DOI: 10.1021/ja043460r. Hydrogen Elimination from a Hydroxycyclopentadienyl Ruthenium(II) Hydride: Study of Hydrogen Activation in a Ligand−Metal Bifunctional Hydrogenation Catalyst

Hydrogen Elimination from a Hydroxycyclopentadienyl Ruthenium(II) Hydride: Study of Hydrogen Activation in a Ligand−Metal Bifunctional Hydrogenation Catalyst

10.1021/ja043460r

Crossref journal-article

American Chemical Society (ACS)

Journal of the American Chemical Society (316)

Bibliography

Casey, C. P., Johnson, J. B., Singer, S. W., & Cui, Q. (2005). Hydrogen Elimination from a Hydroxycyclopentadienyl Ruthenium(II) Hydride:â Study of Hydrogen Activation in a LigandâMetal Bifunctional Hydrogenation Catalyst. Journal of the American Chemical Society, 127(9), 3100â3109.

Authors 4

Charles P. Casey (first)
Jeffrey B. Johnson (additional)
Steven W. Singer (additional)
Qiang Cui (additional)

References 40 Referenced 159

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Assumption of ΔS⧧= 5.0 eu extrapolates to a rate constant of 107 × 10-3s-1at 95 °C, while assumption of ΔS⧧= −5.0 eu extrapolates to a rate constant of 69 × 10-3s-1at 95 °C.
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In principle, ruthenium hydride3may also dimerize through metal hydride to acidic proton hydrogen bonding. PGSE studies have indicated that the ruthenium methyl analogue, [2,5-Ph2-3,4-Tol2(η5-C4COH)]Ru(CO)2CH3, also exists as a dimer in toluene, suggesting that dimerization does not involve the metal hydride unit. The structure involving dimerization through hydrogen bonding of OH groups to one another, shown in Figure 8, is also supported by calculations.
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Dates

Type	When
Created	20 years, 6 months ago (March 2, 2005, 12:37 a.m.)
Deposited	3 years, 11 months ago (Sept. 22, 2021, 4 a.m.)
Indexed	2 weeks, 2 days ago (Aug. 20, 2025, 8:47 a.m.)
Issued	20 years, 6 months ago (Feb. 12, 2005)
Published	20 years, 6 months ago (Feb. 12, 2005)
Published Online	20 years, 6 months ago (Feb. 12, 2005)
Published Print	20 years, 5 months ago (March 9, 2005)

Funders 0

None

BibTeX

@article{Casey_2005, title={Hydrogen Elimination from a Hydroxycyclopentadienyl Ruthenium(II) Hydride: Study of Hydrogen Activation in a Ligand−Metal Bifunctional Hydrogenation Catalyst}, volume={127}, ISSN={1520-5126}, url={http://dx.doi.org/10.1021/ja043460r}, DOI={10.1021/ja043460r}, number={9}, journal={Journal of the American Chemical Society}, publisher={American Chemical Society (ACS)}, author={Casey, Charles P. and Johnson, Jeffrey B. and Singer, Steven W. and Cui, Qiang}, year={2005}, month=feb, pages={3100–3109} }

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