DOI: 10.1021/jp9908404. Energetics of the Nanocrystalline Titanium Dioxide/Aqueous Solution Interface: Approximate Conduction Band Edge Variations between H<sub>0</sub> = −10 and H<sub>-</sub> = +26

Energetics of the Nanocrystalline Titanium Dioxide/Aqueous Solution Interface: Approximate Conduction Band Edge Variations between H0 = −10 and H- = +26

10.1021/jp9908404

Crossref journal-article

American Chemical Society (ACS)

The Journal of Physical Chemistry B (316)

Bibliography

Lyon, L. A., & Hupp, J. T. (1999). Energetics of the Nanocrystalline Titanium Dioxide/Aqueous Solution Interface:â Approximate Conduction Band Edge Variations between H0 = â10 and H- = +26. The Journal of Physical Chemistry B, 103(22), 4623â4628.

Authors 2

L. Andrew Lyon (first)
Joseph T. Hupp (additional)

References 31 Referenced 215

10.1021/j100565a004 / J. Phys. Chem. by Bolts J. M. (1976)
{'key': 'jp9908404b00002/jp9908404b00002_1', 'volume-title': 'H. O. Semiconductor Electrodes', 'author': 'See', 'year': '1988'} / H. O. Semiconductor Electrodes by See (1988)
10.1021/cr00033a003 / Chem. Rev. by For (1995)
10.1021/j100027a032 / J. Phys. Chem. by Representative (1995)
10.1021/ja00003a060 / J. Am. Chem. Soc. by Blackbourn R. L. (1991)
{'key': 'jp9908404b00006/jp9908404b00006_1', 'volume': '81', 'author': 'There', 'year': '1985', 'journal-title': 'Chem. Soc., Faraday Trans. 1'} / Chem. Soc., Faraday Trans. 1 by There (1985)
10.1016/0022-0728(92)80486-N / J. Electroanal. Chem. by Laviron E. (1992)
{'key': 'jp9908404b00008/jp9908404b00008_1', 'volume-title': 'Acidity Functions', 'author': 'Rochester C. H.', 'year': '1970'} / Acidity Functions by Rochester C. H. (1970)
10.1557/JMR.1991.1073 / J. Mater. Res. by Xu Q. (1991)
10.1021/j100043a005 / J. Phys. Chem. by Lyon L. A. (1995)
10.1007/s100080050026 / J. Solid State Electrochem. by Krtil P. (1997)
{'key': 'jp9908404b00011/jp9908404b00011_1', 'first-page': '85', 'volume-title': 'Electroanalytical Chemistry', 'volume': '17', 'author': 'For', 'year': '1991'} / Electroanalytical Chemistry by For (1991)
{'key': 'jp9908404b00012/jp9908404b00012_1', 'first-page': '2426', 'volume': '100', 'author': 'Lemon B. I.', 'year': '1996', 'journal-title': 'J. Phys. Chem. B'} / J. Phys. Chem. B by Lemon B. I. (1996)
10.1021/j100318a069 / J. Phys. Chem. by Ward M. D. (1988)
10.1021/j100031a027 / J. Phys. Chem. by Cao F. (1995)
10.1149/1.2115568 / J. Electrochem. Soc. by Albery W. J. (1984)
10.1149/1.2069045 / J. Electrochem. Soc. by Hodes G. (1992)
10.1021/j100075a023 / J. Phys. Chem. by Enright B. (1994)
10.1016/0009-2614(91)85104-5 / Chem. Phys. Lett. by O'Regan B. (1991)
10.1021/j100109a029 / J. Phys. Chem. by Redmond G. (1993)
10.1021/j100179a001 / J. Phys. Chem. by O'Regan B. (1991)
10.1021/j100193a062 / J. Phys. Chem. by Rothenberger G. (1992)
10.1007/BF01337937 / Z. Phys. by Saurbrey G. Z. (1959)
Schindler and GamsjägerFaradayDiscuss. Chem.Soc.1971,52, 286) report for anatase: pKa1= {7.8 +13(−Ti−O-)} and pKa2= {5.0−26(−Ti−OH2+)}, where the concentrations of the fully protonated and fully deprotonated surface species are given in mol/kg. Thus, at any finite concentration of −Ti−O-, the value of pKa1will be greater than 7.8, while at any finite concentration of −Ti−OH2+, the value of pKa2will be less than 5.0. If one assumes that the acid−base titration data reported by Schindler and Gamsjäger extend to saturation, then the pKavalues for their samples at half saturation (i.e., midpoints of titrations) are 3.9 and 9.7.
{'key': 'jp9908404b00022/jp9908404b00022_1', 'first-page': '2171', 'volume': '117', 'author': 'Ram M. S.', 'year': '1995', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. by Ram M. S. (1995)
10.1021/ic00084a010 / Inorg. Chem. by Liu W. (1994)
10.1149/1.2048726 / J. Electrochem. Soc. by Huang S. Y. (1995)
10.1016/0167-2738(92)90449-Y / J. Solid State Ionics by Macklin W. J. (1992)
10.1021/j100131a004 / J. Phys. Chem. by Lantz J. M. (1993)
10.1016/0010-8545(86)85009-3 / Coord. Chem. Rev. by Kalaysundaram K. (1986)
10.1016/0001-8686(78)85002-7 / Colloid Interface Sci. by Healy T. W. (1978)

Dates

Type	When
Created	23 years ago (July 26, 2002, 1:41 a.m.)
Deposited	2 years, 5 months ago (March 5, 2023, 8:36 a.m.)
Indexed	1 month, 2 weeks ago (July 9, 2025, 7 p.m.)
Issued	26 years, 3 months ago (May 7, 1999)
Published	26 years, 3 months ago (May 7, 1999)
Published Online	26 years, 3 months ago (May 7, 1999)
Published Print	26 years, 2 months ago (June 1, 1999)

Funders 0

None

BibTeX

@article{Lyon_1999, title={Energetics of the Nanocrystalline Titanium Dioxide/Aqueous Solution Interface: Approximate Conduction Band Edge Variations between H0 = −10 and H- = +26}, volume={103}, ISSN={1520-5207}, url={http://dx.doi.org/10.1021/jp9908404}, DOI={10.1021/jp9908404}, number={22}, journal={The Journal of Physical Chemistry B}, publisher={American Chemical Society (ACS)}, author={Lyon, L. Andrew and Hupp, Joseph T.}, year={1999}, month=may, pages={4623–4628} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        9
      ]
    ],
    "date-time": "2025-07-09T23:00:16Z",
    "timestamp": 1752102016301
  },
  "reference-count": 31,
  "publisher": "American Chemical Society (ACS)",
  "issue": "22",
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1999,
        6,
        1
      ]
    ]
  },
  "DOI": "10.1021/jp9908404",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        7,
        26
      ]
    ],
    "date-time": "2002-07-26T05:41:05Z",
    "timestamp": 1027662065000
  },
  "page": "4623-4628",
  "source": "Crossref",
  "is-referenced-by-count": 215,
  "title": "Energetics of the Nanocrystalline Titanium Dioxide/Aqueous Solution Interface:\u2009 Approximate Conduction Band Edge Variations between H<sub>0</sub> = \u221210 and H<sub>-</sub> = +26",
  "prefix": "10.1021",
  "volume": "103",
  "author": [
    {
      "given": "L. Andrew",
      "family": "Lyon",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Chemistry, Northwestern University, Evanston, Illinois 60208"
        }
      ]
    },
    {
      "given": "Joseph T.",
      "family": "Hupp",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry, Northwestern University, Evanston, Illinois 60208"
        }
      ]
    }
  ],
  "member": "316",
  "published-online": {
    "date-parts": [
      [
        1999,
        5,
        7
      ]
    ]
  },
  "reference": [
    {
      "key": "jp9908404b00001/jp9908404b00001_1",
      "doi-asserted-by": "crossref",
      "first-page": "2641",
      "DOI": "10.1021/j100565a004",
      "volume": "80",
      "author": "Bolts J. M.",
      "year": "1976",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "jp9908404b00002/jp9908404b00002_1",
      "volume-title": "H. O. Semiconductor Electrodes",
      "author": "See",
      "year": "1988"
    },
    {
      "key": "jp9908404b00003/jp9908404b00003_1",
      "doi-asserted-by": "crossref",
      "first-page": "49",
      "DOI": "10.1021/cr00033a003",
      "volume": "95",
      "author": "For",
      "year": "1995",
      "journal-title": "Chem. Rev."
    },
    {
      "key": "jp9908404b00004/jp9908404b00004_1",
      "doi-asserted-by": "crossref",
      "first-page": "10883",
      "DOI": "10.1021/j100027a032",
      "volume": "99",
      "author": "Representative",
      "year": "1995",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "jp9908404b00005/jp9908404b00005_1",
      "doi-asserted-by": "crossref",
      "first-page": "1060",
      "DOI": "10.1021/ja00003a060",
      "volume": "113",
      "author": "Blackbourn R. L.",
      "year": "1991",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "jp9908404b00006/jp9908404b00006_1",
      "volume": "81",
      "author": "There",
      "year": "1985",
      "journal-title": "Chem. Soc., Faraday Trans. 1"
    },
    {
      "key": "jp9908404b00007/jp9908404b00007_1",
      "doi-asserted-by": "crossref",
      "first-page": "227",
      "DOI": "10.1016/0022-0728(92)80486-N",
      "volume": "341",
      "author": "Laviron E.",
      "year": "1992",
      "journal-title": "J. Electroanal. Chem."
    },
    {
      "key": "jp9908404b00008/jp9908404b00008_1",
      "volume-title": "Acidity Functions",
      "author": "Rochester C. H.",
      "year": "1970"
    },
    {
      "key": "jp9908404b00009/jp9908404b00009_1",
      "doi-asserted-by": "crossref",
      "first-page": "1073",
      "DOI": "10.1557/JMR.1991.1073",
      "volume": "6",
      "author": "Xu Q.",
      "year": "1991",
      "journal-title": "J. Mater. Res."
    },
    {
      "key": "jp9908404b00010/jp9908404b00010_1",
      "doi-asserted-by": "crossref",
      "first-page": "15718",
      "DOI": "10.1021/j100043a005",
      "volume": "99",
      "author": "Lyon L. A.",
      "year": "1995",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "jp9908404b00010/jp9908404b00010_2",
      "doi-asserted-by": "crossref",
      "first-page": "83",
      "DOI": "10.1007/s100080050026",
      "volume": "1",
      "author": "Krtil P.",
      "year": "1997",
      "journal-title": "J. Solid State Electrochem."
    },
    {
      "key": "jp9908404b00011/jp9908404b00011_1",
      "first-page": "85",
      "volume-title": "Electroanalytical Chemistry",
      "volume": "17",
      "author": "For",
      "year": "1991"
    },
    {
      "key": "jp9908404b00012/jp9908404b00012_1",
      "first-page": "2426",
      "volume": "100",
      "author": "Lemon B. I.",
      "year": "1996",
      "journal-title": "J. Phys. Chem. B"
    },
    {
      "key": "jp9908404b00013/jp9908404b00013_1",
      "doi-asserted-by": "crossref",
      "first-page": "2049",
      "DOI": "10.1021/j100318a069",
      "volume": "92",
      "author": "Ward M. D.",
      "year": "1988",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "jp9908404b00014/jp9908404b00014_1",
      "doi-asserted-by": "crossref",
      "first-page": "11974",
      "DOI": "10.1021/j100031a027",
      "volume": "99",
      "author": "Cao F.",
      "year": "1995",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "jp9908404b00015/jp9908404b00015_1",
      "doi-asserted-by": "crossref",
      "first-page": "315",
      "DOI": "10.1149/1.2115568",
      "volume": "131",
      "author": "Albery W. J.",
      "year": "1984",
      "journal-title": "J. Electrochem. Soc."
    },
    {
      "key": "jp9908404b00015/jp9908404b00015_2",
      "doi-asserted-by": "crossref",
      "first-page": "5983",
      "DOI": "10.1149/1.2069045",
      "volume": "139",
      "author": "Hodes G.",
      "year": "1992",
      "journal-title": "J. Electrochem. Soc."
    },
    {
      "key": "jp9908404b00016/jp9908404b00016_1",
      "doi-asserted-by": "crossref",
      "first-page": "6195",
      "DOI": "10.1021/j100075a023",
      "volume": "98",
      "author": "Enright B.",
      "year": "1994",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "jp9908404b00016/jp9908404b00016_2",
      "doi-asserted-by": "crossref",
      "first-page": "89",
      "DOI": "10.1016/0009-2614(91)85104-5",
      "volume": "183",
      "author": "O'Regan B.",
      "year": "1991",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "jp9908404b00016/jp9908404b00016_3",
      "doi-asserted-by": "crossref",
      "first-page": "1426",
      "DOI": "10.1021/j100109a029",
      "volume": "97",
      "author": "Redmond G.",
      "year": "1993",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "jp9908404b00016/jp9908404b00016_4",
      "doi-asserted-by": "crossref",
      "first-page": "10525",
      "DOI": "10.1021/j100179a001",
      "volume": "95",
      "author": "O'Regan B.",
      "year": "1991",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "jp9908404b00016/jp9908404b00016_5",
      "doi-asserted-by": "crossref",
      "first-page": "5983",
      "DOI": "10.1021/j100193a062",
      "volume": "96",
      "author": "Rothenberger G.",
      "year": "1992",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "jp9908404b00017/jp9908404b00017_1",
      "doi-asserted-by": "crossref",
      "first-page": "206",
      "DOI": "10.1007/BF01337937",
      "volume": "155",
      "author": "Saurbrey G. Z.",
      "year": "1959",
      "journal-title": "Z. Phys."
    },
    {
      "key": "jp9908404b00020/jp9908404b00020_1",
      "unstructured": "Schindler and Gamsj\u00e4gerFaradayDiscuss. Chem.Soc.1971,52, 286) report for anatase:\u2009 pKa1= {7.8 +13(\u2212Ti\u2212O-)} and pKa2= {5.0\u221226(\u2212Ti\u2212OH2+)}, where the concentrations of the fully protonated and fully deprotonated surface species are given in mol/kg. Thus, at any finite concentration of \u2212Ti\u2212O-, the value of pKa1will be greater than 7.8, while at any finite concentration of \u2212Ti\u2212OH2+, the value of pKa2will be less than 5.0. If one assumes that the acid\u2212base titration data reported by Schindler and Gamsj\u00e4ger extend to saturation, then the pKavalues for their samples at half saturation (i.e., midpoints of titrations) are 3.9 and 9.7."
    },
    {
      "key": "jp9908404b00022/jp9908404b00022_1",
      "first-page": "2171",
      "volume": "117",
      "author": "Ram M. S.",
      "year": "1995",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "jp9908404b00023/jp9908404b00023_1",
      "doi-asserted-by": "crossref",
      "first-page": "1026",
      "DOI": "10.1021/ic00084a010",
      "volume": "33",
      "author": "Liu W.",
      "year": "1994",
      "journal-title": "Inorg. Chem."
    },
    {
      "key": "jp9908404b00024/jp9908404b00024_1",
      "doi-asserted-by": "crossref",
      "first-page": "L142",
      "DOI": "10.1149/1.2048726",
      "volume": "142",
      "author": "Huang S. Y.",
      "year": "1995",
      "journal-title": "J. Electrochem. Soc."
    },
    {
      "key": "jp9908404b00024/jp9908404b00024_2",
      "doi-asserted-by": "crossref",
      "first-page": "694",
      "DOI": "10.1016/0167-2738(92)90449-Y",
      "volume": "53",
      "author": "Macklin W. J.",
      "year": "1992",
      "journal-title": "J. Solid State Ionics"
    },
    {
      "key": "jp9908404b00025/jp9908404b00025_1",
      "doi-asserted-by": "crossref",
      "first-page": "7392",
      "DOI": "10.1021/j100131a004",
      "volume": "97",
      "author": "Lantz J. M.",
      "year": "1993",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "jp9908404b00026/jp9908404b00026_1",
      "doi-asserted-by": "crossref",
      "first-page": "57",
      "DOI": "10.1016/0010-8545(86)85009-3",
      "volume": "69",
      "author": "Kalaysundaram K.",
      "year": "1986",
      "journal-title": "Coord. Chem. Rev."
    },
    {
      "key": "jp9908404b00027/jp9908404b00027_1",
      "doi-asserted-by": "crossref",
      "first-page": "303",
      "DOI": "10.1016/0001-8686(78)85002-7",
      "volume": "9",
      "author": "Healy T. W.",
      "year": "1978",
      "journal-title": "Colloid Interface Sci."
    }
  ],
  "container-title": "The Journal of Physical Chemistry B",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.acs.org/doi/pdf/10.1021/jp9908404",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        3,
        5
      ]
    ],
    "date-time": "2023-03-05T13:36:58Z",
    "timestamp": 1678023418000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.acs.org/doi/10.1021/jp9908404"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1999,
        5,
        7
      ]
    ]
  },
  "references-count": 31,
  "journal-issue": {
    "issue": "22",
    "published-print": {
      "date-parts": [
        [
          1999,
          6,
          1
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1021/jp9908404"
  ],
  "URL": "http://dx.doi.org/10.1021/jp9908404",
  "relation": {},
  "ISSN": [
    "1520-6106",
    "1520-5207"
  ],
  "subject": [],
  "container-title-short": "J. Phys. Chem. B",
  "published": {
    "date-parts": [
      [
        1999,
        5,
        7
      ]
    ]
  }
}