Quadrupole Effects in Nuclear Magnetic Resonance Studies of Solids
10.1016/s0081-1947(08)60105-8
Crossref book-chapter
Elsevier
Solid State Physics (78)
Bibliography

Cohen, M. H., & Reif, F. (1957). Quadrupole Effects in Nuclear Magnetic Resonance Studies of Solids. Solid State Physics, 321–438.

Authors 2
  1. M.H. Cohen (first)
  2. F. Reif (additional)
References 173 Referenced 584
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  15. From a semiclassical point of view, the absence of degeneracy in the nuclear ground state is equivalent to rapid motion of the nuclear charges in times duriig which outside fields can cause any effects. The time average charge distribution which alone is important then satisfies the condition for inversion symmetry. px) = p-x) since the Hamiltonian of the nuclear system has this symmetry.
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  165. Note added in proof: Watkins has recalculated the increase in the second moment of the central component caused by applied elastic stress (private communication). The broadening comes from the interaction between the elastic strain and the internal strains already present. Watkins now finds that C = 5 × 106 in well annealed KBr and that 1 + γ = 100 for Br in KBr. For KI, the corresponding values are C = 4 × 105 and 1 + γ = 300. The new values are in much better agreement with what might be expected on the basis of present experience.
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  171. A calculation of the latter width was carried out using the second order statistical theory of Section 20. The computations involve estimates of 1 + γ and include covalent contributions and strain effects. The result is a calculated intensity change of the order of four times greater than that observed for the concentration. C = 3 × 10−4. While suggestive of association, the result is uncertain because of the crude estimates of the field gradients.
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Created 14 years, 8 months ago (Dec. 22, 2010, 2:35 a.m.)
Deposited 6 years, 2 months ago (June 7, 2019, 3:22 a.m.)
Indexed 5 days, 5 hours ago (Aug. 20, 2025, 8:43 a.m.)
Issued 68 years, 7 months ago (Jan. 1, 1957)
Published 68 years, 7 months ago (Jan. 1, 1957)
Published Print 68 years, 7 months ago (Jan. 1, 1957)
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@inbook{Cohen_1957, title={Quadrupole Effects in Nuclear Magnetic Resonance Studies of Solids}, ISSN={0081-1947}, url={http://dx.doi.org/10.1016/s0081-1947(08)60105-8}, DOI={10.1016/s0081-1947(08)60105-8}, booktitle={Solid State Physics}, publisher={Elsevier}, author={Cohen, M.H. and Reif, F.}, year={1957}, pages={321–438} }