DOI: 10.1021/la9600513. Molecular-Thermodynamic Modeling of Mixed Cationic/Anionic Vesicles

Molecular-Thermodynamic Modeling of Mixed Cationic/Anionic Vesicles

10.1021/la9600513

Crossref journal-article

American Chemical Society (ACS)

Langmuir (316)

Bibliography

Yuet, P. K., & Blankschtein, D. (1996). Molecular-Thermodynamic Modeling of Mixed Cationic/Anionic Vesicles. Langmuir, 12(16), 3802â3818.

Authors 2

Pak K. Yuet (first)
Daniel Blankschtein (additional)

References 84 Referenced 94

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Note that the term “final”, as used here, does not imply the minimum-energy configuration of the vesicle. Instead, it refers to the charging stage in the calculation ofgelec. In other words, the term “final” corresponds to the state at which λ = 1. As discussed in section IV,gvesis minimized by sampling a large configuration space, and each sampled vesicle configuration will have a “final” charge on each surface.
Here, we assume that the distance between the location of the charge on the surfactant head of component A and the hydrocarbon/water interface,dch,A, is smaller than that corresponding to component B,dch,B.
Note that, in utilizing the PB equation, we are making the usual assumptions of smeared surface charges and point-sized ions. This, in turn, restricts the ability of the present theory to reveal the effect of different counterions on vesicle properties and on vesicle phase behavior, an effect which has been observed experimentally.
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 1 a.m.)
Deposited	2 years, 5 months ago (March 23, 2023, 7:24 p.m.)
Indexed	1 year, 1 month ago (July 25, 2024, 3:48 p.m.)
Issued	29 years, 7 months ago (Jan. 1, 1996)
Published	29 years, 7 months ago (Jan. 1, 1996)
Published Online	29 years ago (Aug. 7, 1996)
Published Print	29 years, 7 months ago (Jan. 1, 1996)

Funders 0

None

BibTeX

@article{Yuet_1996, title={Molecular-Thermodynamic Modeling of Mixed Cationic/Anionic Vesicles}, volume={12}, ISSN={1520-5827}, url={http://dx.doi.org/10.1021/la9600513}, DOI={10.1021/la9600513}, number={16}, journal={Langmuir}, publisher={American Chemical Society (ACS)}, author={Yuet, Pak K. and Blankschtein, Daniel}, year={1996}, month=jan, pages={3802–3818} }

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      "unstructured": "Note that the term \u201cfinal\u201d, as used here, does not imply the minimum-energy configuration of the vesicle. Instead, it refers to the charging stage in the calculation ofgelec. In other words, the term \u201cfinal\u201d corresponds to the state at which \u03bb = 1. As discussed in section IV,gvesis minimized by sampling a large configuration space, and each sampled vesicle configuration will have a \u201cfinal\u201d charge on each surface."
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    {
      "key": "la9600513b00076/la9600513b00076_1",
      "unstructured": "Here, we assume that the distance between the location of the charge on the surfactant head of component A and the hydrocarbon/water interface,dch,A, is smaller than that corresponding to component B,dch,B."
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      "unstructured": "Note that, in utilizing the PB equation, we are making the usual assumptions of smeared surface charges and point-sized ions. This, in turn, restricts the ability of the present theory to reveal the effect of different counterions on vesicle properties and on vesicle phase behavior, an effect which has been observed experimentally."
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      "unstructured": "Flory, P. J.\t\t\t\t\tStatistical Mechanics of Chain Molecules; Hanser Publishers:\u2009 Munich,1989."
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      "unstructured": "Lide, D. R.\t\t\t\t\tCRC Handbook of Chemistry and Physics, 71st ed.; CRC Press:\u2009 Boca Raton, FL, 1990."
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