DOI: 10.1017/s0885715600009738. Crystal structure determination of molecular compounds from conventional powder diffraction data: Trimeric silver(<i>I</i>) 3,5-dimethylpyrazolate

Crystal structure determination of molecular compounds from conventional powder diffraction data: Trimeric silver(I) 3,5-dimethylpyrazolate

10.1017/s0885715600009738

Crossref journal-article

Cambridge University Press (CUP)

Powder Diffraction (56)

Abstract

In the absence of single crystals, silver(I) 3,5-dimethylpyrazolate, [Ag(dmpz)]3, has been structurally characterized byab initioX-ray powder diffraction, using conventional laboratory data. Its crystals are triclinic,P1¯, witha=8.0876(10),b=11.1204(13),c=11.6136(16) Å, α=68.293(6), β=78.350(7), and γ=81.243(6)°. The structure has been solved by Patterson, difference Fourier, and geometrical modeling, and ultimately refined by the Rietveld method down toRp=0.068,Rwp=0.085, andRF=0.055, for 4300 observations in the 17<2θ<103° range. Each molecule consists of a cyclic, trimeric assembly ofAg(dmpz) fragments, with thedmpzligand bridging, in the exo-bidentate mode, nonbonded Ag…Ag edges.

Bibliography

Masciocchi, N., Cairati, P., & Sironi, A. (1998). Crystal structure determination of molecular compounds from conventional powder diffraction data: Trimeric silver(I) 3,5-dimethylpyrazolate. Powder Diffraction, 13(1), 35â40.

Authors 3

N. Masciocchi (first)
P. Cairati (additional)
A. Sironi (additional)

References 25 Referenced 18

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Dates

Type	When
Created	12 years, 7 months ago (Jan. 10, 2013, 2:12 p.m.)
Deposited	1 year, 3 months ago (May 4, 2024, 11:27 a.m.)
Indexed	1 year, 2 months ago (June 8, 2024, 1:16 a.m.)
Issued	27 years, 6 months ago (March 1, 1998)
Published	27 years, 6 months ago (March 1, 1998)
Published Online	12 years, 7 months ago (Jan. 10, 2013)
Published Print	27 years, 6 months ago (March 1, 1998)

Funders 0

None

BibTeX

@article{Masciocchi_1998, title={Crystal structure determination of molecular compounds from conventional powder diffraction data: Trimeric silver(I) 3,5-dimethylpyrazolate}, volume={13}, ISSN={1945-7413}, url={http://dx.doi.org/10.1017/s0885715600009738}, DOI={10.1017/s0885715600009738}, number={1}, journal={Powder Diffraction}, publisher={Cambridge University Press (CUP)}, author={Masciocchi, N. and Cairati, P. and Sironi, A.}, year={1998}, month=mar, pages={35–40} }

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