DOI: 10.1021/ja960036k. Synthesis and Structure of a Trigonal Monopyramidal Fe(II) Complex and Its Paramagnetic Carbon Monoxide Derivative

Synthesis and Structure of a Trigonal Monopyramidal Fe(II) Complex and Its Paramagnetic Carbon Monoxide Derivative

10.1021/ja960036k

Crossref journal-article

American Chemical Society (ACS)

Journal of the American Chemical Society (316)

Bibliography

Ray, M., Golombek, A. P., Hendrich, M. P., Young, V. G., & Borovik, A. S. (1996). Synthesis and Structure of a Trigonal Monopyramidal Fe(II) Complex and Its Paramagnetic Carbon Monoxide Derivative. Journal of the American Chemical Society, 118(25), 6084â6085.

Authors 5

Manabendra Ray (first)
Adina P. Golombek (additional)
Michael P. Hendrich (additional)
Victor G. Young, (additional)
A. S. Borovik (additional)

References 23 Referenced 43

{'key': 'ja960036kb00001/ja960036kb00001_1', 'first-page': '886', 'author': 'Structurally', 'year': '1973', 'journal-title': 'J. Chem. Soc., Chem. Commun.'} / J. Chem. Soc., Chem. Commun. by Structurally (1973)
10.1021/ic00080a033 / Inorg. Chem. by dal Fe (1994)
10.1021/ar00045a004 / J. Acc. Chem. Res. by For (1994)
10.1021/ja00032a061 / J. Am. Chem. Soc. by Examples (1992)
10.1021/je60079a006 / J. Chem. Eng. Data by Barnes D. J. (1978)
Yield: 60%; FTIR (Nujol, cm-1), ν(NH) 3316 (s); ν(CO) 1676 (sh), 1658 (s), 1631 (s);1H NMR (CDCl3, 400 MHz, TMS) δ 7.04 (d, 3 H, NH), 4.08 (m, 3 H, (CH3)2CH), 3.24 (s, 6 H, −CH2), 1.18 (d, 18 H, (CH3)2CH); mp 146−147 °C (uncorrected); MH+m/e315 (CI, isobutane).
Anal. Calcd (Found) for K[Fe1iPr]·DMF, C18H34FeKN5O4: C, 45.09 (45.42); H, 7.15 (7.00); N, 14.61 (14.53). IR (Nujol, cm-1), ν(CO) 1679 (DMF, s), 1593 (amide, s); λmax(DMF) 343 (2500 M-1cm-1); μeff= 5.38μB(solid, 298 K), μeff= 4.98μB[(CD3)2SO, 298 K].
{'key': 'ja960036kb00008/ja960036kb00008_1', 'volume-title': 'b = 10.3589(8) Å, and c = 14.2889(11) Å', 'author': 'Fe'} / b = 10.3589(8) Å, and c = 14.2889(11) Å by Fe
10.1002/anie.199515121 / Angew. Chem., Int. Ed. Engl. by Lubben M. (1995)
10.1021/ja00137a024 / J. Am. Chem. Soc. by The (1995)
10.1021/ja00267a028 / J. Am. Chem. Soc. by Gearing” (1986)
{'key': 'ja960036kb00014/ja960036kb00014_1', 'volume-title': 'C19H36FeKN5O6:\u2009 C, 43.43(43.35)', 'author': 'Fe CO.', 'year': '1940'} / C19H36FeKN5O6: C, 43.43(43.35) by Fe CO. (1940)
10.1073/pnas.78.10.5919 / Proc. Natl. Acad. Sci. U.S.A. by Busch D. H. (1981)
10.1021/ja00518a047 / J. Am. Chem. Soc. by Caron C. (1979)
10.1016/S0022-328X(00)88569-1 / J. Organomet. Chem. by Calderazzo F. (1980)
10.1021/ja00016a023 / J. Am. Chem. Soc. by Kim K. (1991)
Hawker, P. N.; Twigg, M. V. InComprehensive Coordination Chemistry; Wilkinson, G., Guillard, R. D., McCleverty, J. A., Eds.; Pergamon Press: New York, 1987; Vol. 4, pp 1213−1214.
{'key': 'ja960036kb00018/ja960036kb00018_1', 'volume-title': 'Physical Methods in Inorganic Chemistry', 'author': 'Drago R.', 'year': '1977'} / Physical Methods in Inorganic Chemistry by Drago R. (1977)
Greenwood, N. N.; Gibb, T. C.Mössbauer Spectroscopy; Chapman and Hall, New York, 1971; p 205. (10.1007/978-94-009-5697-1)
10.1021/ja00843a015 / J. Am. Chem. Soc. by Collman J. P. (1975)
10.1016/0076-6879(93)27019-D / Methods Enzymol. by Münck E. (1993)
{'key': 'ja960036kb00024/ja960036kb00024_1', 'volume': '62', 'author': 'The', 'year': '1985', 'journal-title': 'J. Chem. Educ.'} / J. Chem. Educ. by The (1985)
10.1126/science.7638619 / Science by For (1995)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 1:02 a.m.)
Deposited	3 years, 10 months ago (Oct. 17, 2021, 3:24 a.m.)
Indexed	4 months ago (April 30, 2025, 4:05 a.m.)
Issued	29 years, 8 months ago (Jan. 1, 1996)
Published	29 years, 8 months ago (Jan. 1, 1996)
Published Online	29 years, 2 months ago (June 26, 1996)
Published Print	29 years, 8 months ago (Jan. 1, 1996)

Funders 0

None

BibTeX

@article{Ray_1996,_Borovik_1996, title={Synthesis and Structure of a Trigonal Monopyramidal Fe(II) Complex and Its Paramagnetic Carbon Monoxide Derivative}, volume={118}, ISSN={1520-5126}, url={http://dx.doi.org/10.1021/ja960036k}, DOI={10.1021/ja960036k}, number={25}, journal={Journal of the American Chemical Society}, publisher={American Chemical Society (ACS)}, author={Ray, Manabendra and Golombek, Adina P. and Hendrich, Michael P. and Young, Victor G. and Borovik, A. S.}, year={1996}, month=jan, pages={6084–6085} }

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