DOI: 10.1021/ja067876b. Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocyclic Glyoxime and Tetraimine Complexes

Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocyclic Glyoxime and Tetraimine Complexes

10.1021/ja067876b

Crossref journal-article

American Chemical Society (ACS)

Journal of the American Chemical Society (316)

Bibliography

Hu, X., Brunschwig, B. S., & Peters, J. C. (2007). Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocyclic Glyoxime and Tetraimine Complexes. Journal of the American Chemical Society, 129(29), 8988â8998.

Authors 3

Xile Hu (first)
Bruce S. Brunschwig (additional)
Jonas C. Peters (additional)

References 31 Referenced 651

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{'key': 'ja067876bb00002/ja067876bb00002_1', 'first-page': '126', 'volume-title': 'Structure and Bonding', 'volume': '90', 'author': 'Adams M. W. W.', 'year': '1997'} / Structure and Bonding by Adams M. W. W. (1997)
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{'key': 'ja067876bb00006/ja067876bb00006_1', 'first-page': '3983', 'volume': '118', 'author': 'Bhugun I.', 'year': '1996', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. by Bhugun I. (1996)
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{'key': 'ja067876bb00009/ja067876bb00009_1', 'first-page': '366', 'volume': '128', 'author': 'Wilson A. D.', 'year': '2006', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. by Wilson A. D. (2006)
{'key': 'ja067876bb00010/ja067876bb00010_1', 'first-page': '4725', 'volume': '4723', 'author': 'Hu X. L.', 'year': '2005', 'journal-title': 'Chem. Commun.'} / Chem. Commun. by Hu X. L. (2005)
{'key': 'ja067876bb00011/ja067876bb00011_1', 'first-page': '2688', 'volume': '25', 'author': 'Connolly P.', 'year': '1986', 'journal-title': 'Inorg. Chem.'} / Inorg. Chem. by Connolly P. (1986)
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10.1016/0022-0728(84)80125-4 / J. Electroanal. Chem. by Saveant J. M. (1984)
Tait, A. M.; Busch, D. E. InInorganic Syntheses; Douglas, B. E., Ed.; Wiley-Interscience: New York, 1978; Vol. XVIII, pp 22−26.
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{'key': 'ja067876bb00022/ja067876bb00022_1', 'volume-title': 'Acid-Base Dissociation Constants in Dipolar Aprotic Solvents', 'author': 'Izutsu K.', 'year': '1990'} / Acid-Base Dissociation Constants in Dipolar Aprotic Solvents by Izutsu K. (1990)
{'key': 'ja067876bb00025/ja067876bb00025_1', 'first-page': '4114', 'volume': '25', 'author': 'Bakac A.', 'year': '1986', 'journal-title': 'Inorg. Chem.'} / Inorg. Chem. by Bakac A. (1986)
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We chose a potential of −0.14 V vs Fc/Fc+(i.e., 0.24 V vs SCE using [nBu4](ClO4) as the electrolyte, see ref 30) as the thermodynamic potential for H+/H2in acetonitrile. This potential was determined by Daniele, S., et al. using platinized platinum as the working electrode. A reversible H+/H2couple was observed in acetonitrile, and the potential for this couple corresponds to the true thermodynamic potential for this reaction. It is noted, however, that Parker, V. D., et al. (Acc. Chem. Res.1993,26, 287−294) and DuBois, D. L., et al. (J. Am. Chem. Soc.2004,126, 2738−2743) estimated values of −0.05 V and −0.07 V vs Fc/Fc+, respectively, for H+/H2in acetonitrile, based on the junction potential between aqueous and acetonitrile solutions.
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10.1016/S0003-2670(00)84951-X / Anal. Chim. Acta by Daniele S. (1985)
10.1021/ja00330a027 / J. Am. Chem. Soc. by Bakac A. (1984)

Dates

Type	When
Created	18 years, 1 month ago (June 29, 2007, 1:30 p.m.)
Deposited	3 years, 10 months ago (Oct. 9, 2021, 4:37 a.m.)
Indexed	6 hours, 30 minutes ago (Aug. 23, 2025, 9:31 p.m.)
Issued	18 years, 1 month ago (June 28, 2007)
Published	18 years, 1 month ago (June 28, 2007)
Published Online	18 years, 1 month ago (June 28, 2007)
Published Print	18 years, 1 month ago (July 1, 2007)

Funders 0

None

BibTeX

@article{Hu_2007, title={Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocyclic Glyoxime and Tetraimine Complexes}, volume={129}, ISSN={1520-5126}, url={http://dx.doi.org/10.1021/ja067876b}, DOI={10.1021/ja067876b}, number={29}, journal={Journal of the American Chemical Society}, publisher={American Chemical Society (ACS)}, author={Hu, Xile and Brunschwig, Bruce S. and Peters, Jonas C.}, year={2007}, month=jun, pages={8988–8998} }

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