DOI: 10.1021/la980083l. Spectroscopic and Photoluminescence Studies of a Wide Band Gap Insulating Material: Powdered and Colloidal ZrO<sub>2</sub> Sols

Spectroscopic and Photoluminescence Studies of a Wide Band Gap Insulating Material: Powdered and Colloidal ZrO2 Sols

10.1021/la980083l

Crossref journal-article

American Chemical Society (ACS)

Langmuir (316)

Bibliography

Emeline, A., Kataeva, G. V., Litke, A. S., Rudakova, A. V., Ryabchuk, V. K., & Serpone, N. (1998). Spectroscopic and Photoluminescence Studies of a Wide Band Gap Insulating Material:â Powdered and Colloidal ZrO2 Sols. Langmuir, 14(18), 5011â5022.

Authors 6

Alexei Emeline (first)
Galina V. Kataeva (additional)
Alexander S. Litke (additional)
Aida V. Rudakova (additional)
Vladimir K. Ryabchuk (additional)
Nick Serpone (additional)

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(a) The nature of photogenerated hole centers in zirconia is less certain. Intrinsic and extrinsic preexisting hole traps no doubt exist with Harrison's30bZr4+being among them. The trapped hole O--like center (g1= 2.0196,g2= 2.101, andg3= 2.0045) has been detected by Burukina47b,cby EPR techniques both at the surface and in the bulk of the zirconia lattice after UV irradiation by a mercury lamp (note the same ZrO2sample and same irradiation source were used as in the present study). The growth kinetics of O-centers under illumination correlate with the growth kinetics of the color centers detected by diffuse reflectance spectra; the surface O-trapped holes vanish upon postillumination adsorption of H2. The complex optical absorption band of the hole centers illustrated in Figure 3 arises, at least partially, from these hole centers. Similar EPR signals of these O-hole centers were reported for γ-irradiated zirconia.47d(b) Burukina, G. V. Ph.D. Thesis, Leningrad State University, Leningrad, Soviet Union, 1990.
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 1:28 a.m.)
Deposited	3 years, 11 months ago (Sept. 23, 2021, 3:02 p.m.)
Indexed	1 day, 10 hours ago (Sept. 4, 2025, 10:20 a.m.)
Issued	27 years, 1 month ago (Aug. 1, 1998)
Published	27 years, 1 month ago (Aug. 1, 1998)
Published Online	27 years, 1 month ago (Aug. 1, 1998)
Published Print	27 years ago (Sept. 1, 1998)

Funders 0

None

BibTeX

@article{Emeline_1998, title={Spectroscopic and Photoluminescence Studies of a Wide Band Gap Insulating Material: Powdered and Colloidal ZrO2 Sols}, volume={14}, ISSN={1520-5827}, url={http://dx.doi.org/10.1021/la980083l}, DOI={10.1021/la980083l}, number={18}, journal={Langmuir}, publisher={American Chemical Society (ACS)}, author={Emeline, Alexei and Kataeva, Galina V. and Litke, Alexander S. and Rudakova, Aida V. and Ryabchuk, Vladimir K. and Serpone, Nick}, year={1998}, month=aug, pages={5011–5022} }

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