DOI: 10.1021/ja102030w. Triple-Stranded Metallo-Helicates Addressable as Lloyd’s Electron Spin Qubits

Triple-Stranded Metallo-Helicates Addressable as Lloyd’s Electron Spin Qubits

10.1021/ja102030w

Crossref journal-article

American Chemical Society (ACS)

Journal of the American Chemical Society (316)

Bibliography

Morita, Y., Yakiyama, Y., Nakazawa, S., Murata, T., Ise, T., Hashizume, D., Shiomi, D., Sato, K., Kitagawa, M., Nakasuji, K., & Takui, T. (2010). Triple-Stranded Metallo-Helicates Addressable as Lloydâs Electron Spin Qubits. Journal of the American Chemical Society, 132(20), 6944â6946.

Authors 11

Yasushi Morita (first)
Yumi Yakiyama (additional)
Shigeaki Nakazawa (additional)
Tsuyoshi Murata (additional)
Tomoaki Ise (additional)
Daisuke Hashizume (additional)
Daisuke Shiomi (additional)
Kazunobu Sato (additional)
Masahiro Kitagawa (additional)
Kazuhiro Nakasuji (additional)
Takeji Takui (additional)

References 32 Referenced 66

{'key': 'ref1/cit1a', 'volume-title': 'Proceedings, 35th Annual Symposium on Foundations of Computer Science', 'author': 'Shor P. W.', 'year': '1994'} / Proceedings, 35th Annual Symposium on Foundations of Computer Science by Shor P. W. (1994)
10.1007/978-94-015-8839-3 / Mesoscopic Electron Transport, NATO ASI Series E by Sohn L. (1997)
10.1103/PhysRevLett.90.153001 / Phys. Rev. Lett. by Mehring M. (2003)
10.1103/PhysRevLett.93.206603 / Phys. Rev. Lett. by Mehring M. (2004)
10.1103/PhysRevA.79.042335 / Phys. Rev. A by Wang H. (2009)
aA thematic issue on “molecular spintronics and quantum computing” has recently been published in:
J. Mater. Chem.2009,19,1661−1768. (10.1039/b903881g)
10.1063/1.3266959 / J. Chem. Phys. by Kassal I. (2009)
10.1038/nchem.483 / Nature Chem. by Lanyon B. P. (2010)
10.1142/S0219749905001377 / Int. J. Quantum Inf. by Rahimi R. (2005)
10.1016/j.physe.2007.06.031 / Physica E by Sato K. (2007)
10.1039/b819556k / J. Mater. Chem. by Sato K. (2009)
10.1038/scientificamerican1095-140 / Sci. Am. by Lloyd S. (1995)
10.1039/b208777d / J. Chem. Soc., Perkin Trans. 1 by Morita Y. (2002)
10.1246/cl.2004.188 / Chem. Lett. by Morita Y. (2004)
10.1021/cg0600602 / Cryst. Growth Des. by Murata T. (2006)
10.1021/cg800202n / Cryst. Growth Des. by Murata T. (2008)
Experimental evidence of the formations of triple-stranded dinuclear metallo-helicates7ofQimwith Mn(II) and Zn(II) in solution and solid states is described in theSupporting Information.
Metallo-helicate: a supramolecular metal complex having helical structure; see:
aLehn, J.M.Supramolecular Chemistry-Concepts and Perspectives; VCH:Weinheim, 1995. (10.1002/3527607439)
10.1021/cr960053s / Chem. Rev. by Piguet C. (1997)
10.1021/cr0103672 / Chem. Rev. by Albrecht M. (2001)
10.1039/b212352e / Dalton Trans. by Ouali N. (2003)
10.1038/35071024 / Nature by Leuenberger M. (2001)
O−H···O or O−H···Cl type hydrogen bonds connect helicates to construct one-dimensional chain structures. See:
10.1039/b308963k / Chem. Commun. by Lavalette A. (2003)
The observed hyperfine structure shows line-broadening effects attributable to the nonvanishing fine-structure tensors. The effects arise from the departure from complete octahedral symmetry at the Mn(II) sites; note that the complete symmetry with the sextet state gives only a single ESR fine-structure transition due to vanishing fine-structure parameters.
{'key': 'ref12/cit12', 'volume-title': 'Electron Spin Resonance: A Comprehensive Treatise on Experimental Techniques', 'author': 'Poole C. P., Jr.', 'year': '1967'} / Electron Spin Resonance: A Comprehensive Treatise on Experimental Techniques by Poole C. P., Jr. (1967)
10.1002/jcc.1056 / J. Comput. Chem. by te Velde G. (2001)
10.1021/jp963060t / J. Phys. Chem. A by Schreckenbach G. (1997)
Further studies on metallo-helicates with different metal centers and π-extended ligandSimwill be reported elsewhere.
Optical resolutions of the helicates ofQimhave been achieved. Detailed experimental results will be published soon.

Dates

Type	When
Created	15 years, 3 months ago (May 3, 2010, 7:26 a.m.)
Deposited	2 years, 5 months ago (March 9, 2023, 7:40 p.m.)
Indexed	1 year, 1 month ago (July 6, 2024, 4:31 a.m.)
Issued	15 years, 3 months ago (May 3, 2010)
Published	15 years, 3 months ago (May 3, 2010)
Published Online	15 years, 3 months ago (May 3, 2010)
Published Print	15 years, 2 months ago (May 26, 2010)

Funders 0

None

BibTeX

@article{Morita_2010, title={Triple-Stranded Metallo-Helicates Addressable as Lloyd’s Electron Spin Qubits}, volume={132}, ISSN={1520-5126}, url={http://dx.doi.org/10.1021/ja102030w}, DOI={10.1021/ja102030w}, number={20}, journal={Journal of the American Chemical Society}, publisher={American Chemical Society (ACS)}, author={Morita, Yasushi and Yakiyama, Yumi and Nakazawa, Shigeaki and Murata, Tsuyoshi and Ise, Tomoaki and Hashizume, Daisuke and Shiomi, Daisuke and Sato, Kazunobu and Kitagawa, Masahiro and Nakasuji, Kazuhiro and Takui, Takeji}, year={2010}, month=may, pages={6944–6946} }

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