DOI: 10.1021/ja905242r. A Ring-Opening Metathesis Polymerization Route to Alkaline Anion Exchange Membranes: Development of Hydroxide-Conducting Thin Films from an Ammonium-Functionalized Monomer

A Ring-Opening Metathesis Polymerization Route to Alkaline Anion Exchange Membranes: Development of Hydroxide-Conducting Thin Films from an Ammonium-Functionalized Monomer

10.1021/ja905242r

Crossref journal-article

American Chemical Society (ACS)

Journal of the American Chemical Society (316)

Bibliography

Clark, T. J., Robertson, N. J., Kostalik IV, H. A., Lobkovsky, E. B., Mutolo, P. F., AbruÃ±a, H. D., & Coates, G. W. (2009). A Ring-Opening Metathesis Polymerization Route to Alkaline Anion Exchange Membranes: Development of Hydroxide-Conducting Thin Films from an Ammonium-Functionalized Monomer. Journal of the American Chemical Society, 131(36), 12888â12889.

Authors 7

Timothy J. Clark (first)
Nicholas J. Robertson (additional)
Henry A. Kostalik IV (additional)
Emil B. Lobkovsky (additional)
Paul F. Mutolo (additional)
Héctor D. Abruña (additional)
Geoffrey W. Coates (additional)

References 22 Referenced 227

{'key': 'ref1/cit1a', 'volume-title': 'Fuel Cell Handbook', 'author': 'Appleby A. J.', 'year': '1989'} / Fuel Cell Handbook by Appleby A. J. (1989)
10.1021/cr020705e / Chem. Rev. by Whittingham M. S. (2004)
10.1021/ie0501172 / Ind. Eng. Chem. Res. by Lee C. H. (2005)
10.1016/j.memsci.2003.12.021 / J. Membr. Sci. by Gil M. (2004)
10.1016/S0013-4686(02)00344-4 / Electrochim. Acta by Thomas S. C. (2002)
10.1002/fuce.200400045 / Fuel Cells by Varcoe J. R. (2005)
10.1021/cm062407u / Chem. Mater. by Varcoe J. R. (2007)
10.1021/cm703263n / Chem. Mater. by Hibbs M. R. (2008)
10.1016/j.memsci.2009.01.038 / J. Membr. Sci. by Wang G. (2009)
10.1016/j.jpowsour.2008.12.127 / J. Power Sources by Zhou J. (2009)
10.1002/9783527619481 / Handbook of Metathesis by Grubbs R. H. (2003)
10.1021/ar000114f / Acc. Chem. Res. by Trnka T. M. (2001)
10.1002/anie.200600680 / Angew. Chem., Int. Ed. by Grubbs R. H. (2006)
It has been reported that [BnMe3N+][OH−] exhibits negligible degradation in 1 M sodium hydroxide at 80 °C over 29 days:
{'key': 'ref9/cit9a', 'first-page': '1173', 'volume': '11', 'author': 'Einsla B. R.', 'year': '2007', 'journal-title': 'Electrochem. Soc. Trans'} / Electrochem. Soc. Trans by Einsla B. R. (2007)
Other possible hydroxide ion induced means of degradation with Me4N+have recently been described including nucleophilic substitution at a methyl substituent and ylide formation at the nitrogen atom that must also be carefully considered:
10.1021/jp7115577 / J. Phys. Chem. C by Chempath S. (2008)
10.1016/0011-9164(90)85002-R / Desalination by Bauer B. (1990)
10.1016/0376-7388(95)00292-8 / J. Membr. Sci. by Sata T. (1996)
10.1021/ma900389n / Macromolecules by Chen L. (2009)
10.1021/cm049083z / Chem. Mater. by Schmeisser J. (2005)
10.1021/ja064391e / J. Am. Chem. Soc. by Zhou Z. (2006)

Dates

Type	When
Created	16 years ago (Aug. 21, 2009, 10:13 a.m.)
Deposited	2 years, 5 months ago (March 14, 2023, 10:46 a.m.)
Indexed	2 months, 3 weeks ago (June 10, 2025, 3:47 a.m.)
Issued	16 years ago (Aug. 21, 2009)
Published	16 years ago (Aug. 21, 2009)
Published Online	16 years ago (Aug. 21, 2009)
Published Print	15 years, 11 months ago (Sept. 16, 2009)

Funders 0

None

BibTeX

@article{Clark_2009, title={A Ring-Opening Metathesis Polymerization Route to Alkaline Anion Exchange Membranes: Development of Hydroxide-Conducting Thin Films from an Ammonium-Functionalized Monomer}, volume={131}, ISSN={1520-5126}, url={http://dx.doi.org/10.1021/ja905242r}, DOI={10.1021/ja905242r}, number={36}, journal={Journal of the American Chemical Society}, publisher={American Chemical Society (ACS)}, author={Clark, Timothy J. and Robertson, Nicholas J. and Kostalik IV, Henry A. and Lobkovsky, Emil B. and Mutolo, Paul F. and Abruña, Héctor D. and Coates, Geoffrey W.}, year={2009}, month=aug, pages={12888–12889} }

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