DOI: 10.1016/0039-6028(92)90669-w. Bonding and decomposition of thiophene, sulfhydryl, thiomethoxy and phenyl thiolate on Mo surfaces

Bonding and decomposition of thiophene, sulfhydryl, thiomethoxy and phenyl thiolate on Mo surfaces

10.1016/0039-6028(92)90669-w

Crossref journal-article

Elsevier BV

Surface Science (78)

Bibliography

Rodriguez, JosÃ©A. (1992). Bonding and decomposition of thiophene, sulfhydryl, thiomethoxy and phenyl thiolate on Mo surfaces. Surface Science, 278(3), 326â338.

Authors 1

JoséA. Rodriguez (first)

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The ΔH of the reaction: RS → R + S, was calculated for MeS (72 kcal/mol), EtS (67 kcal/mol), n-PrS (70 kcal/mol), i-PrS (67 kcal/mol) and t-BuS (64 kcal/mol). The heats of formation of S and the alkyl radicals were taken from ref. [51]. The heats of formation of MeS (29.4 kcal/mol), EtS (24.9 kcal/mol), n-PrS (17.7 kcal/mol), i-PrS (16.7 kcal/mol ) and t-BuS (8.7 kcal/mol) were determined employing the procedure described in ref. [49], using the enthalpy changes reported in ref. [91] for the reaction: RSH → RS + H.
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Dates

Type	When
Created	22 years, 10 months ago (Oct. 21, 2002, 12:08 p.m.)
Deposited	6 years, 5 months ago (April 4, 2019, 5:54 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 7:40 p.m.)
Issued	32 years, 10 months ago (Nov. 1, 1992)
Published	32 years, 10 months ago (Nov. 1, 1992)
Published Print	32 years, 10 months ago (Nov. 1, 1992)

Funders 0

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BibTeX

@article{Rodriguez_1992, title={Bonding and decomposition of thiophene, sulfhydryl, thiomethoxy and phenyl thiolate on Mo surfaces}, volume={278}, ISSN={0039-6028}, url={http://dx.doi.org/10.1016/0039-6028(92)90669-w}, DOI={10.1016/0039-6028(92)90669-w}, number={3}, journal={Surface Science}, publisher={Elsevier BV}, author={Rodriguez, JoséA.}, year={1992}, month=nov, pages={326–338} }

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      "unstructured": "The \u0394H of the reaction: RS \u2192 R + S, was calculated for MeS (72 kcal/mol), EtS (67 kcal/mol), n-PrS (70 kcal/mol), i-PrS (67 kcal/mol) and t-BuS (64 kcal/mol). The heats of formation of S and the alkyl radicals were taken from ref. [51]. The heats of formation of MeS (29.4 kcal/mol), EtS (24.9 kcal/mol), n-PrS (17.7 kcal/mol), i-PrS (16.7 kcal/mol ) and t-BuS (8.7 kcal/mol) were determined employing the procedure described in ref. [49], using the enthalpy changes reported in ref. [91] for the reaction: RSH \u2192 RS + H."
    },
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      "unstructured": "An adsorption energy of 62 kcal/mol was estimated for the CnH2n+1 S species following the procedure described in ref. [62]. A value of 103 kcal/mol was used for the adsorption energy of S on Mo [63]. The dissociation energy of the C-S bond in CnH2n\u22121S was set equal to ~ 67 kcal/mol [92]."
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