DOI: 10.1021/ja303560c. Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis

10.1021/ja303560c

Crossref journal-article

American Chemical Society (ACS)

Journal of the American Chemical Society (316)

Bibliography

Costentin, C., Drouet, S., Robert, M., & SavÃ©ant, J.-M. (2012). Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis. Journal of the American Chemical Society, 134(27), 11235â11242.

Authors 4

Cyrille Costentin (first)
Samuel Drouet (additional)
Marc Robert (additional)
Jean-Michel Savéant (additional)

References 21 Referenced 739

10.1073/pnas.0603395103 / Proc. Natl. Acad. Sci. U.S.A. by Lewis N. S. (2006)
10.1021/ic060984e / Inorg. Chem. by Felton G. A. N. (2006)
10.1021/cr068079z / Chem. Rev. by Savéant J.-M. (2008)
10.1039/B804323J / Chem. Soc. Rev. by Benson E. E. (2009)
10.1021/ar9001526 / Acc. Chem. Res. by Concepcion J. J. (2009)
10.1021/ar900110c / Acc. Chem. Res. by DuBois R. M. (2009)
10.1039/B801796B / Chem. Soc. Rev. by Gloaguen F. (2009)
10.1002/anie.201007987 / Angew. Chem., Int. Ed. by Artero V. (2011)
10.1002/anie.201103616 / Angew. Chem., Int. Ed. by Bourrez M. (2011)
10.1039/c2ee03250c / Energy Environ. Sci. by Du P. (2012)
10.1021/ja067876b / J. Am. Chem. Soc. by Hu X. (2007)
10.1021/ja210661k / J. Am. Chem. Soc. by McCrory C. C. L. (2012)
Savéant, J.M.Elements of Molecular and Biomolecular Electrochemistry;Wiley-Interscience:New York, 2006; Chap. 2, pp132–136. (10.1002/0471758078)
aSavéant, J.M.; Vianello, E.InAdvances in Polarography;Longmuir, I. S., Ed.Pergamon Press:London, 1960; pp367–374.
10.1016/0022-0728(84)80125-4 / J. Electroanal. Chem. by Savéant J.-M. (1984)
10.1016/0013-4686(65)80003-2 / Electrochim. Acta by Savéant J.-M. (1965)
dReference13, pp 108–119.
10.1021/ja9534462 / J. Am. Chem. Soc. by Bhugun I. (1996)
10.1016/0022-0728(95)04512-0 / J. Electroanal. Chem. by Bhugun I. (1996)
aThe current oscillations that appear in front of the catalytic current rise in Figure7a, indicating that the resistance between the working and reference electrodes, which is not compensated by the potentiostat, is minimized(22b)(seeSI).
bReference13, Chap. 1, pp 14–20; Chap. 6, pp 353–361.

Dates

Type	When
Created	13 years, 2 months ago (June 6, 2012, 1:59 p.m.)
Deposited	2 years, 4 months ago (April 22, 2023, 7:31 p.m.)
Indexed	51 minutes ago (Aug. 30, 2025, 6:14 a.m.)
Issued	13 years, 2 months ago (June 27, 2012)
Published	13 years, 2 months ago (June 27, 2012)
Published Online	13 years, 2 months ago (June 27, 2012)
Published Print	13 years, 1 month ago (July 11, 2012)

Funders 0

None

BibTeX

@article{Costentin_2012, title={Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis}, volume={134}, ISSN={1520-5126}, url={http://dx.doi.org/10.1021/ja303560c}, DOI={10.1021/ja303560c}, number={27}, journal={Journal of the American Chemical Society}, publisher={American Chemical Society (ACS)}, author={Costentin, Cyrille and Drouet, Samuel and Robert, Marc and Savéant, Jean-Michel}, year={2012}, month=jun, pages={11235–11242} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        30
      ]
    ],
    "date-time": "2025-08-30T10:14:32Z",
    "timestamp": 1756548872625
  },
  "reference-count": 21,
  "publisher": "American Chemical Society (ACS)",
  "issue": "27",
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2012,
        7,
        11
      ]
    ]
  },
  "DOI": "10.1021/ja303560c",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2012,
        6,
        6
      ]
    ],
    "date-time": "2012-06-06T17:59:17Z",
    "timestamp": 1339005557000
  },
  "page": "11235-11242",
  "source": "Crossref",
  "is-referenced-by-count": 739,
  "title": "Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis",
  "prefix": "10.1021",
  "volume": "134",
  "author": [
    {
      "given": "Cyrille",
      "family": "Costentin",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Laboratoire\rd\u2019Electrochimie Mol\u00e9culaire,\rUnit\u00e9 Mixte de Recherche Universit\u00e9\u2212CNRS No.\r7591, Universit\u00e9 Paris Diderot,\rSorbonne Paris Cit\u00e9, B\u00e2timent Lavoisier, 15 rue Jean\rde Ba\u00eff, 75205 Paris Cedex 13, France"
        }
      ]
    },
    {
      "given": "Samuel",
      "family": "Drouet",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Laboratoire\rd\u2019Electrochimie Mol\u00e9culaire,\rUnit\u00e9 Mixte de Recherche Universit\u00e9\u2212CNRS No.\r7591, Universit\u00e9 Paris Diderot,\rSorbonne Paris Cit\u00e9, B\u00e2timent Lavoisier, 15 rue Jean\rde Ba\u00eff, 75205 Paris Cedex 13, France"
        }
      ]
    },
    {
      "given": "Marc",
      "family": "Robert",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Laboratoire\rd\u2019Electrochimie Mol\u00e9culaire,\rUnit\u00e9 Mixte de Recherche Universit\u00e9\u2212CNRS No.\r7591, Universit\u00e9 Paris Diderot,\rSorbonne Paris Cit\u00e9, B\u00e2timent Lavoisier, 15 rue Jean\rde Ba\u00eff, 75205 Paris Cedex 13, France"
        }
      ]
    },
    {
      "given": "Jean-Michel",
      "family": "Sav\u00e9ant",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Laboratoire\rd\u2019Electrochimie Mol\u00e9culaire,\rUnit\u00e9 Mixte de Recherche Universit\u00e9\u2212CNRS No.\r7591, Universit\u00e9 Paris Diderot,\rSorbonne Paris Cit\u00e9, B\u00e2timent Lavoisier, 15 rue Jean\rde Ba\u00eff, 75205 Paris Cedex 13, France"
        }
      ]
    }
  ],
  "member": "316",
  "published-online": {
    "date-parts": [
      [
        2012,
        6,
        27
      ]
    ]
  },
  "reference": [
    {
      "key": "ref1/cit1",
      "doi-asserted-by": "crossref",
      "first-page": "15729",
      "DOI": "10.1073/pnas.0603395103",
      "volume": "103",
      "author": "Lewis N. S.",
      "year": "2006",
      "journal-title": "Proc. Natl. Acad. Sci. U.S.A."
    },
    {
      "key": "ref2/cit2",
      "doi-asserted-by": "crossref",
      "first-page": "9181",
      "DOI": "10.1021/ic060984e",
      "volume": "45",
      "author": "Felton G. A. N.",
      "year": "2006",
      "journal-title": "Inorg. Chem."
    },
    {
      "key": "ref3/cit3",
      "doi-asserted-by": "crossref",
      "first-page": "2348",
      "DOI": "10.1021/cr068079z",
      "volume": "108",
      "author": "Sav\u00e9ant J.-M.",
      "year": "2008",
      "journal-title": "Chem. Rev."
    },
    {
      "key": "ref4/cit4",
      "doi-asserted-by": "crossref",
      "first-page": "89",
      "DOI": "10.1039/B804323J",
      "volume": "38",
      "author": "Benson E. E.",
      "year": "2009",
      "journal-title": "Chem. Soc. Rev."
    },
    {
      "key": "ref5/cit5",
      "doi-asserted-by": "crossref",
      "first-page": "1954",
      "DOI": "10.1021/ar9001526",
      "volume": "42",
      "author": "Concepcion J. J.",
      "year": "2009",
      "journal-title": "Acc. Chem. Res."
    },
    {
      "key": "ref6/cit6",
      "doi-asserted-by": "crossref",
      "first-page": "1974",
      "DOI": "10.1021/ar900110c",
      "volume": "42",
      "author": "DuBois R. M.",
      "year": "2009",
      "journal-title": "Acc. Chem. Res."
    },
    {
      "key": "ref7/cit7",
      "doi-asserted-by": "crossref",
      "first-page": "100",
      "DOI": "10.1039/B801796B",
      "volume": "38",
      "author": "Gloaguen F.",
      "year": "2009",
      "journal-title": "Chem. Soc. Rev."
    },
    {
      "key": "ref8/cit8",
      "doi-asserted-by": "crossref",
      "first-page": "7238",
      "DOI": "10.1002/anie.201007987",
      "volume": "50",
      "author": "Artero V.",
      "year": "2011",
      "journal-title": "Angew. Chem., Int. Ed."
    },
    {
      "key": "ref9/cit9",
      "doi-asserted-by": "crossref",
      "first-page": "9903",
      "DOI": "10.1002/anie.201103616",
      "volume": "50",
      "author": "Bourrez M.",
      "year": "2011",
      "journal-title": "Angew. Chem., Int. Ed."
    },
    {
      "key": "ref10/cit10",
      "doi-asserted-by": "crossref",
      "first-page": "6012",
      "DOI": "10.1039/c2ee03250c",
      "volume": "5",
      "author": "Du P.",
      "year": "2012",
      "journal-title": "Energy Environ. Sci."
    },
    {
      "key": "ref12/cit12a",
      "doi-asserted-by": "crossref",
      "first-page": "8988",
      "DOI": "10.1021/ja067876b",
      "volume": "129",
      "author": "Hu X.",
      "year": "2007",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "ref12/cit12b",
      "doi-asserted-by": "crossref",
      "first-page": "3164",
      "DOI": "10.1021/ja210661k",
      "volume": "134",
      "author": "McCrory C. C. L.",
      "year": "2012",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "ref13/cit13",
      "doi-asserted-by": "crossref",
      "unstructured": "Sav\u00e9ant, J.M.Elements of Molecular and Biomolecular Electrochemistry;Wiley-Interscience:New York, 2006; Chap. 2, pp132\u2013136.",
      "DOI": "10.1002/0471758078"
    },
    {
      "key": "ref16/cit16a",
      "unstructured": "aSav\u00e9ant, J.M.; Vianello, E.InAdvances in Polarography;Longmuir, I. S., Ed.Pergamon Press:London, 1960; pp367\u2013374."
    },
    {
      "key": "ref16/cit16b",
      "doi-asserted-by": "crossref",
      "first-page": "341",
      "DOI": "10.1016/0022-0728(84)80125-4",
      "volume": "171",
      "author": "Sav\u00e9ant J.-M.",
      "year": "1984",
      "journal-title": "J. Electroanal. Chem."
    },
    {
      "key": "ref16/cit16c",
      "doi-asserted-by": "crossref",
      "first-page": "905",
      "DOI": "10.1016/0013-4686(65)80003-2",
      "volume": "10",
      "author": "Sav\u00e9ant J.-M.",
      "year": "1965",
      "journal-title": "Electrochim. Acta"
    },
    {
      "key": "ref16/cit16d",
      "unstructured": "dReference13, pp 108\u2013119."
    },
    {
      "key": "ref19/cit19",
      "doi-asserted-by": "crossref",
      "first-page": "1769",
      "DOI": "10.1021/ja9534462",
      "volume": "118",
      "author": "Bhugun I.",
      "year": "1996",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "ref20/cit20",
      "doi-asserted-by": "crossref",
      "first-page": "5",
      "DOI": "10.1016/0022-0728(95)04512-0",
      "volume": "408",
      "author": "Bhugun I.",
      "year": "1996",
      "journal-title": "J. Electroanal. Chem."
    },
    {
      "key": "ref22/cit22a",
      "unstructured": "aThe current oscillations that appear in front of the catalytic current rise in Figure7a, indicating that the resistance between the working and reference electrodes, which is not compensated by the potentiostat, is minimized(22b)(seeSI)."
    },
    {
      "key": "ref22/cit22b",
      "unstructured": "bReference13, Chap. 1, pp 14\u201320; Chap. 6, pp 353\u2013361."
    }
  ],
  "container-title": "Journal of the American Chemical Society",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.acs.org/doi/pdf/10.1021/ja303560c",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        4,
        22
      ]
    ],
    "date-time": "2023-04-22T23:31:56Z",
    "timestamp": 1682206316000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.acs.org/doi/10.1021/ja303560c"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2012,
        6,
        27
      ]
    ]
  },
  "references-count": 21,
  "journal-issue": {
    "issue": "27",
    "published-print": {
      "date-parts": [
        [
          2012,
          7,
          11
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1021/ja303560c"
  ],
  "URL": "http://dx.doi.org/10.1021/ja303560c",
  "relation": {},
  "ISSN": [
    "0002-7863",
    "1520-5126"
  ],
  "subject": [],
  "container-title-short": "J. Am. Chem. Soc.",
  "published": {
    "date-parts": [
      [
        2012,
        6,
        27
      ]
    ]
  }
}