DOI: 10.1021/ic034873g. A Robust Microporous Zinc Porphyrin Framework Solid

A Robust Microporous Zinc Porphyrin Framework Solid

10.1021/ic034873g

Crossref journal-article

American Chemical Society (ACS)

Inorganic Chemistry (316)

Bibliography

Smithenry, D. W., Wilson, S. R., & Suslick, K. S. (2003). A Robust Microporous Zinc Porphyrin Framework Solid. Inorganic Chemistry, 42(24), 7719â7721.

Authors 3

Dennis W. Smithenry (first)
Scott R. Wilson (additional)
Kenneth S. Suslick (additional)

References 19 Referenced 116

10.1038/nmat730 / Nat. Mater. by Kosal M. E. (2002)
10.1021/ar000034b / Acc. Chem. Res. by Eddaoudi M. (2001)
{'key': 'ic034873gb00003/ic034873gb00003_1', 'first-page': '3054', 'volume': '39', 'author': 'Zaworotko M.', 'year': '2000', 'journal-title': 'J. Angew. Chem., Int. Ed.'} / J. Angew. Chem., Int. Ed. by Zaworotko M. (2000)
10.1039/a704290f / Chem. Soc. Rev. by Langley P. J. (1999)
{'key': 'ic034873gb00005/ic034873gb00005_1', 'first-page': '161', 'volume': '198', 'author': 'Aoyama Y.', 'year': '1998', 'journal-title': 'Top. Curr. Chem.'} / Top. Curr. Chem. by Aoyama Y. (1998)
{'key': 'ic034873gb00006/ic034873gb00006_1', 'volume-title': 'Metalloporphrins in Catalytic Oxidations', 'author': 'Sheldon R.', 'year': '1994'} / Metalloporphrins in Catalytic Oxidations by Sheldon R. (1994)
{'key': 'ic034873gb00007/ic034873gb00007_1', 'volume-title': 'Catalysis by Metal Complexes', 'volume': '17', 'author': 'Meunier', 'year': '1994'} / Catalysis by Metal Complexes by Meunier (1994)
{'key': 'ic034873gb00008/ic034873gb00008_1', 'volume-title': 'The Porphyrin Handbook', 'volume': '4', 'author': 'Suslick K.', 'year': '2000'} / The Porphyrin Handbook by Suslick K. (2000)
10.1021/ja971093w / J. Am. Chem. Soc. by Bhyrappa P. (1997)
10.1142/S1088424602000464 / J. Porphyrins Phthalocyanines by Kosal M. E. (2002)
10.1002/(SICI)1099-1409(200006/07)4:4<407::AID-JPP256>3.0.CO;2-5 / J. Porphyrins Phthalocyanines by Suslick K. S. (2000)
{'key': 'ic034873gb00012/ic034873gb00012_1', 'first-page': '732', 'volume': '6', 'author': 'Byrn M. P.', 'year': '1996', 'journal-title': 'Compr. Supramol. Chem.'} / Compr. Supramol. Chem. by Byrn M. P. (1996)
10.1039/b202190k / CrystEngComm. by Goldberg I. (2002)
10.1002/1521-3765(20001103)6:21<3863::AID-CHEM3863>3.0.CO;2-V / Chem. Eur. J. by Goldberg I. (2000)
10.1126/science.1067208 / Science by Eddaoudi M. (2002)
{'key': 'ic034873gb00017/ic034873gb00017_1', 'volume-title': 'Germany', 'year': '1997'} / Germany (1997)
Crystal data for PIZA-4: cubicFd3̄,a= 51.1237(12) Å,V= 133619(5) Å3,Z= 16, calculated density = 0.561 g/cm3, R1 = 0.1922, wR2 = 0.4629, Cu Kα (1.54178 Å), μ = 0.768 mm-1. In the single crystal structure, the Zn4O clusters of the host framework were well ordered; however, the porphyrin links suffered from considerable libration in addition to modeled and suspected solvate disorder. No crystals examined diffracted beyond 1.5 Å resolution, most likely due to the large amount of disordered solvate in the host framework. All efforts to refine more complex disordered models as well as efforts to refine discrete framework models in nonisomorphous subgroups cascading down to F1 failed to improve the model chemically. Benzoate, pyrrole, and mesityl moieties were refined as rigid idealized groups. Positions for solvate atoms were so severely disordered that no discrete model for solvate molecules surfaced in difference Fourier maps. The proposed structural model was refined with contributions from the solvate molecules removed from the diffraction data using the bypass procedure in PLATON.23The electron count from the “squeeze” model converged in good agreement with the number of solvate molecules predicted by TGA results on the as-synthesized solvated crystals. The space group choice was confirmed by successful convergence of the full-matrix least-squares refinement onF2.
10.1021/cr00032a005 / Chem. Rev. by Reichardt C. (1994)
Van der Sluis, P.; Spek, A. L.Acta Crystallogr., Sect. A: Found.Crystallogr.1990,A46, 194−201. (10.1107/S0108767389011189)

Dates

Type	When
Created	21 years, 8 months ago (Nov. 24, 2003, 12:37 a.m.)
Deposited	3 years, 10 months ago (Sept. 23, 2021, 11:53 a.m.)
Indexed	4 weeks, 1 day ago (July 23, 2025, 8:41 a.m.)
Issued	21 years, 9 months ago (Oct. 31, 2003)
Published	21 years, 9 months ago (Oct. 31, 2003)
Published Online	21 years, 9 months ago (Oct. 31, 2003)
Published Print	21 years, 8 months ago (Dec. 1, 2003)

Funders 0

None

BibTeX

@article{Smithenry_2003, title={A Robust Microporous Zinc Porphyrin Framework Solid}, volume={42}, ISSN={1520-510X}, url={http://dx.doi.org/10.1021/ic034873g}, DOI={10.1021/ic034873g}, number={24}, journal={Inorganic Chemistry}, publisher={American Chemical Society (ACS)}, author={Smithenry, Dennis W. and Wilson, Scott R. and Suslick, Kenneth S.}, year={2003}, month=oct, pages={7719–7721} }

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