-8007}, url={http://dx.doi.org/10.1029/2003gl017021}, DOI={10.1029/2003gl017021}, number={10}, journal={Geophysical Research Letters}, publisher={American Geophysical Union (AGU)}, author={Guyodo, Yohan and Mostrom, Alison and Lee Penn, R. and Banerjee, Subir K.}, year={2003}, month=may }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        30
      ]
    ],
    "date-time": "2025-07-30T10:25:46Z",
    "timestamp": 1753871146550,
    "version": "3.41.2"
  },
  "reference-count": 21,
  "publisher": "American Geophysical Union (AGU)",
  "issue": "10",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2003,
            5,
            22
          ]
        ],
        "date-time": "2003-05-22T00:00:00Z",
        "timestamp": 1053561600000
      },
      "content-version": "vor",
      "delay-in-days": 7,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2003,
        5,
        15
      ]
    ]
  },
  "abstract": "<jats:p>Goethite is a common iron oxyhydroxide and an important mineral in the biogeochemical cycle of iron at the Earth's surface. However, environmental controls on its formation and alteration have been difficult to quantify. Perhaps this is because past studies have traditionally used needle\u2010shaped goethite particles that are substantially larger than the goethite nanoparticles commonly observed in nature. High\u2010resolution transmission electron microscopy and low\u2010temperature magnetometry of synthetic goethite nanocrystals show that when aqueous suspensions are aged at 90\u00b0C, the nanocrystals grow almost exclusively by oriented aggregation of 3\u20134 nm primary nanocrystals. These primary particles are superparamagnetic above about 35 K, as shown by variations of magnetic susceptibility with temperature. At low temperature (&lt;300 K), both remanent and induced magnetizations of primary nanoparticles are about an order of magnitude larger than for micron\u2010sized goethite and can act as magnetic signatures of nanophase in controlled environments.</jats:p>",
  "DOI": "10.1029/2003gl017021",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2003,
        5,
        23
      ]
    ],
    "date-time": "2003-05-23T18:26:56Z",
    "timestamp": 1053714416000
  },
  "source": "Crossref",
  "is-referenced-by-count": 108,
  "title": "From Nanodots to Nanorods: Oriented aggregation and magnetic evolution of nanocrystalline goethite",
  "prefix": "10.1029",
  "volume": "30",
  "author": [
    {
      "given": "Yohan",
      "family": "Guyodo",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Institute for Rock Magnetism, Department of Geology and Geophysics University of Minnesota  Minneapolis Minnesota USA"
        }
      ]
    },
    {
      "given": "Alison",
      "family": "Mostrom",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry University of Minnesota  Minneapolis Minnesota USA"
        }
      ]
    },
    {
      "given": "R.",
      "family": "Lee Penn",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry University of Minnesota  Minneapolis Minnesota USA"
        }
      ]
    },
    {
      "given": "Subir K.",
      "family": "Banerjee",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Institute for Rock Magnetism, Department of Geology and Geophysics University of Minnesota  Minneapolis Minnesota USA"
        }
      ]
    }
  ],
  "member": "13",
  "published-online": {
    "date-parts": [
      [
        2003,
        5,
        22
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_6_2_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.289.5480.751"
    },
    {
      "key": "e_1_2_6_3_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1111/j.1365-246X.1989.tb00504.x"
    },
    {
      "key": "e_1_2_6_4_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1111/j.1365-246X.1989.tb00505.x"
    },
    {
      "key": "e_1_2_6_5_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/92JB01026"
    },
    {
      "key": "e_1_2_6_6_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/9780470141571.ch4"
    },
    {
      "key": "e_1_2_6_7_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0038-1098(01)00147-8"
    },
    {
      "key": "e_1_2_6_8_1",
      "unstructured": "D. J. Dunlop \u00d6. \u00d6zdemir 1997 Cambridge University Press Cambridge"
    },
    {
      "key": "e_1_2_6_9_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-1902(74)80119-3"
    },
    {
      "key": "e_1_2_6_10_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0304-8853(99)00347-9"
    },
    {
      "key": "e_1_2_6_11_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1006/qres.1995.1083"
    },
    {
      "key": "e_1_2_6_12_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0016-7037(00)00427-0"
    },
    {
      "key": "e_1_2_6_13_1",
      "first-page": "99",
      "article-title": "Th\u00e9orie du tra\u00eenage magn\u00e9tique des ferromagn\u00e9tiques en grains fins avec applications aux terres cuites",
      "volume": "5",
      "author": "N\u00e9el L.",
      "year": "1949",
      "journal-title": "Annales de G\u00e9ophysique"
    },
    {
      "key": "e_1_2_6_14_1",
      "first-page": "676",
      "article-title": "Propri\u00e9t\u00e9s Magn\u00e9tiques des Grains Fins Antiferro magn\u00e9tiques: Superparamagn\u00e9tisme et Superantiferromagn\u00e9tisme",
      "volume": "17",
      "author": "N\u00e9el L.",
      "year": "1962",
      "journal-title": "J. Phys. Soc. Jap."
    },
    {
      "key": "e_1_2_6_15_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/96GL00904"
    },
    {
      "key": "e_1_2_6_16_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0016-7037(99)00037-X"
    },
    {
      "key": "e_1_2_6_17_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1130/0091-7613(2001)029<0843:IOCOSG>2.0.CO;2"
    },
    {
      "issue": "1",
      "key": "e_1_2_6_18_1",
      "doi-asserted-by": "crossref",
      "first-page": "36",
      "DOI": "10.1006/jcis.1999.6106",
      "article-title": "Mechanism of formation of monodispersed colloids by aggregation of nanosize precursors",
      "volume": "213",
      "author": "Privman V.",
      "year": "1999",
      "journal-title": "J. Colloid Interface Sci."
    },
    {
      "key": "e_1_2_6_19_1",
      "doi-asserted-by": "crossref",
      "first-page": "217",
      "DOI": "10.1515/9781501508783-011",
      "volume-title": "Nanoparticles and the Environment",
      "author": "Rancourt D. G.",
      "year": "2001"
    },
    {
      "key": "e_1_2_6_20_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1029/GL016i008p00851"
    },
    {
      "key": "e_1_2_6_21_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/978-94-009-4007-9_11"
    },
    {
      "key": "e_1_2_6_22_1",
      "unstructured": "U. Schwertmann R. M. Cornell 1991 VCH Publishers New York"
    }
  ],
  "container-title": "Geophysical Research Letters",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1029%2F2003GL017021",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://agupubs.onlinelibrary.wiley.com/doi/pdf/10.1029/2003GL017021",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        31
      ]
    ],
    "date-time": "2023-10-31T20:07:35Z",
    "timestamp": 1698782855000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://agupubs.onlinelibrary.wiley.com/doi/10.1029/2003GL017021"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2003,
        5,
        15
      ]
    ]
  },
  "references-count": 21,
  "journal-issue": {
    "issue": "10",
    "published-print": {
      "date-parts": [
        [
          2003,
          5,
          15
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1029/2003GL017021"
  ],
  "URL": "http://dx.doi.org/10.1029/2003GL017021",
  "relation": {},
  "ISSN": [
    "0094-8276",
    "1944-8007"
  ],
  "subject": [],
  "container-title-short": "Geophysical Research Letters",
  "published": {
    "date-parts": [
      [
        2003,
        5,
        15
      ]
    ]
  },
  "article-number": "2003GL017021"
}