DOI: 10.1016/0039-6028(85)90033-0. Precursor adsorption of CO on Ni(111) near 5 K and the activation energy for chemisorption

Precursor adsorption of CO on Ni(111) near 5 K and the activation energy for chemisorption

10.1016/0039-6028(85)90033-0

Crossref journal-article

Elsevier BV

Surface Science (78)

Bibliography

Shayegan, M., Williams, E. D., Glover, R. E., & Park, R. L. (1985). Precursor adsorption of CO on Ni(111) near 5 K and the activation energy for chemisorption. Surface Science, 154(2â3), L239âL246.

Authors 4

M. Shayegan (first)
E.D. Williams (additional)
R.E. Glover (additional)
Robert L. Park (additional)

References 31 Referenced 19

{'first-page': '83', 'year': '1980', 'author': 'Schmidt', 'key': '10.1016/0039-6028(85)90033-0_BIB1'} by Schmidt (1980)
10.1098/rspa.1974.0120 / Proc. Roy. Soc. (London) by King (1974)
10.1063/1.1680972 / J. Chem. Phys. by Christmann (1974)
10.1016/0021-9517(76)90250-5 / J. Catalysis by Weinberg (1976)
10.1016/0022-3697(57)90054-9 / J. Phys. Chem. Solids by Kisliuk (1957)
10.1016/0022-3697(58)90132-X / J. Phys. Chem. Solids by Kisliuk (1958)
10.1016/0039-6028(79)90218-8 / Surface Sci. by Hofmann (1979)
10.1016/0039-6028(81)90146-1 / Surface Sci. by Opila (1981)
10.1016/0039-6028(81)90147-3 / Surface Sci. by Michel (1981)
10.1016/0039-6028(82)90540-4 / Surface Sci. by Hsu (1982)
10.1016/0039-6028(83)90306-0 / Surface Sci. by Tatarenko (1983)
10.1016/0039-6028(80)90278-2 / Surface Sci. by Gland (1980)
10.1016/0039-6028(81)90137-0 / Surface Sci. by Backx (1981)
10.1007/BF01375170 / Z. Physik by Rühl (1963)
10.1116/1.569587 / J. Vacuum Sci. Technol. by Chottiner (1978)
{'year': '1980', 'author': 'Chottiner', 'key': '10.1016/0039-6028(85)90033-0_BIB11_3'} by Chottiner (1980)
10.1016/0378-5963(82)90063-0 / Appl. Surface Sci. by Schmeisser (1982)
10.1103/PhysRevLett.53.1578 / Phys. Rev. Letters by Shayegan (1984)
{'year': '1984', 'author': 'Cavallo', 'key': '10.1016/0039-6028(85)90033-0_BIB13'} by Cavallo (1984)
10.1016/0039-6028(84)90012-8 / Surface Sci. by Grunze (1984)
10.1016/0039-6028(78)90375-8 / Surface Sci. by Norton (1978)
For a comprehensive review of the adsorption of CO on transition metals, see J.T. Yates Jr. and T.E. Madey, in: The Chemical Physics of Solid Surface and Heterogeneous Catalysis, Eds. D.A. King and D.P. Woodruff (Elsevier, Amsterdam, in press).
10.1016/0039-6028(73)90117-9 / Surface Sci. by Strayer (1973)
The saturation coverage for CO/Ni(111) at room temperature is reported to be θ = 0.53 ML (ref. [3]). For adsorption at 5.5 K (fig. 1b), θ = 0.53 ML corresponds to an exposure of ~ 11 L. For a given exposure, the amount of CO reaching the surface for adsorption at 77 K (fig. 1a) is larger than that at 5.5 K (due to the higher temperature of the radiation shields). Also, the sticking coefficient at 77 K may be less than unity for high coverages. The amount of CO on the surface for the 77 K and 5.5 K. exposures (fig. 2), therefore, may be quite different for the same measured exposure.
{'key': '10.1016/0039-6028(85)90033-0_BIB19', 'first-page': '1', 'volume': 'Vol. 85', 'author': 'Hölzl', 'year': '1979'} by Hölzl (1979)
Previously reported saturation value of Δφ for CO/Ni(111) is 1.1 eV for adsorption at room temperature (ref. [3]). While our lower value may be due to the differences in temperature and/or measurement techniques, the presence of small amounts of impurities on the surface cannot be excluded. In ref. [4] it was observed that spurious amounts of carbon/sulfur at the surface result in too small values of Δφ even if present in concentrations that are below the detection level of AES.
10.1103/PhysRevLett.37.1497 / Phys. Rev. Letters by Apai (1976)
10.1021/j100792a006 / J. Phys. Chem. by Blyholder (1964)
10.1116/1.1317970 / J. Vacuum Sci. Technol. by Taylor (1973)
{'key': '10.1016/0039-6028(85)90033-0_BIB24', 'first-page': '360', 'volume': '21', 'author': 'Honig', 'year': '1960', 'journal-title': 'RCA Rev.'} / RCA Rev. by Honig (1960)
10.1103/PhysRevB.30.78 / Phys. Rev. by Bader (1984)

Dates

Type	When
Created	22 years, 10 months ago (Oct. 18, 2002, 10:34 a.m.)
Deposited	6 years, 4 months ago (April 5, 2019, 11:53 a.m.)
Indexed	11 months, 1 week ago (Sept. 15, 2024, 9:25 p.m.)
Issued	40 years, 3 months ago (May 1, 1985)
Published	40 years, 3 months ago (May 1, 1985)
Published Print	40 years, 3 months ago (May 1, 1985)

Funders 0

None

BibTeX

@article{Shayegan_1985, title={Precursor adsorption of CO on Ni(111) near 5 K and the activation energy for chemisorption}, volume={154}, ISSN={0039-6028}, url={http://dx.doi.org/10.1016/0039-6028(85)90033-0}, DOI={10.1016/0039-6028(85)90033-0}, number={2–3}, journal={Surface Science}, publisher={Elsevier BV}, author={Shayegan, M. and Williams, E.D. and Glover, R.E. and Park, Robert L.}, year={1985}, month=may, pages={L239–L246} }

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