DOI: 10.1021/cm7022136. New Ambipolar Organic Semiconductors. 2. Effects of Electron Acceptor Strength on Intramolecular Charge Transfer Photophysics, Highly Efficient Electroluminescence, and Field-Effect Charge Transport of Phenoxazine-Based Donor−Acceptor Materials

New Ambipolar Organic Semiconductors. 2. Effects of Electron Acceptor Strength on Intramolecular Charge Transfer Photophysics, Highly Efficient Electroluminescence, and Field-Effect Charge Transport of Phenoxazine-Based Donor−Acceptor Materials

10.1021/cm7022136

Crossref journal-article

American Chemical Society (ACS)

Chemistry of Materials (316)

Bibliography

Kulkarni, A. P., Zhu, Y., Babel, A., Wu, P.-T., & Jenekhe, S. A. (2008). New Ambipolar Organic Semiconductors. 2. Effects of Electron Acceptor Strength on Intramolecular Charge Transfer Photophysics, Highly Efficient Electroluminescence, and Field-Effect Charge Transport of Phenoxazine-Based DonorâAcceptor Materials. Chemistry of Materials, 20(13), 4212â4223.

Authors 5

Abhishek P. Kulkarni (first)
Yan Zhu (additional)
Amit Babel (additional)
Pei-Tzu Wu (additional)
Samson A. Jenekhe (additional)

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The excited state dipole moments were calculated using the relationν̃flu=ν̃flu0−14πε0hc2a03μ⃗e(μ⃗e−μ⃗g)f(ε,n)wheref(ε,n)=ε−12ε+1−12(n2−12n2+1)= solvent polarity parameter νfluis the charge transfer emission maximum (cm−1), νflu0is the charge transfer emission maximum (cm−1) extrapolated to the gas phase,a0is the radius of the Onsager cavity (nm),μ⃗gandμ⃗eare the ground- and excited-state dipole moments (D), respectively, ε is the dielectric constant of the solvent, andnis the refractive index of the solvent. For further details, see ref28a.
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Dates

Type	When
Created	17 years, 3 months ago (June 4, 2008, 4 a.m.)
Deposited	2 years, 6 months ago (March 5, 2023, 6:55 p.m.)
Indexed	2 weeks, 2 days ago (Aug. 21, 2025, 1:20 p.m.)
Issued	17 years, 3 months ago (June 4, 2008)
Published	17 years, 3 months ago (June 4, 2008)
Published Online	17 years, 3 months ago (June 4, 2008)
Published Print	17 years, 1 month ago (July 8, 2008)

Funders 0

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BibTeX

@article{Kulkarni_2008, title={New Ambipolar Organic Semiconductors. 2. Effects of Electron Acceptor Strength on Intramolecular Charge Transfer Photophysics, Highly Efficient Electroluminescence, and Field-Effect Charge Transport of Phenoxazine-Based Donor−Acceptor Materials}, volume={20}, ISSN={1520-5002}, url={http://dx.doi.org/10.1021/cm7022136}, DOI={10.1021/cm7022136}, number={13}, journal={Chemistry of Materials}, publisher={American Chemical Society (ACS)}, author={Kulkarni, Abhishek P. and Zhu, Yan and Babel, Amit and Wu, Pei-Tzu and Jenekhe, Samson A.}, year={2008}, month=jun, pages={4212–4223} }

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