DOI: 10.1021/jp076106z. Kinetic and Mechanistic Studies of the Electrocatalytic Reduction of O<sub>2</sub> to H<sub>2</sub>O with Mononuclear Cu Complexes of Substituted 1,10-Phenanthrolines

Kinetic and Mechanistic Studies of the Electrocatalytic Reduction of O2 to H2O with Mononuclear Cu Complexes of Substituted 1,10-Phenanthrolines

10.1021/jp076106z

Crossref journal-article

American Chemical Society (ACS)

The Journal of Physical Chemistry A (316)

Bibliography

McCrory, C. C. L., Ottenwaelder, X., Stack, T. D. P., & Chidsey, C. E. D. (2007). Kinetic and Mechanistic Studies of the Electrocatalytic Reduction of O2 to H2O with Mononuclear Cu Complexes of Substituted 1,10-Phenanthrolines. The Journal of Physical Chemistry A, 111(49), 12641â12650.

Authors 4

Charles C. L. McCrory (first)
Xavier Ottenwaelder (additional)
T. Daniel P. Stack (additional)
Christopher E. D. Chidsey (additional)

References 33 Referenced 99

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{'key': 'jp076106zb00007/jp076106zb00007_1', 'first-page': '5009', 'volume': '33', 'author': 'Lei Y.', 'year': '1994', 'journal-title': 'Inorg. Chem.'} / Inorg. Chem. by Lei Y. (1994)
{'key': 'jp076106zb00008/jp076106zb00008_1', 'first-page': '1089', 'volume': '34', 'author': 'Lei Y.', 'year': '1995', 'journal-title': 'Inorg. Chem.'} / Inorg. Chem. by Lei Y. (1995)
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The kinetic current due to O2reduction to H2O2at −150 mV vs NHE at a 0.195 cm2electrode in a standard pH 4.8, 20 mM AcO-/20 mM AcOH buffer solution was determined from a Koutecky−Levich analysis to be −26 μA. Upon adsorption of ca. 5 × 10-10mol/cm2of Cu(phen) to the same electrode, the resulting kinetic current due to O2reduction to H2O was determined to be −347 μA, so the kinetic current due to O2reduction to H2O2was ca. 8%. Similarly, Anson and colleagues reported less than 6% peroxide generation at -60 mV vs. NHE and fast rotations rates at EPG electrodes with adsorbed Cu(phen) (ref 8).
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Dates

Type	When
Created	17 years, 8 months ago (Dec. 12, 2007, 6 p.m.)
Deposited	3 years, 11 months ago (Sept. 23, 2021, 11:56 p.m.)
Indexed	2 months ago (June 24, 2025, 8:24 a.m.)
Issued	17 years, 8 months ago (Dec. 1, 2007)
Published	17 years, 8 months ago (Dec. 1, 2007)
Published Online	17 years, 8 months ago (Dec. 6, 2007)
Published Print	17 years, 8 months ago (Dec. 1, 2007)

Funders 0

None

BibTeX

@article{McCrory_2007, title={Kinetic and Mechanistic Studies of the Electrocatalytic Reduction of O2 to H2O with Mononuclear Cu Complexes of Substituted 1,10-Phenanthrolines}, volume={111}, ISSN={1520-5215}, url={http://dx.doi.org/10.1021/jp076106z}, DOI={10.1021/jp076106z}, number={49}, journal={The Journal of Physical Chemistry A}, publisher={American Chemical Society (ACS)}, author={McCrory, Charles C. L. and Ottenwaelder, Xavier and Stack, T. Daniel P. and Chidsey, Christopher E. D.}, year={2007}, month=dec, pages={12641–12650} }

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