DOI: 10.1021/ja021009z. Pushing Up the Size Limit of Chalcogenide Supertetrahedral Clusters: Two- and Three-Dimensional Photoluminescent Open Frameworks from (Cu5In30S54)13-Clusters

Pushing Up the Size Limit of Chalcogenide Supertetrahedral Clusters: Two- and Three-Dimensional Photoluminescent Open Frameworks from (Cu5In30S54)13-Clusters

10.1021/ja021009z

Crossref journal-article

American Chemical Society (ACS)

Journal of the American Chemical Society (316)

Bibliography

Bu, X., Zheng, N., Li, Y., & Feng, P. (2002). Pushing Up the Size Limit of Chalcogenide Supertetrahedral Clusters:â Two- and Three-Dimensional Photoluminescent Open Frameworks from (Cu5In30S54)13-Clusters. Journal of the American Chemical Society, 124(43), 12646â12647.

Authors 4

Xianhui Bu (first)
Nanfeng Zheng (additional)
Yuqi Li (additional)
Pingyun Feng (additional)

References 18 Referenced 131

Dance, I.; Fisher, K. InProgress in Inorganic Chemistry; Karlin, K. D., Ed.; John Wiley & Sons: New York, 1994; Vol. 41, pp 637−803. (10.1002/9780470166420.ch9)
10.1002/anie.199107691 / Angew. Chem., Int. Ed. Engl. by Krebs B. (1991)
Bedard, R. L.; Wilson, S. T.; Vail, L. D.; Bennett, J. M.; Flanigen, E. M. InZeolites: Facts, Figures, Future. Proceedings of the 8thInternationalZeolite Conference; Jacobs, P. A., van Santen, R. A., Eds.; Elsevier: Amsterdam, 1989; p 375. (10.1016/S0167-2991(08)61735-8)
{'key': 'ja021009zb00004/ja021009zb00004_1', 'first-page': '121', 'volume': '4', 'author': 'Scott R. W. J.', 'year': '1999', 'journal-title': 'Curr. Opin. Solid State Mater. Sci.'} / Curr. Opin. Solid State Mater. Sci. by Scott R. W. J. (1999)
10.1146/annurev.physchem.49.1.371 / Annu. Rev. Phys. Chem. by Collier C. P. (1998)
10.1021/ja003598j / J. Am. Chem. Soc. by Soloviev V. N. (2001)
10.1126/science.267.5203.1476 / Science by Vossmeyer T. (1995)
10.1126/science.259.5100.1426 / Science by Herron N. (1993)
10.1021/ja972111c / J. Am. Chem. Soc. by Wehmschulte R. J. (1997)
{'key': 'ja021009zb00010/ja021009zb00010_1', 'first-page': '6868', 'volume': '123', 'author': 'Li H.', 'year': '2001', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. by Li H. (2001)
{'key': 'ja021009zb00011/ja021009zb00011_1', 'first-page': '11507', 'volume': '123', 'author': 'Wang C.', 'year': '2001', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. by Wang C. (2001)
{'key': 'ja021009zb00012/ja021009zb00012_1', 'first-page': '1482', 'volume': '1475', 'author': 'Cahill C. L.', 'year': '2000', 'journal-title': 'J. Chem. Soc., Dalton Trans.'} / J. Chem. Soc., Dalton Trans. by Cahill C. L. (2000)
{'key': 'ja021009zb00013/ja021009zb00013_1', 'first-page': '10269', 'volume': '124', 'author': 'Wang C.', 'year': '2002', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. by Wang C. (2002)
{'key': 'ja021009zb00014/ja021009zb00014_1', 'first-page': '558', 'volume': '557', 'author': 'Hirpo W.', 'year': '1992', 'journal-title': 'J. Chem. Soc., Chem. Commun.'} / J. Chem. Soc., Chem. Commun. by Hirpo W. (1992)
Crystallographic data for UCR-16, (Cu5In30S54)(C13H26N2H2)6.5,C2/c,a= 27.615(9) Å,b= 27.648(9) Å,c= 28.548(9) Å, β = 112.761(6)°,V= 20099(11) Å3,Z= 4, Mo Kα,T= 150 K, 2θmax= 40°,R(F) = 9.44% for 421 parameters and 3464 reflections withI> 2σ(I). Elemental analysis (wt %): 15.34 (calc. 14.76) for C, 2.80 (calc. 2.67) for H, 2.64 (calc. 2.65) for N, 49.17 (calc. 50.11) for In, 4.27 (calc. 4.62) for Cu. Crystallographic data for UCR-17, (Cu5In30S54)(C13H26N2H2)6.5,Fddd,a= 43.266(6) Å,b= 43.467(6) Å,c= 53.721(7) Å,V= 101030(23) Å3,Z= 16, Mo Kα, 2θmax= 45°,R(F) = 7.35% for 415 parameters and 8812 reflections withI> 2σ(I). Electron microprobe elemental analysis (wt %): 48.90 (calc. 50.11) for In, 4.16 (calc. 4.62) for Cu. UCR-17 has a body-centered pseudotetragonal cell witha= 30.665(3) Å andc= 53.721(7) Å. In both UCR-16 and -17, all framework atoms are unambiguously located, but amine molecules are disordered.
{'key': 'ja021009zb00016/ja021009zb00016_1', 'first-page': 'C34', 'volume': '46', 'author': 'Spek A. L.', 'year': '1990', 'journal-title': 'Acta Crystallogr.'} / Acta Crystallogr. by Spek A. L. (1990)
{'key': 'ja021009zb00017/ja021009zb00017_1', 'first-page': '1961', 'volume': '41', 'author': 'Wang C.', 'year': '2002', 'journal-title': 'Angew. Chem.'} / Angew. Chem. by Wang C. (2002)
{'key': 'ja021009zb00018/ja021009zb00018_1', 'first-page': '1669', 'volume': '1668', 'author': 'Feng P.', 'year': '2001', 'journal-title': 'Chem. Commun.'} / Chem. Commun. by Feng P. (2001)

Dates

Type	When
Created	22 years, 10 months ago (Oct. 23, 2002, 1:07 a.m.)
Deposited	1 year, 7 months ago (Jan. 7, 2024, 10:29 a.m.)
Indexed	1 month ago (July 22, 2025, 6:46 a.m.)
Issued	22 years, 10 months ago (Oct. 1, 2002)
Published	22 years, 10 months ago (Oct. 1, 2002)
Published Online	22 years, 10 months ago (Oct. 5, 2002)
Published Print	22 years, 10 months ago (Oct. 1, 2002)

Funders 0

None

BibTeX

@article{Bu_2002, title={Pushing Up the Size Limit of Chalcogenide Supertetrahedral Clusters: Two- and Three-Dimensional Photoluminescent Open Frameworks from (Cu5In30S54)13-Clusters}, volume={124}, ISSN={1520-5126}, url={http://dx.doi.org/10.1021/ja021009z}, DOI={10.1021/ja021009z}, number={43}, journal={Journal of the American Chemical Society}, publisher={American Chemical Society (ACS)}, author={Bu, Xianhui and Zheng, Nanfeng and Li, Yuqi and Feng, Pingyun}, year={2002}, month=oct, pages={12646–12647} }

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