DOI: 10.1016/s0022-328x(01)01118-4. Substituent effects in polarized phosphaalkenes: a theoretical study of aminocarbene

Substituent effects in polarized phosphaalkenes: a theoretical study of aminocarbene–phosphinidene adducts

10.1016/s0022-328x(01)01118-4

Crossref journal-article

Elsevier BV

Journal of Organometallic Chemistry (78)

Bibliography

Frison, G., & Sevin, A. (2002). Substituent effects in polarized phosphaalkenes: a theoretical study of aminocarbeneâphosphinidene adducts. Journal of Organometallic Chemistry, 643â644, 105â111.

Authors 2

Gilles Frison (first)
Alain Sevin (additional)

References 40 Referenced 47

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The calculated singlet–triplet energy (ZPE corrected) differences of the free phosphinidenes PH, PCH3 and PCF3 are, respectively, 33.46, 29.44 and 29.43 kcal mol−1. As suggested by one referee, these values have to be taken into account to evaluate the actual strength of the PC bonds as the PR fragments must bond to the N-heterocyclic carbene as singlet species.
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Dates

Type	When
Created	22 years, 10 months ago (Oct. 14, 2002, 4:05 p.m.)
Deposited	6 years, 3 months ago (May 1, 2019, 2:54 p.m.)
Indexed	3 months, 2 weeks ago (May 15, 2025, 4:28 a.m.)
Issued	23 years, 7 months ago (Feb. 1, 2002)
Published	23 years, 7 months ago (Feb. 1, 2002)
Published Print	23 years, 7 months ago (Feb. 1, 2002)

Funders 0

None

BibTeX

@article{Frison_2002, title={Substituent effects in polarized phosphaalkenes: a theoretical study of aminocarbene–phosphinidene adducts}, volume={643–644}, ISSN={0022-328X}, url={http://dx.doi.org/10.1016/s0022-328x(01)01118-4}, DOI={10.1016/s0022-328x(01)01118-4}, journal={Journal of Organometallic Chemistry}, publisher={Elsevier BV}, author={Frison, Gilles and Sevin, Alain}, year={2002}, month=feb, pages={105–111} }

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