DOI: 10.1021/bp00013a010. Integrated Ozonation‐Biotreatment of Pulp Bleaching Effluents Containing Chlorinated Phenolic Compounds

Integrated Ozonation‐Biotreatment of Pulp Bleaching Effluents Containing Chlorinated Phenolic Compounds

10.1021/bp00013a010

Crossref journal-article

Wiley

Biotechnology Progress (311)

Abstract

AbstractBleaching effluents from pulp and paper industry are problematic because they contain toxic chlorinated phenolic compounds and recalcitrant chlorinated lignin fragments of higher molecular weight. The chlorinated phenolic compounds have been shown to be rather easily removable in fluidized bed bioreactors. The total amount of adsorbable organic halogens (AOX), however, was only reduced by 20%‐30%. It is generally possible to oxidize all unsaturated organic compounds in the bleaching effluents by ozonation. However, ozone is still too expensive to allow complete treatment. Nevertheless, the increase of biodegradability of recalcitrant components by dechlorination and degradation of high molecular weight fractions by ozone can lead to increased efficiency in a subsequent biotreatment. In this study the simple ozonation of bleaching effluents with and without biological pretreatment was compared with sequential or cyclic ozonation—biotreatment schemes. By integrated ozonation—biotreatment, the degradation efficiency relative to the amount of ozone consumed was markedly increased. The overall efficiency of the treatment process in terms of fractional removals of global parameters COD, TOC, and AOX increased. More than 70% of AOX were eliminated. No toxic effect was observed in the cyclic reactor, where the liquid passed was cycling between an ozonation and a biotreatment zone. In the liquid phase no dissolved ozone could be detected in this reactor.

Bibliography

Heinzle, E., Geiger, F., Fahmy, M., & Kut, O. M. (1992). Integrated OzonationâBiotreatment of Pulp Bleaching Effluents Containing Chlorinated Phenolic Compounds. Biotechnology Progress, 8(1), 67â77. Portico.

Authors 4

E. Heinzle (first)
F. Geiger (additional)
M. Fahmy (additional)
O. M. Kut (additional)

References 41 Referenced 41

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10.2166/wst.1991.0478 / Water Sci. Technol. / Membrane filtration combined with biological treatment for purification of bleach plant effluents by Boman B. (1991)
DIN 38409‐H14. Bestimmung der adsorbierbaren organisch gebundenen Halogenen (AOX) (H14). Deutsche Norm. Summarische Wirkungs‐und Stoffkenngrössen (Gruppe H). Deutsche Einheitsverfahren zur Wasser‐ Abwasserund Schlammuntersuchung 1985.
DIN 38409‐H41‐1. Bestimmung des chemischen Sauerstoffbe darfs (CSB) im Bereich über 15 mg/1 (H41). Deutsche Norm. Summarische Wirkungs‐und Stoffkenngrössen (Gruppe H). Deutsche Einheitsverfahren zur Wasser‐ Abwasser‐und Schlammuntersuchung 1981.
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10.2166/wst.1991.0474 / Water Sci. Technol. / Treatment of bleaching effluents in aerobic/anaerobic fluidized biofilm systems by Fahmy M. (1991)
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{'key': 'e_1_2_1_10_1', 'first-page': '275', 'article-title': 'Ueber den Abbau von organischen Schadstoffen im Wasser durch Ozon', 'volume': '43', 'author': 'Gilbert E.', 'year': '1974', 'journal-title': 'Vom Wasser'} / Vom Wasser / Ueber den Abbau von organischen Schadstoffen im Wasser durch Ozon by Gilbert E. (1974)
10.1016/0043-1354(87)90180-1
10.1080/01919518708552336
10.1007/978-1-4684-8556-1_11
{'key': 'e_1_2_1_14_1', 'first-page': '261', 'article-title': 'Determination of ozone and chlorine dioxide in water by the indigo method', 'volume': '55', 'author': 'Hoigne J.', 'year': '1980', 'journal-title': 'Vom Wasser'} / Vom Wasser / Determination of ozone and chlorine dioxide in water by the indigo method by Hoigne J. (1980)
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{'key': 'e_1_2_1_18_1', 'first-page': '221', 'article-title': 'Die Behandlung des Abwassers einer Zellstoff‐und Papierfabrik mittels Ozon und Belebtschlammverfahren', 'volume': '46', 'author': 'Koppe P.', 'year': '1976', 'journal-title': 'Vom Wasser'} / Vom Wasser / Die Behandlung des Abwassers einer Zellstoff‐und Papierfabrik mittels Ozon und Belebtschlammverfahren by Koppe P. (1976)
{'key': 'e_1_2_1_19_1', 'first-page': '207', 'article-title': 'Organische Chlorverbindungen in Bleichabwässern, eine Literaturübersicht', 'volume': '39', 'author': 'Kordsachia O.', 'year': '1985', 'journal-title': 'Papier (Darmstadt)'} / Papier (Darmstadt) / Organische Chlorverbindungen in Bleichabwässern, eine Literaturübersicht by Kordsachia O. (1985)
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Legeron J. P.;Martin G.;Elmghari‐Tabib M.Treatment of wastewaters by the activated sludge method. German Patent DE 3 134 774 April 8 1982.
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{'key': 'e_1_2_1_25_1', 'first-page': '1742', 'article-title': 'Ozone treatment of Kraft mill wastes', 'volume': '50', 'author': 'Ng K. S.', 'year': '1978', 'journal-title': 'J—Water Pollut. Control Fed.'} / J—Water Pollut. Control Fed. / Ozone treatment of Kraft mill wastes by Ng K. S. (1978)
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{'issue': '209', 'key': 'e_1_2_1_28_1', 'first-page': '79', 'article-title': 'Ozone‐treatment of hazardous materials', 'volume': '77', 'author': 'Rice R. G.', 'year': '1981', 'journal-title': 'AICHE Symp. Ser.'} / AICHE Symp. Ser. / Ozone‐treatment of hazardous materials by Rice R. G. (1981)
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{'key': 'e_1_2_1_30_1', 'first-page': '37', 'article-title': 'Pulp bleaching—The race for safer methods', 'volume': '98', 'author': 'Samdani G.', 'year': '1991', 'journal-title': 'Chem. Eng. (Int. Ed.)'} / Chem. Eng. (Int. Ed.) / Pulp bleaching—The race for safer methods by Samdani G. (1991)
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10.1021/es00142a012
10.1080/01919518208550956
{'key': 'e_1_2_1_38_1', 'first-page': '478', 'article-title': 'Pulp and paper effluent management', 'volume': '62', 'author': 'Tirsch F. S.', 'year': '1990', 'journal-title': 'Res. J. Water Pollut. Control Fed.'} / Res. J. Water Pollut. Control Fed. / Pulp and paper effluent management by Tirsch F. S. (1990)
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10.1016/0043-1354(90)90101-B
{'key': 'e_1_2_1_41_1', 'first-page': '320', 'article-title': 'Effects of preozonation on the methanogenic toxicity of 2, 5‐chlorophenol', 'volume': '61', 'author': 'Wang Y.‐T.', 'year': '1989', 'journal-title': 'J. — Water Pollut. Control Fed.'} / J. — Water Pollut. Control Fed. / Effects of preozonation on the methanogenic toxicity of 2, 5‐chlorophenol by Wang Y.‐T. (1989)
{'issue': '8', 'key': 'e_1_2_1_42_1', 'first-page': '46', 'article-title': 'Wet air oxidation—an alternative to incineration', 'volume': '75', 'author': 'Wilhelmi A. R.', 'year': '1979', 'journal-title': 'Chem. Eng. Prog.'} / Chem. Eng. Prog. / Wet air oxidation—an alternative to incineration by Wilhelmi A. R. (1979)

Dates

Type	When
Created	20 years, 5 months ago (March 7, 2005, 9:40 p.m.)
Deposited	1 year, 10 months ago (Oct. 23, 2023, 4:47 a.m.)
Indexed	1 year, 10 months ago (Oct. 27, 2023, 7:28 a.m.)
Issued	33 years, 8 months ago (Jan. 1, 1992)
Published	33 years, 8 months ago (Jan. 1, 1992)
Published Online	17 years ago (Sept. 5, 2008)
Published Print	33 years, 8 months ago (Jan. 1, 1992)

Funders 0

None

BibTeX

@article{Heinzle_1992, title={Integrated Ozonation‐Biotreatment of Pulp Bleaching Effluents Containing Chlorinated Phenolic Compounds}, volume={8}, ISSN={1520-6033}, url={http://dx.doi.org/10.1021/bp00013a010}, DOI={10.1021/bp00013a010}, number={1}, journal={Biotechnology Progress}, publisher={Wiley}, author={Heinzle, E. and Geiger, F. and Fahmy, M. and Kut, O. M.}, year={1992}, month=jan, pages={67–77} }

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  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1992,
        1
      ]
    ]
  },
  "references-count": 41,
  "journal-issue": {
    "issue": "1",
    "published-print": {
      "date-parts": [
        [
          1992,
          1
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1021/bp00013a010"
  ],
  "URL": "http://dx.doi.org/10.1021/bp00013a010",
  "relation": {},
  "ISSN": [
    "8756-7938",
    "1520-6033"
  ],
  "subject": [],
  "container-title-short": "Biotechnology Progress",
  "published": {
    "date-parts": [
      [
        1992,
        1
      ]
    ]
  }
}