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journal-article
American Chemical Society (ACS)
Journal of the American Chemical Society (316)
References
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Referenced
579
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- In an attempt to maximize porphyrin loading intorho-ZMOF, 1.198 mmole of 4,5-H3ImDC, 0.5 mmole of In(NO3)3·xH2O, 30 μmol of [H2TMPyP][p-tosyl]4, DMF, and ethanol (3 mL each) were mixed in a 25 mL scintillation vial. The vial was then heated using the same procedure for the synthesis of1. The resultant crystals,1′, were washed several times with methanol until no residual porphyrin was present. A 10.8 mg portion of1′ was dissolved in 25 mL of concd HNO3, from which 1 mL was diluted to the volume of 10 mL using DI water. Using atomic absorption to determine concentration of In3+ions and UV−vis for porphyrin (ϵ438= 1.9 × 105M−1cm−1), an estimate of 67% loading of porphyrin into the α-cages (each made of 24 In3+ions) was possible. Further increase of the free-base porphyrin concentration in the reaction mixture precludes formation of crystalline material.
- Oxidation reaction conditions: 77 μmol TBHP, dried over MgSO4, 100 μmol chlorobenzene as internal standard, 10 mL cyclohexane, and 88 mg of1a(equivalent to 2.9 μmol of Mn-TMPyP) were mixed, under aerobic conditions, in a 25 mL round-bottom flask fitted with a silicone septum. The reaction mixture was then held at 65°C in an isothermal bath for the required amount of time, as determined by analyzing aliquots of the mixture over time using GC-FID.
Dates
| Type | When |
|---|---|
| Created | 17 years ago (Aug. 29, 2008, 3:01 a.m.) |
| Deposited | 2 years, 5 months ago (March 7, 2023, 5:38 a.m.) |
| Indexed | 1 month ago (July 31, 2025, 11:48 p.m.) |
| Issued | 17 years ago (Aug. 29, 2008) |
| Published | 17 years ago (Aug. 29, 2008) |
| Published Online | 17 years ago (Aug. 29, 2008) |
| Published Print | 16 years, 11 months ago (Sept. 24, 2008) |
@article{Alkordi_2008, title={Zeolite-like Metal−Organic Frameworks as Platforms for Applications: On Metalloporphyrin-Based Catalysts}, volume={130}, ISSN={1520-5126}, url={http://dx.doi.org/10.1021/ja804703w}, DOI={10.1021/ja804703w}, number={38}, journal={Journal of the American Chemical Society}, publisher={American Chemical Society (ACS)}, author={Alkordi, Mohamed H. and Liu, Yunling and Larsen, Randy W. and Eubank, Jarrod F. and Eddaoudi, Mohamed}, year={2008}, month=aug, pages={12639–12641} }