DOI: 10.1021/ja0024744. Thermally Activated, Inverted Interfacial Electron Transfer Kinetics: High Driving Force Reactions between Tin Oxide Nanoparticles and Electrostatically-Bound Molecular Reactants

Thermally Activated, Inverted Interfacial Electron Transfer Kinetics: High Driving Force Reactions between Tin Oxide Nanoparticles and Electrostatically-Bound Molecular Reactants

10.1021/ja0024744

Crossref journal-article

American Chemical Society (ACS)

Journal of the American Chemical Society (316)

Bibliography

Gaal, D. A., & Hupp, J. T. (2000). Thermally Activated, Inverted Interfacial Electron Transfer Kinetics:â High Driving Force Reactions between Tin Oxide Nanoparticles and Electrostatically-Bound Molecular Reactants. Journal of the American Chemical Society, 122(44), 10956â10963.

Authors 2

Dennis A. Gaal (first)
Joseph T. Hupp (additional)

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Using the 1600 cm-1mode in the nonclassical activation enthalpy calculations produces similar results: an activation enthalpy of 8 kJ mol-1was calculated assuming an entropic driving force of −192 J deg-1mol-1, an activation enthalpy of 5 kJ mol-1for ΔS= −96 J deg-1mol-1, but only 2 kJ mol-1assuming ΔS= 0.

Dates

Type	When
Created	23 years ago (July 26, 2002, 1:57 a.m.)
Deposited	3 years, 11 months ago (Sept. 23, 2021, 10:54 a.m.)
Indexed	2 months, 2 weeks ago (June 6, 2025, 4:27 a.m.)
Issued	24 years, 10 months ago (Oct. 21, 2000)
Published	24 years, 10 months ago (Oct. 21, 2000)
Published Online	24 years, 10 months ago (Oct. 21, 2000)
Published Print	24 years, 9 months ago (Nov. 1, 2000)

Funders 0

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BibTeX

@article{Gaal_2000, title={Thermally Activated, Inverted Interfacial Electron Transfer Kinetics: High Driving Force Reactions between Tin Oxide Nanoparticles and Electrostatically-Bound Molecular Reactants}, volume={122}, ISSN={1520-5126}, url={http://dx.doi.org/10.1021/ja0024744}, DOI={10.1021/ja0024744}, number={44}, journal={Journal of the American Chemical Society}, publisher={American Chemical Society (ACS)}, author={Gaal, Dennis A. and Hupp, Joseph T.}, year={2000}, month=oct, pages={10956–10963} }

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