DOI: 10.1016/j.nanoen.2019.04.092. Nitrogen-coordinated single Fe sites for efficient electrocatalytic N2 fixation in neutral media

Nitrogen-coordinated single Fe sites for efficient electrocatalytic N2 fixation in neutral media

10.1016/j.nanoen.2019.04.092

Crossref journal-article

Elsevier BV

Nano Energy (78)

Bibliography

LÃ¼, F., Zhao, S., Guo, R., He, J., Peng, X., Bao, H., Fu, J., Han, L., Qi, G., Luo, J., Tang, X., & Liu, X. (2019). Nitrogen-coordinated single Fe sites for efficient electrocatalytic N2 fixation in neutral media. Nano Energy, 61, 420â427.

Authors 12

Fang Lü (first)
Shunzheng Zhao (additional)
Ruijie Guo (additional)
Jia He (additional)
Xianyun Peng (additional)
Haihong Bao (additional)
Jiantao Fu (additional)
Lili Han (additional)
Gaocan Qi (additional)
Jun Luo (additional)
Xiaolong Tang (additional)
Xijun Liu (additional)

References 46 Referenced 390

10.1126/science.345.6197.610 / Science / New recipe produces ammonia from air, water, and sunlight by Service (2014)
10.1021/cr8003696 / Chem. Rev. / Nitrogen cycle electrocatalysis by Rosca (2009)
10.1039/C7EE02220D / Energy Environ. Sci. / Rational design of electrocatalysts and photo(electro)catalysts for nitrogen reduction to ammonia (NH3) under ambient conditions by Guo (2018)
10.1016/j.joule.2018.09.011 / Joule / Efficient electrocatalytic N2 fixation with MXene under ambient conditions by Luo (2019)
{'key': '10.1016/j.nanoen.2019.04.092_bib5', 'first-page': '1800331', 'article-title': 'Defect engineering strategies for nitrogen reduction reactions under ambient conditions', 'author': 'Yan', 'year': '2018', 'journal-title': 'Small Methods'} / Small Methods / Defect engineering strategies for nitrogen reduction reactions under ambient conditions by Yan (2018)
10.1016/j.joule.2018.06.007 / Joule / Boron-doped graphene for electrocatalytic N2 reduction by Yu (2018)
10.1002/adma.201604799 / Adv. Mater. / Electrochemical reduction of N2 under ambient conditions for artificial N2 fixation and renewable energy storage using N2/NH3 cycle by Bao (2017)
{'key': '10.1016/j.nanoen.2019.04.092_bib8', 'first-page': '1800337', 'article-title': 'Advances in electrocatalytic N2 reduction-strategies to tackle the selectivity challenge', 'author': 'Chen', 'year': '2018', 'journal-title': 'Small Methods'} / Small Methods / Advances in electrocatalytic N2 reduction-strategies to tackle the selectivity challenge by Chen (2018)
10.1002/adma.201801526 / Adv. Mater. / Carbon-based metal-free catalysts for key reactions involved in energy conversion and storage by Zhao (2018)
10.1002/adma.201805367 / Adv. Mater. / Carbon-based metal-free catalysts for electrocatalytic reduction of nitrogen for synthesis of ammonia at ambient conditions by Zhao (2019)
10.1002/aenm.201801357 / Adv. Energy Mater. / Boosted electrocatalytic N2 reduction to NH3 by defect-rich MoS2 nanoflower by Li (2018)
10.1002/adma.201800191 / Adv. Mater. / Electrochemical ammonia synthesis via nitrogen reduction reaction on a MoS2 catalyst: theoretical and experimental studies by Zhang (2018)
10.1016/j.nanoen.2018.07.045 / Nano Energy / Ambient N2 fixation to NH3 at ambient conditions: using Nb2O5 nanofiber as a high-performance electrocatalyst by Han (2018)
10.1002/adma.201700001 / Adv. Mater. / Amorphizing of Au nanoparticles by CeOx-GO hybrid support towards highly efficient electrocatalyst for N2 reduction under ambient conditions by Li (2017)
10.1002/adma.201606550 / Adv. Mater. / Au sub-nanoclusters on TiO2 toward highly efficient and selective electrocatalyst for N2 conversion to NH3 at ambient conditions by Shi (2017)
10.1002/adma.201803694 / Adv. Mater. / Molybdenum carbide nanodots enable efficient electrocatalytic nitrogen fixation under ambient conditions by Cheng (2018)
10.1002/anie.201801538 / Angew. Chem. Int. Ed. / An amorphous noble-metal-free electrocatalyst that enables nitrogen fixation under ambient conditions by Lv (2018)
10.1002/anie.201806386 / Angew. Chem. Int. Ed. / Defect engineering metal-free polymeric carbon nitride electrocatalyst for effective nitrogen fixation under ambient conditions by Lv (2018)
10.1038/s41467-018-08120-x / Nat. Commun. / Over 56.55% faradaic efficiency of ambient ammonia synthesis enabled by positively shifting the reaction potential by Wang (2019)
10.1021/acscatal.8b02585 / ACS Catal. / Ambient electrochemical ammonia synthesis with high selectivity on Fe/Fe oxide catalyst by Hu (2018)
10.1021/jacs.7b05372 / J. Am. Chem. Soc. / Metal (hydr)oxides@polymer core-shell strategy to metal single-atom materials by Zhang (2017)
10.1016/j.chempr.2018.05.006 / Chemistry / Room-temperature methane conversion by graphene-confined single Iron atoms by Cui (2018)
10.1021/jacs.8b07294 / J. Am. Chem. Soc. / Edge-site engineering of atomically dispersed Fe-N4 by selective C-N bond cleavage for enhanced oxygen reduction reaction activities by Jiang (2018)
10.1002/adma.201800588 / Adv. Mater. / Fe isolated single atoms on S, N codoped carbon by copolymer pyrolysis strategy for highly efficient oxygen reduction reaction by Li (2018)
10.1002/anie.201706921 / Angew. Chem. Int. Ed. / Potential-cycling synthesis of single platinum atoms for efficient hydrogen evolution in neutral media by Zhang (2017)
10.1002/anie.201712451 / Angew. Chem. Int. Ed. / Regulation of coordination number over single Co sites: triggering the efficient electroreduction of CO2 by Wang (2018)
10.1002/adma.201803498 / Adv. Mater. / Achieving a record-high yield rate of 120.9 for N2 electrochemical reduction over Ru single-atom catalysts by Geng (2018)
{'key': '10.1016/j.nanoen.2019.04.092_bib28', 'first-page': '1800291', 'article-title': 'Single or double: which is the altar of atomic catalysts for nitrogen reduction reaction?', 'author': 'Chen', 'year': '2018', 'journal-title': 'Small Methods'} / Small Methods / Single or double: which is the altar of atomic catalysts for nitrogen reduction reaction? by Chen (2018)
10.1021/jacs.7b05213 / J. Am. Chem. Soc. / Single Mo atom supported on defective boron nitride monolayer as an efficient electrocatalyst for nitrogen fixation: a computational study by Zhao (2017)
10.1038/s41467-018-03795-8 / Nat. Commun. / Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism by Liu (2018)
10.1021/acs.jpca.8b02089 / J. Phys. Chem. A / Efficient nitrogen fixation via a redox-flexible single-Iron site with reverse-dative Iron -> boron sigma bonding by Lu (2018)
{'key': '10.1016/j.nanoen.2019.04.092_bib32', 'first-page': '1800340', 'article-title': 'N2 reduction on Fe-based complexes with different supporting main-group elements: critical roles of anchor and peripheral ligands', 'author': 'Jiang', 'year': '2018', 'journal-title': 'Small Methods'} / Small Methods / N2 reduction on Fe-based complexes with different supporting main-group elements: critical roles of anchor and peripheral ligands by Jiang (2018)
10.1021/jacs.6b04778 / J. Am. Chem. Soc. / Conversion of dinitrogen to ammonia by FeN3-embedded graphene by Li (2016)
10.1002/anie.201811728 / Angew. Chem. Int. Ed. / Atomically dispersed molybdenum catalysts for efficient ambient nitrogen fixation by Han (2019)
10.1016/j.chempr.2018.10.007 / Chemistry / Nitrogen fixation by Ru single-atom electrocatalytic reduction by Tao (2019)
10.1039/C8CC06524A / Chem. Commun. / Ambient NH3 synthesis via electrochemical reduction of N2 over cubic sub-micron SnO2 particles by Zhang (2018)
10.1038/nenergy.2016.184 / Nature Energy / Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution by Zhao (2016)
10.1007/s12274-018-2172-z / Nano Res / Two-in-one solution using insect wings to produce graphene-graphite films for efficient electrocatalysis by Li (2019)
10.1039/C8TA03974G / J. Mater. Chem. / MoO3 nanosheets for efficient electrocatalytic N2 fixation to NH3 by Han (2018)
10.1039/C8CC06365F / Chem. Commun. / Ag nanosheets for efficient electrocatalytic N2 fixation to NH3 under ambient conditions by Huang (2018)
10.1039/C8NR04524K / Nanoscale / Ambient N2 fixation to NH3 electrocatalyzed by a spinel Fe3O4 nanorod by Liu (2018)
10.1002/smll.201803111 / Small / Mn3O4 nanocube: an efficient electrocatalyst toward artificial N2 fixation to NH3 by Wu (2018)
10.1039/C8CC06366D / Chem. Commun. / Efficient and durable N2 reduction electrocatalysis under ambient conditions: β-FeOOH nanorods as a non-noble-metal catalyst by Zhu (2018)
10.1021/acscatal.8b02120 / ACS Catal. / The use of controls for consistent and accurate measurements of electrocatalytic ammonia synthesis from dinitrogen by Greenlee (2018)
10.1038/s41929-018-0092-7 / Nature Catal / Catalysts for nitrogen reduction to ammonia by Foster (2018)
10.1002/smtd.201800204 / Small Methods / Hierarchical cobalt phosphide hollow nanocages toward electrocatalytic ammonia synthesis under ambient pressure and room temperature by Guo (2018)

Dates

Type	When
Created	6 years, 3 months ago (May 3, 2019, 7:48 a.m.)
Deposited	5 years, 11 months ago (Sept. 20, 2019, 11:41 a.m.)
Indexed	3 days, 17 hours ago (Aug. 30, 2025, 12:22 p.m.)
Issued	6 years, 2 months ago (July 1, 2019)
Published	6 years, 2 months ago (July 1, 2019)
Published Print	6 years, 2 months ago (July 1, 2019)

Funders 5

National Key R&D Program of China
Awards1
1. 2017YFA0700104
National Science Fund for Distinguished Young Scholars
Awards1
1. 51825102
National Natural Science Foundation of China 10.13039/501100001809
Region: Asia
gov (National government)
Labels11
1. Chinese National Science Foundation
2. Natural Science Foundation of China
3. National Science Foundation of China
4. NNSF of China
5. NSF of China
6. 国家自然科学基金委员会
7. National Nature Science Foundation of China
8. Guójiā Zìrán Kēxué Jījīn Wěiyuánhuì
9. NSFC
10. NNSF
11. NNSFC
Awards6
1. 21677010
2. 51761165012
3. 21601136
4. 21501132
5. 21603161
6. 51671145
National Program for Thousand Young Talents of China
Tianjin Municipal Science and Technology Commission
Awards1
1. 15JCYBJC52600

BibTeX

@article{L__2019, title={Nitrogen-coordinated single Fe sites for efficient electrocatalytic N2 fixation in neutral media}, volume={61}, ISSN={2211-2855}, url={http://dx.doi.org/10.1016/j.nanoen.2019.04.092}, DOI={10.1016/j.nanoen.2019.04.092}, journal={Nano Energy}, publisher={Elsevier BV}, author={Lü, Fang and Zhao, Shunzheng and Guo, Ruijie and He, Jia and Peng, Xianyun and Bao, Haihong and Fu, Jiantao and Han, Lili and Qi, Gaocan and Luo, Jun and Tang, Xiaolong and Liu, Xijun}, year={2019}, month=jul, pages={420–427} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        30
      ]
    ],
    "date-time": "2025-08-30T16:22:02Z",
    "timestamp": 1756570922926,
    "version": "3.37.3"
  },
  "reference-count": 46,
  "publisher": "Elsevier BV",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2019,
            7,
            1
          ]
        ],
        "date-time": "2019-07-01T00:00:00Z",
        "timestamp": 1561939200000
      },
      "content-version": "tdm",
      "delay-in-days": 0,
      "URL": "https://www.elsevier.com/tdm/userlicense/1.0/"
    }
  ],
  "funder": [
    {
      "name": "National Key R&D Program of China",
      "award": [
        "2017YFA0700104"
      ]
    },
    {
      "name": "National Science Fund for Distinguished Young Scholars",
      "award": [
        "51825102"
      ]
    },
    {
      "DOI": "10.13039/501100001809",
      "name": "National Natural Science Foundation of China",
      "doi-asserted-by": "publisher",
      "award": [
        "21601136",
        "21677010",
        "21603161",
        "21501132",
        "51671145",
        "51761165012"
      ],
      "id": [
        {
          "id": "10.13039/501100001809",
          "id-type": "DOI",
          "asserted-by": "publisher"
        }
      ]
    },
    {
      "name": "National Program for Thousand Young Talents of China"
    },
    {
      "name": "Tianjin Municipal Science and Technology Commission",
      "award": [
        "15JCYBJC52600"
      ]
    }
  ],
  "content-domain": {
    "domain": [
      "elsevier.com",
      "sciencedirect.com"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        2019,
        7
      ]
    ]
  },
  "DOI": "10.1016/j.nanoen.2019.04.092",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2019,
        5,
        3
      ]
    ],
    "date-time": "2019-05-03T11:48:37Z",
    "timestamp": 1556884117000
  },
  "page": "420-427",
  "update-policy": "https://doi.org/10.1016/elsevier_cm_policy",
  "source": "Crossref",
  "is-referenced-by-count": 390,
  "special_numbering": "C",
  "title": "Nitrogen-coordinated single Fe sites for efficient electrocatalytic N2 fixation in neutral media",
  "prefix": "10.1016",
  "volume": "61",
  "author": [
    {
      "given": "Fang",
      "family": "L\u00fc",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Shunzheng",
      "family": "Zhao",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Ruijie",
      "family": "Guo",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Jia",
      "family": "He",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Xianyun",
      "family": "Peng",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Haihong",
      "family": "Bao",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Jiantao",
      "family": "Fu",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Lili",
      "family": "Han",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Gaocan",
      "family": "Qi",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Jun",
      "family": "Luo",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Xiaolong",
      "family": "Tang",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Xijun",
      "family": "Liu",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "78",
  "reference": [
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib1",
      "doi-asserted-by": "crossref",
      "first-page": "610",
      "DOI": "10.1126/science.345.6197.610",
      "article-title": "New recipe produces ammonia from air, water, and sunlight",
      "volume": "345",
      "author": "Service",
      "year": "2014",
      "journal-title": "Science"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib2",
      "doi-asserted-by": "crossref",
      "first-page": "2209",
      "DOI": "10.1021/cr8003696",
      "article-title": "Nitrogen cycle electrocatalysis",
      "volume": "109",
      "author": "Rosca",
      "year": "2009",
      "journal-title": "Chem. Rev."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib3",
      "doi-asserted-by": "crossref",
      "first-page": "45",
      "DOI": "10.1039/C7EE02220D",
      "article-title": "Rational design of electrocatalysts and photo(electro)catalysts for nitrogen reduction to ammonia (NH3) under ambient conditions",
      "volume": "11",
      "author": "Guo",
      "year": "2018",
      "journal-title": "Energy Environ. Sci."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib4",
      "doi-asserted-by": "crossref",
      "first-page": "279",
      "DOI": "10.1016/j.joule.2018.09.011",
      "article-title": "Efficient electrocatalytic N2 fixation with MXene under ambient conditions",
      "volume": "3",
      "author": "Luo",
      "year": "2019",
      "journal-title": "Joule"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib5",
      "first-page": "1800331",
      "article-title": "Defect engineering strategies for nitrogen reduction reactions under ambient conditions",
      "author": "Yan",
      "year": "2018",
      "journal-title": "Small Methods"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib6",
      "doi-asserted-by": "crossref",
      "first-page": "1610",
      "DOI": "10.1016/j.joule.2018.06.007",
      "article-title": "Boron-doped graphene for electrocatalytic N2 reduction",
      "volume": "2",
      "author": "Yu",
      "year": "2018",
      "journal-title": "Joule"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib7",
      "doi-asserted-by": "crossref",
      "first-page": "1604799",
      "DOI": "10.1002/adma.201604799",
      "article-title": "Electrochemical reduction of N2 under ambient conditions for artificial N2 fixation and renewable energy storage using N2/NH3 cycle",
      "volume": "29",
      "author": "Bao",
      "year": "2017",
      "journal-title": "Adv. Mater."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib8",
      "first-page": "1800337",
      "article-title": "Advances in electrocatalytic N2 reduction-strategies to tackle the selectivity challenge",
      "author": "Chen",
      "year": "2018",
      "journal-title": "Small Methods"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib9",
      "doi-asserted-by": "crossref",
      "first-page": "1801526",
      "DOI": "10.1002/adma.201801526",
      "article-title": "Carbon-based metal-free catalysts for key reactions involved in energy conversion and storage",
      "volume": "31",
      "author": "Zhao",
      "year": "2018",
      "journal-title": "Adv. Mater."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib10",
      "doi-asserted-by": "crossref",
      "first-page": "1805367",
      "DOI": "10.1002/adma.201805367",
      "article-title": "Carbon-based metal-free catalysts for electrocatalytic reduction of nitrogen for synthesis of ammonia at ambient conditions",
      "volume": "31",
      "author": "Zhao",
      "year": "2019",
      "journal-title": "Adv. Mater."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib11",
      "doi-asserted-by": "crossref",
      "first-page": "1801357",
      "DOI": "10.1002/aenm.201801357",
      "article-title": "Boosted electrocatalytic N2 reduction to NH3 by defect-rich MoS2 nanoflower",
      "volume": "8",
      "author": "Li",
      "year": "2018",
      "journal-title": "Adv. Energy Mater."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib12",
      "doi-asserted-by": "crossref",
      "first-page": "1800191",
      "DOI": "10.1002/adma.201800191",
      "article-title": "Electrochemical ammonia synthesis via nitrogen reduction reaction on a MoS2 catalyst: theoretical and experimental studies",
      "volume": "30",
      "author": "Zhang",
      "year": "2018",
      "journal-title": "Adv. Mater."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib13",
      "doi-asserted-by": "crossref",
      "first-page": "264",
      "DOI": "10.1016/j.nanoen.2018.07.045",
      "article-title": "Ambient N2 fixation to NH3 at ambient conditions: using Nb2O5 nanofiber as a high-performance electrocatalyst",
      "volume": "52",
      "author": "Han",
      "year": "2018",
      "journal-title": "Nano Energy"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib14",
      "doi-asserted-by": "crossref",
      "first-page": "1700001",
      "DOI": "10.1002/adma.201700001",
      "article-title": "Amorphizing of Au nanoparticles by CeOx-GO hybrid support towards highly efficient electrocatalyst for N2 reduction under ambient conditions",
      "volume": "29",
      "author": "Li",
      "year": "2017",
      "journal-title": "Adv. Mater."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib15",
      "doi-asserted-by": "crossref",
      "first-page": "1606550",
      "DOI": "10.1002/adma.201606550",
      "article-title": "Au sub-nanoclusters on TiO2 toward highly efficient and selective electrocatalyst for N2 conversion to NH3 at ambient conditions",
      "volume": "29",
      "author": "Shi",
      "year": "2017",
      "journal-title": "Adv. Mater."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib16",
      "doi-asserted-by": "crossref",
      "first-page": "1803694",
      "DOI": "10.1002/adma.201803694",
      "article-title": "Molybdenum carbide nanodots enable efficient electrocatalytic nitrogen fixation under ambient conditions",
      "volume": "30",
      "author": "Cheng",
      "year": "2018",
      "journal-title": "Adv. Mater."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib17",
      "doi-asserted-by": "crossref",
      "first-page": "6073",
      "DOI": "10.1002/anie.201801538",
      "article-title": "An amorphous noble-metal-free electrocatalyst that enables nitrogen fixation under ambient conditions",
      "volume": "57",
      "author": "Lv",
      "year": "2018",
      "journal-title": "Angew. Chem. Int. Ed."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib18",
      "doi-asserted-by": "crossref",
      "first-page": "10246",
      "DOI": "10.1002/anie.201806386",
      "article-title": "Defect engineering metal-free polymeric carbon nitride electrocatalyst for effective nitrogen fixation under ambient conditions",
      "volume": "57",
      "author": "Lv",
      "year": "2018",
      "journal-title": "Angew. Chem. Int. Ed."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib19",
      "doi-asserted-by": "crossref",
      "first-page": "341",
      "DOI": "10.1038/s41467-018-08120-x",
      "article-title": "Over 56.55% faradaic efficiency of ambient ammonia synthesis enabled by positively shifting the reaction potential",
      "volume": "10",
      "author": "Wang",
      "year": "2019",
      "journal-title": "Nat. Commun."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib20",
      "doi-asserted-by": "crossref",
      "first-page": "9312",
      "DOI": "10.1021/acscatal.8b02585",
      "article-title": "Ambient electrochemical ammonia synthesis with high selectivity on Fe/Fe oxide catalyst",
      "volume": "8",
      "author": "Hu",
      "year": "2018",
      "journal-title": "ACS Catal."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib21",
      "doi-asserted-by": "crossref",
      "first-page": "10976",
      "DOI": "10.1021/jacs.7b05372",
      "article-title": "Metal (hydr)oxides@polymer core-shell strategy to metal single-atom materials",
      "volume": "139",
      "author": "Zhang",
      "year": "2017",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib22",
      "doi-asserted-by": "crossref",
      "first-page": "1902",
      "DOI": "10.1016/j.chempr.2018.05.006",
      "article-title": "Room-temperature methane conversion by graphene-confined single Iron atoms",
      "volume": "4",
      "author": "Cui",
      "year": "2018",
      "journal-title": "Chemistry"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib23",
      "doi-asserted-by": "crossref",
      "first-page": "11594",
      "DOI": "10.1021/jacs.8b07294",
      "article-title": "Edge-site engineering of atomically dispersed Fe-N4 by selective C-N bond cleavage for enhanced oxygen reduction reaction activities",
      "volume": "140",
      "author": "Jiang",
      "year": "2018",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib24",
      "doi-asserted-by": "crossref",
      "first-page": "1800588",
      "DOI": "10.1002/adma.201800588",
      "article-title": "Fe isolated single atoms on S, N codoped carbon by copolymer pyrolysis strategy for highly efficient oxygen reduction reaction",
      "volume": "30",
      "author": "Li",
      "year": "2018",
      "journal-title": "Adv. Mater."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib25",
      "doi-asserted-by": "crossref",
      "first-page": "13694",
      "DOI": "10.1002/anie.201706921",
      "article-title": "Potential-cycling synthesis of single platinum atoms for efficient hydrogen evolution in neutral media",
      "volume": "56",
      "author": "Zhang",
      "year": "2017",
      "journal-title": "Angew. Chem. Int. Ed."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib26",
      "doi-asserted-by": "crossref",
      "first-page": "1944",
      "DOI": "10.1002/anie.201712451",
      "article-title": "Regulation of coordination number over single Co sites: triggering the efficient electroreduction of CO2",
      "volume": "57",
      "author": "Wang",
      "year": "2018",
      "journal-title": "Angew. Chem. Int. Ed."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib27",
      "doi-asserted-by": "crossref",
      "first-page": "1803498",
      "DOI": "10.1002/adma.201803498",
      "article-title": "Achieving a record-high yield rate of 120.9 for N2 electrochemical reduction over Ru single-atom catalysts",
      "volume": "30",
      "author": "Geng",
      "year": "2018",
      "journal-title": "Adv. Mater."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib28",
      "first-page": "1800291",
      "article-title": "Single or double: which is the altar of atomic catalysts for nitrogen reduction reaction?",
      "author": "Chen",
      "year": "2018",
      "journal-title": "Small Methods"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib29",
      "doi-asserted-by": "crossref",
      "first-page": "12480",
      "DOI": "10.1021/jacs.7b05213",
      "article-title": "Single Mo atom supported on defective boron nitride monolayer as an efficient electrocatalyst for nitrogen fixation: a computational study",
      "volume": "139",
      "author": "Zhao",
      "year": "2017",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib30",
      "doi-asserted-by": "crossref",
      "first-page": "1610",
      "DOI": "10.1038/s41467-018-03795-8",
      "article-title": "Heterogeneous Fe3 single-cluster catalyst for ammonia synthesis via an associative mechanism",
      "volume": "9",
      "author": "Liu",
      "year": "2018",
      "journal-title": "Nat. Commun."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib31",
      "doi-asserted-by": "crossref",
      "first-page": "4530",
      "DOI": "10.1021/acs.jpca.8b02089",
      "article-title": "Efficient nitrogen fixation via a redox-flexible single-Iron site with reverse-dative Iron -> boron sigma bonding",
      "volume": "122",
      "author": "Lu",
      "year": "2018",
      "journal-title": "J. Phys. Chem. A"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib32",
      "first-page": "1800340",
      "article-title": "N2 reduction on Fe-based complexes with different supporting main-group elements: critical roles of anchor and peripheral ligands",
      "author": "Jiang",
      "year": "2018",
      "journal-title": "Small Methods"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib33",
      "doi-asserted-by": "crossref",
      "first-page": "8706",
      "DOI": "10.1021/jacs.6b04778",
      "article-title": "Conversion of dinitrogen to ammonia by FeN3-embedded graphene",
      "volume": "138",
      "author": "Li",
      "year": "2016",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib34",
      "doi-asserted-by": "crossref",
      "first-page": "2321",
      "DOI": "10.1002/anie.201811728",
      "article-title": "Atomically dispersed molybdenum catalysts for efficient ambient nitrogen fixation",
      "volume": "58",
      "author": "Han",
      "year": "2019",
      "journal-title": "Angew. Chem. Int. Ed."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib35",
      "doi-asserted-by": "crossref",
      "first-page": "204",
      "DOI": "10.1016/j.chempr.2018.10.007",
      "article-title": "Nitrogen fixation by Ru single-atom electrocatalytic reduction",
      "volume": "5",
      "author": "Tao",
      "year": "2019",
      "journal-title": "Chemistry"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib36",
      "doi-asserted-by": "crossref",
      "first-page": "12966",
      "DOI": "10.1039/C8CC06524A",
      "article-title": "Ambient NH3 synthesis via electrochemical reduction of N2 over cubic sub-micron SnO2 particles",
      "volume": "54",
      "author": "Zhang",
      "year": "2018",
      "journal-title": "Chem. Commun."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib37",
      "doi-asserted-by": "crossref",
      "first-page": "16184",
      "DOI": "10.1038/nenergy.2016.184",
      "article-title": "Ultrathin metal\u2013organic framework nanosheets for electrocatalytic oxygen evolution",
      "volume": "1",
      "author": "Zhao",
      "year": "2016",
      "journal-title": "Nature Energy"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib38",
      "doi-asserted-by": "crossref",
      "first-page": "33",
      "DOI": "10.1007/s12274-018-2172-z",
      "article-title": "Two-in-one solution using insect wings to produce graphene-graphite films for efficient electrocatalysis",
      "volume": "12",
      "author": "Li",
      "year": "2019",
      "journal-title": "Nano Res"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib39",
      "doi-asserted-by": "crossref",
      "first-page": "12974",
      "DOI": "10.1039/C8TA03974G",
      "article-title": "MoO3 nanosheets for efficient electrocatalytic N2 fixation to NH3",
      "volume": "6",
      "author": "Han",
      "year": "2018",
      "journal-title": "J. Mater. Chem."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib40",
      "doi-asserted-by": "crossref",
      "first-page": "11427",
      "DOI": "10.1039/C8CC06365F",
      "article-title": "Ag nanosheets for efficient electrocatalytic N2 fixation to NH3 under ambient conditions",
      "volume": "54",
      "author": "Huang",
      "year": "2018",
      "journal-title": "Chem. Commun."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib41",
      "doi-asserted-by": "crossref",
      "first-page": "14386",
      "DOI": "10.1039/C8NR04524K",
      "article-title": "Ambient N2 fixation to NH3 electrocatalyzed by a spinel Fe3O4 nanorod",
      "volume": "10",
      "author": "Liu",
      "year": "2018",
      "journal-title": "Nanoscale"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib42",
      "doi-asserted-by": "crossref",
      "first-page": "1803111",
      "DOI": "10.1002/smll.201803111",
      "article-title": "Mn3O4 nanocube: an efficient electrocatalyst toward artificial N2 fixation to NH3",
      "volume": "14",
      "author": "Wu",
      "year": "2018",
      "journal-title": "Small"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib43",
      "doi-asserted-by": "crossref",
      "first-page": "11332",
      "DOI": "10.1039/C8CC06366D",
      "article-title": "Efficient and durable N2 reduction electrocatalysis under ambient conditions: \u03b2-FeOOH nanorods as a non-noble-metal catalyst",
      "volume": "54",
      "author": "Zhu",
      "year": "2018",
      "journal-title": "Chem. Commun."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib44",
      "doi-asserted-by": "crossref",
      "first-page": "7820",
      "DOI": "10.1021/acscatal.8b02120",
      "article-title": "The use of controls for consistent and accurate measurements of electrocatalytic ammonia synthesis from dinitrogen",
      "volume": "8",
      "author": "Greenlee",
      "year": "2018",
      "journal-title": "ACS Catal."
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib45",
      "doi-asserted-by": "crossref",
      "first-page": "490",
      "DOI": "10.1038/s41929-018-0092-7",
      "article-title": "Catalysts for nitrogen reduction to ammonia",
      "volume": "1",
      "author": "Foster",
      "year": "2018",
      "journal-title": "Nature Catal"
    },
    {
      "key": "10.1016/j.nanoen.2019.04.092_bib46",
      "doi-asserted-by": "crossref",
      "first-page": "1800204",
      "DOI": "10.1002/smtd.201800204",
      "article-title": "Hierarchical cobalt phosphide hollow nanocages toward electrocatalytic ammonia synthesis under ambient pressure and room temperature",
      "author": "Guo",
      "year": "2018",
      "journal-title": "Small Methods"
    }
  ],
  "container-title": "Nano Energy",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.elsevier.com/content/article/PII:S2211285519303933?httpAccept=text/xml",
      "content-type": "text/xml",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://api.elsevier.com/content/article/PII:S2211285519303933?httpAccept=text/plain",
      "content-type": "text/plain",
      "content-version": "vor",
      "intended-application": "text-mining"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2019,
        9,
        20
      ]
    ],
    "date-time": "2019-09-20T15:41:39Z",
    "timestamp": 1568994099000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://linkinghub.elsevier.com/retrieve/pii/S2211285519303933"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2019,
        7
      ]
    ]
  },
  "references-count": 46,
  "alternative-id": [
    "S2211285519303933"
  ],
  "URL": "http://dx.doi.org/10.1016/j.nanoen.2019.04.092",
  "relation": {},
  "ISSN": [
    "2211-2855"
  ],
  "subject": [],
  "container-title-short": "Nano Energy",
  "published": {
    "date-parts": [
      [
        2019,
        7
      ]
    ]
  },
  "assertion": [
    {
      "value": "Elsevier",
      "name": "publisher",
      "label": "This article is maintained by"
    },
    {
      "value": "Nitrogen-coordinated single Fe sites for efficient electrocatalytic N2 fixation in neutral media",
      "name": "articletitle",
      "label": "Article Title"
    },
    {
      "value": "Nano Energy",
      "name": "journaltitle",
      "label": "Journal Title"
    },
    {
      "value": "https://doi.org/10.1016/j.nanoen.2019.04.092",
      "name": "articlelink",
      "label": "CrossRef DOI link to publisher maintained version"
    },
    {
      "value": "article",
      "name": "content_type",
      "label": "Content Type"
    },
    {
      "value": "\u00a9 2019 Elsevier Ltd. All rights reserved.",
      "name": "copyright",
      "label": "Copyright"
    }
  ]
}