DOI: 10.1021/ic0257219. Ferromagnetism and Chirality in Two-Dimensional Cyanide-Bridged Bimetallic Compounds

Ferromagnetism and Chirality in Two-Dimensional Cyanide-Bridged Bimetallic Compounds

10.1021/ic0257219

Crossref journal-article

American Chemical Society (ACS)

Inorganic Chemistry (316)

Bibliography

Coronado, E., GÃ³mez-GarcÃa, C. J., Nuez, A., Romero, F. M., Rusanov, E., & Stoeckli-Evans, H. (2002). Ferromagnetism and Chirality in Two-Dimensional Cyanide-Bridged Bimetallic Compounds. Inorganic Chemistry, 41(18), 4615â4617.

Authors 6

Eugenio Coronado (first)
Carlos J. Gómez-García (additional)
Alicia Nuez (additional)
Francisco M. Romero (additional)
Eduard Rusanov (additional)
Helen Stoeckli-Evans (additional)

References 20 Referenced 129

(a) Universitat de València.
(b) Université de Neuchâtel.
Coronado, E., Delhaès, P., Gatteschi, D., Miller, J. S., Eds. Molecular Magnetism: From Molecular Assemblies to the Devices; NATO ASI Series E321; Kluwer Academic Publishers: Dordrecht, 1996. (10.1007/978-94-017-2319-0)
10.1016/S0010-8545(00)00233-2
10.1038/35044035
10.1021/ja0002619
10.1038/37323
10.1021/ic00020a029
10.1021/ic980306v
10.1021/ic9904135
10.1021/ic0008870
10.1002/(SICI)1521-3773(19990601)38:11%3C1601::AID-ANIE1601%3E3.0.CO;2-%23
10.1002/1521-3773(20020215)41:4%3C586::AID-ANIE586%3E3.0.CO;2-6
While our work was in progress, a 3D cyanide-bridged Cr−Mn system based on chiral propane-1,2-diamine was reported: Inoue, K.; Imai, H.; Ghalsasi, P. S.; Kikuchi, K.; Ohba, M.; Okawa, H.; Yakhmi, J. V. Angew. Chem. Int. Ed.2001, 40, 4242−4245.10.1002/1521-3773(20011119)40:22%3C4242:AID-ANIE4242%3E3.0.CO;2-H (10.1002/1521-3773(20011119)40:22%3C4242::AID-ANIE4242%3E3.0.CO;2-H)
10.1016/S0020-1693(96)05525-9
10.1002/1099-0682(200207)2002:7%3C1603::AID-EJIC1603%3E3.0.CO;2-T
Single crystals of compounds 1 and 2 were grown by slow diffusion of the precursors in a water/acetonitrile mixture. Anal. Calcd for C48H88Fe2N24Ni3O2 (1): C, 43.64; H, 6.71; N, 25.44. Found: C, 43.56; H, 6.49; N, 25.26. IR (KBr, cm-1): ν = 3339, 3277 (N−H); 2919, 2847 (C−H); 2105 (C⋮N). Anal. Calcd for C48H88Fe2N24Ni3O2 (2): C, 43.64; H, 6.71; N, 25.44. Found: C, 43.46; H, 6.63; N, 25.34. IR (KBr, cm-1): ν = 3334, 3283 (N−H); 2924, 2858 (C−H); 2105 (C⋮N).
Crystallographic data for 1: C48H88Fe2Ni3N24O2, M = 1321.25, P1, a = 9.0917(8) Å, b = 12.6682(12) Å, c = 14.9606(14) Å, α = 99.107(11)°, β = 93.897(11)°, γ = 109.239(11)°, V = 1593.0(3) Å3, Z = 1, ρcalcd = 1.377 Mg m-3. λ(Mo Kα) = 0.71073 Å, T = 153(2) K. R1 (I > 2σ(I)) = 0.0329, wR2 = 0.0583 (all data) with R1 = ∑||Fo| − |Fc||/∑|Fo| and wR2 = (∑w(Fo2 − Fc2)2/∑w(Fo2)2)0.5. The absolute structure parameter was −0.02(2). Crystallographic data for 2: C48H88Fe2Ni3N24O2, M = 1321.25, P1, a = 9.0858(10) Å, b = 12.6638(15) Å, c = 14.9822(16) Å, α = 98.900(10)°, β = 93.950(10)°, γ = 109.45(10)°, V = 1592.4(3) Å3, Z = 1, ρcalcd = 1.378 Mg m-3. λ(Mo Kα) = 0.71073 Å, T = 153(2) K, μ = 1.371 mm-1, R1 (I > 2σ(I)) = 0.0604, wR2 = 0.1507 (all data) with R1 = ∑||Fo| − |Fc||/∑|Fo| and wR2 = (∑w(Fo2 − Fc2)2/∑w(Fo2)2)0.5. The absolute crystal structure was determined by the Flack method (Flack number = 0.00(4)).
Closely related structures with (12, 3) topology in which the [Fe(CN)6]3- anions binds to three adjacent nickel centers, either in fac or mer arrangements, have been reported in similar 2D bimetallic systems: Kou, H.Z.; Gao, S.; Bu, W.M.; Liao, D.Z.; Ma, B.Q.; Jiang, Z.H.; Yan, S.P.; Fan, Y.G.; Wang G−L. J. Chem. Soc., Dalton. Trans.1999, 2477−2480. Kou, H.Z.; Bu, W.M.; Gao, S.; Liao, D.Z.; Jiang, Z.H.; Yan, S.P.; Fan, Y.G.; Wang, G.L.J. Chem. Soc., Dalton. Trans.2000, 2996−3000.
10.1016/S0304-8853(98)00180-2

Dates

Type	When
Created	23 years ago (Sept. 3, 2002, 12:44 a.m.)
Deposited	1 year, 1 month ago (July 23, 2024, 12:16 p.m.)
Indexed	1 year, 1 month ago (July 23, 2024, 12:42 p.m.)
Issued	23 years ago (Aug. 13, 2002)
Published	23 years ago (Aug. 13, 2002)
Published Online	23 years ago (Aug. 13, 2002)
Published Print	23 years ago (Sept. 1, 2002)

Funders 0

None

BibTeX

@article{Coronado_2002, title={Ferromagnetism and Chirality in Two-Dimensional Cyanide-Bridged Bimetallic Compounds}, volume={41}, ISSN={1520-510X}, url={http://dx.doi.org/10.1021/ic0257219}, DOI={10.1021/ic0257219}, number={18}, journal={Inorganic Chemistry}, publisher={American Chemical Society (ACS)}, author={Coronado, Eugenio and Gómez-García, Carlos J. and Nuez, Alicia and Romero, Francisco M. and Rusanov, Eduard and Stoeckli-Evans, Helen}, year={2002}, month=aug, pages={4615–4617} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        7,
        23
      ]
    ],
    "date-time": "2024-07-23T16:42:51Z",
    "timestamp": 1721752971944
  },
  "reference-count": 20,
  "publisher": "American Chemical Society (ACS)",
  "issue": "18",
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2002,
        9,
        1
      ]
    ]
  },
  "DOI": "10.1021/ic0257219",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        9,
        3
      ]
    ],
    "date-time": "2002-09-03T04:44:31Z",
    "timestamp": 1031028271000
  },
  "page": "4615-4617",
  "source": "Crossref",
  "is-referenced-by-count": 129,
  "title": "Ferromagnetism and Chirality in Two-Dimensional Cyanide-Bridged Bimetallic Compounds",
  "prefix": "10.1021",
  "volume": "41",
  "author": [
    {
      "given": "Eugenio",
      "family": "Coronado",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Instituto de Ciencia Molecular, Universitat de Val\u00e8ncia, Dr. Moliner 50, 46100 Burjassot, Spain,\rand Institut de Chimie, Universit\u00e9 de Neuch\u00e2tel, Avenue de Bellevaux, 51,\r2000 Neuch\u00e2tel, Switzerland"
        }
      ]
    },
    {
      "given": "Carlos J.",
      "family": "G\u00f3mez-Garc\u00eda",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Instituto de Ciencia Molecular, Universitat de Val\u00e8ncia, Dr. Moliner 50, 46100 Burjassot, Spain,\rand Institut de Chimie, Universit\u00e9 de Neuch\u00e2tel, Avenue de Bellevaux, 51,\r2000 Neuch\u00e2tel, Switzerland"
        }
      ]
    },
    {
      "given": "Alicia",
      "family": "Nuez",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Instituto de Ciencia Molecular, Universitat de Val\u00e8ncia, Dr. Moliner 50, 46100 Burjassot, Spain,\rand Institut de Chimie, Universit\u00e9 de Neuch\u00e2tel, Avenue de Bellevaux, 51,\r2000 Neuch\u00e2tel, Switzerland"
        }
      ]
    },
    {
      "given": "Francisco M.",
      "family": "Romero",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Instituto de Ciencia Molecular, Universitat de Val\u00e8ncia, Dr. Moliner 50, 46100 Burjassot, Spain,\rand Institut de Chimie, Universit\u00e9 de Neuch\u00e2tel, Avenue de Bellevaux, 51,\r2000 Neuch\u00e2tel, Switzerland"
        }
      ]
    },
    {
      "given": "Eduard",
      "family": "Rusanov",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Instituto de Ciencia Molecular, Universitat de Val\u00e8ncia, Dr. Moliner 50, 46100 Burjassot, Spain,\rand Institut de Chimie, Universit\u00e9 de Neuch\u00e2tel, Avenue de Bellevaux, 51,\r2000 Neuch\u00e2tel, Switzerland"
        }
      ]
    },
    {
      "given": "Helen",
      "family": "Stoeckli-Evans",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Instituto de Ciencia Molecular, Universitat de Val\u00e8ncia, Dr. Moliner 50, 46100 Burjassot, Spain,\rand Institut de Chimie, Universit\u00e9 de Neuch\u00e2tel, Avenue de Bellevaux, 51,\r2000 Neuch\u00e2tel, Switzerland"
        }
      ]
    }
  ],
  "member": "316",
  "published-online": {
    "date-parts": [
      [
        2002,
        8,
        13
      ]
    ]
  },
  "reference": [
    {
      "key": "ic0257219b00001/ic0257219b00001_1",
      "unstructured": "(a) Universitat de Val\u00e8ncia."
    },
    {
      "key": "ic0257219b00001/ic0257219b00001_2",
      "unstructured": "(b) Universit\u00e9 de Neuch\u00e2tel."
    },
    {
      "key": "ic0257219b00002/ic0257219b00002_1",
      "doi-asserted-by": "crossref",
      "unstructured": "Coronado, E., Delha\u00e8s, P., Gatteschi, D., Miller, J. S., Eds.   Molecular Magnetism:\u2009 From Molecular Assemblies to the Devices; NATO ASI Series E321; Kluwer Academic Publishers:\u2009 Dordrecht, 1996.",
      "DOI": "10.1007/978-94-017-2319-0"
    },
    {
      "key": "ic0257219b00003/ic0257219b00003_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0010-8545(00)00233-2"
    },
    {
      "key": "ic0257219b00004/ic0257219b00004_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/35044035"
    },
    {
      "key": "ic0257219b00005/ic0257219b00005_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja0002619"
    },
    {
      "key": "ic0257219b00006/ic0257219b00006_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/37323"
    },
    {
      "key": "ic0257219b00007/ic0257219b00007_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic00020a029"
    },
    {
      "key": "ic0257219b00007/ic0257219b00007_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic980306v"
    },
    {
      "key": "ic0257219b00007/ic0257219b00007_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic9904135"
    },
    {
      "key": "ic0257219b00007/ic0257219b00007_4",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic0008870"
    },
    {
      "key": "ic0257219b00007/ic0257219b00007_5",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/(SICI)1521-3773(19990601)38:11%3C1601::AID-ANIE1601%3E3.0.CO;2-%23"
    },
    {
      "key": "ic0257219b00007/ic0257219b00007_6",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/1521-3773(20020215)41:4%3C586::AID-ANIE586%3E3.0.CO;2-6"
    },
    {
      "key": "ic0257219b00008/ic0257219b00008_1",
      "doi-asserted-by": "publisher",
      "unstructured": "While our work was in progress, a 3D cyanide-bridged Cr\u2212Mn system based on chiral propane-1,2-diamine was reported:\u2009 Inoue, K.; Imai, H.; Ghalsasi, P. S.; Kikuchi, K.; Ohba, M.; Okawa, H.; Yakhmi, J. V.  Angew. Chem. Int. Ed.2001, 40, 4242\u22124245.10.1002/1521-3773(20011119)40:22%3C4242:AID-ANIE4242%3E3.0.CO;2-H",
      "DOI": "10.1002/1521-3773(20011119)40:22%3C4242::AID-ANIE4242%3E3.0.CO;2-H"
    },
    {
      "key": "ic0257219b00009/ic0257219b00009_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0020-1693(96)05525-9"
    },
    {
      "key": "ic0257219b00010/ic0257219b00010_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/1099-0682(200207)2002:7%3C1603::AID-EJIC1603%3E3.0.CO;2-T"
    },
    {
      "key": "ic0257219b00011/ic0257219b00011_1",
      "unstructured": "Single crystals of compounds 1 and 2 were grown by slow diffusion of the precursors in a water/acetonitrile mixture. Anal. Calcd for C48H88Fe2N24Ni3O2 (1):\u2009 C, 43.64; H, 6.71; N, 25.44. Found:\u2009 C, 43.56; H, 6.49; N, 25.26. IR (KBr, cm-1):\u2009 \u03bd = 3339, 3277 (N\u2212H); 2919, 2847 (C\u2212H); 2105 (C\u22eeN). Anal. Calcd for C48H88Fe2N24Ni3O2 (2):\u2009 C, 43.64; H, 6.71; N, 25.44. Found:\u2009 C, 43.46; H, 6.63; N, 25.34. IR (KBr, cm-1):\u2009 \u03bd = 3334, 3283 (N\u2212H); 2924, 2858 (C\u2212H); 2105 (C\u22eeN)."
    },
    {
      "key": "ic0257219b00012/ic0257219b00012_1",
      "unstructured": "Crystallographic data for 1:\u2009 C48H88Fe2Ni3N24O2, M = 1321.25, P1, a = 9.0917(8) \u00c5, b = 12.6682(12) \u00c5, c = 14.9606(14) \u00c5, \u03b1 = 99.107(11)\u00b0, \u03b2 = 93.897(11)\u00b0, \u03b3 = 109.239(11)\u00b0, V = 1593.0(3) \u00c53, Z = 1, \u03c1calcd = 1.377 Mg m-3. \u03bb(Mo K\u03b1) = 0.71073 \u00c5, T = 153(2) K. R1 (I > 2\u03c3(I)) = 0.0329, wR2 = 0.0583 (all data) with R1 = \u2211||Fo| \u2212 |Fc||/\u2211|Fo| and wR2 = (\u2211w(Fo2 \u2212 Fc2)2/\u2211w(Fo2)2)0.5. The absolute structure parameter was \u22120.02(2). Crystallographic data for 2:\u2009 C48H88Fe2Ni3N24O2, M = 1321.25, P1, a = 9.0858(10) \u00c5, b = 12.6638(15) \u00c5, c = 14.9822(16) \u00c5, \u03b1 = 98.900(10)\u00b0, \u03b2 = 93.950(10)\u00b0, \u03b3 = 109.45(10)\u00b0, V = 1592.4(3) \u00c53, Z = 1, \u03c1calcd = 1.378 Mg m-3. \u03bb(Mo K\u03b1) = 0.71073 \u00c5, T = 153(2) K, \u03bc = 1.371 mm-1, R1 (I > 2\u03c3(I)) = 0.0604, wR2 = 0.1507 (all data) with R1 = \u2211||Fo| \u2212 |Fc||/\u2211|Fo| and wR2 = (\u2211w(Fo2 \u2212 Fc2)2/\u2211w(Fo2)2)0.5. The absolute crystal structure was determined by the Flack method (Flack number = 0.00(4))."
    },
    {
      "key": "ic0257219b00013/ic0257219b00013_1",
      "unstructured": "Closely related structures with (12, 3) topology in which the [Fe(CN)6]3- anions binds to three adjacent nickel centers, either in fac or mer arrangements, have been reported in similar 2D bimetallic systems:\u2009 Kou, H.Z.; Gao, S.; Bu, W.M.; Liao, D.Z.; Ma, B.Q.; Jiang, Z.H.; Yan, S.P.; Fan, Y.G.; Wang G\u2212L.   J. Chem. Soc., Dalton. Trans.1999, 2477\u22122480. Kou, H.Z.; Bu, W.M.; Gao, S.; Liao, D.Z.; Jiang, Z.H.; Yan, S.P.; Fan, Y.G.; Wang, G.L.J. Chem. Soc., Dalton. Trans.2000, 2996\u22123000."
    },
    {
      "key": "ic0257219b00014/ic0257219b00014_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0304-8853(98)00180-2"
    }
  ],
  "container-title": "Inorganic Chemistry",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.acs.org/doi/pdf/10.1021/ic0257219",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        7,
        23
      ]
    ],
    "date-time": "2024-07-23T16:16:17Z",
    "timestamp": 1721751377000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.acs.org/doi/10.1021/ic0257219"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2002,
        8,
        13
      ]
    ]
  },
  "references-count": 20,
  "journal-issue": {
    "issue": "18",
    "published-print": {
      "date-parts": [
        [
          2002,
          9,
          1
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1021/ic0257219"
  ],
  "URL": "http://dx.doi.org/10.1021/ic0257219",
  "relation": {},
  "ISSN": [
    "0020-1669",
    "1520-510X"
  ],
  "subject": [],
  "container-title-short": "Inorg. Chem.",
  "published": {
    "date-parts": [
      [
        2002,
        8,
        13
      ]
    ]
  }
}