DOI: 10.1007/s11743-000-0136-x. Optimization of lipase‐catalyzed sorbitol monoester synthesis in organic medium

Optimization of lipase‐catalyzed sorbitol monoester synthesis in organic medium

10.1007/s11743-000-0136-x

Crossref journal-article

Wiley

Journal of Surfactants and Detergents (311)

Abstract

AbstractThe influence of acid/polyol molar ratio and reaction time on lipase‐catalyzed esterification of oleic acid (OA) and sorbitol was studied to determine optimal conditions for monoester synthesis. A simple mathematical model was developed to determine relationships between various parameters of technical and/or economical importance. A direct relationship. independent of OA initial concentration and reaction time, was shown between the percentage of monoester in total esters, monoester concentration (the maximum was 25–30 mM for 70–80% monoester), and sorbitol conversion rate. A high sorbitol conversion was always associated with a low percentage of monoester in total ester. No absolute optimum could be found, so that compromises should be chosen, with the help of the results presented herein, depending on the constraints on the process. Two possible optima are proposed. In both examples, monoester (25–30 mM) is 80% pure. In the first case, productivity is maximized (15 mmol·L−1·h−1), but OA and sorbitol conversions are only 40 and 60%, respectively. In the second case, a high OA conversion (>99%) is favored at the expense of monoester productivity (1.8 mmol·L−1·h−1), 60% of the sorbitol being converted. It was shown that, although sorbitol monoester has better surface properties than diester, the addition of 20% diester did not modify the interfacial activity of monoester and slightly increased its surface activity.

Bibliography

Dubreucq, E., Ducret, A., & Lortie, R. (2000). Optimization of lipaseâcatalyzed sorbitol monoester synthesis in organic medium. Journal of Surfactants and Detergents, 3(3), 327â333. Portico.

Authors 3

Eric Dubreucq (first)
Amélie Ducret (additional)
Robert Lortie (additional)

References 13 Referenced 5

{'key': 'e_1_2_1_2_1', 'first-page': '286', 'article-title': 'Food Applications of Sucrose Esters', 'volume': '29', 'author': 'Walker C.E.', 'year': '1984', 'journal-title': 'Cereal Food World'} / Cereal Food World / Food Applications of Sucrose Esters by Walker C.E. (1984)
{'key': 'e_1_2_1_3_1', 'first-page': '201', 'article-title': 'Polyol Ester Surfactants', 'volume': '72', 'author': 'Lewis J.J.', 'year': '1998', 'journal-title': 'Nonionic‐Surfactants'} / Nonionic‐Surfactants / Polyol Ester Surfactants by Lewis J.J. (1998)
10.1002/bit.260480308
10.1023/A:1018306224698
10.1002/bit.260310305
{'key': 'e_1_2_1_7_1', 'first-page': '53', 'article-title': 'Structure and Surface‐Active Property Determinations of Fructose Monooleates', 'volume': '1', 'author': 'Jung S.', 'year': '1998', 'journal-title': 'J. Surfact. Deterg.'} / J. Surfact. Deterg. / Structure and Surface‐Active Property Determinations of Fructose Monooleates by Jung S. (1998)
10.1007/BF02523456
10.1002/bit.260400116
10.1007/s11743-998-0035-1
10.1016/S0141-0229(96)00090-7
10.1002/(SICI)1097-0290(19981005)60:1<53::AID-BIT6>3.0.CO;2-#
{'key': 'e_1_2_1_13_1', 'first-page': '129', 'article-title': 'Influence of Water Activity on the Synthesis of Triolein Catalyzed by Immobilized Mucor miehei Lipase', 'volume': '45', 'author': 'Dudal Y.', 'year': '1995', 'journal-title': 'Ibid.'} / Ibid. / Influence of Water Activity on the Synthesis of Triolein Catalyzed by Immobilized Mucor miehei Lipase by Dudal Y. (1995)
10.1080/03610918408812407

Dates

Type	When
Created	18 years, 9 months ago (Nov. 15, 2006, 6:54 a.m.)
Deposited	1 year, 11 months ago (Sept. 27, 2023, 11:17 p.m.)
Indexed	1 year, 10 months ago (Oct. 4, 2023, 2:27 a.m.)
Issued	25 years, 1 month ago (July 1, 2000)
Published	25 years, 1 month ago (July 1, 2000)
Published Online	25 years, 1 month ago (July 1, 2000)
Published Print	25 years, 1 month ago (July 1, 2000)

Funders 0

None

BibTeX

@article{Dubreucq_2000, title={Optimization of lipase‐catalyzed sorbitol monoester synthesis in organic medium}, volume={3}, ISSN={1558-9293}, url={http://dx.doi.org/10.1007/s11743-000-0136-x}, DOI={10.1007/s11743-000-0136-x}, number={3}, journal={Journal of Surfactants and Detergents}, publisher={Wiley}, author={Dubreucq, Eric and Ducret, Amélie and Lortie, Robert}, year={2000}, month=jul, pages={327–333} }

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