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Topics in Current Chemistry (297)
References
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Referenced
53
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For an analogous explanation of striking differences in 1H-NMR spectra of compounds C6H3D2CAlk3 and C6H3D2CHal3 see Whitesides, G. M., Selgestad, J. G., Thomas, S. P., Andrews, D. W., Morrison, B. A., Panek, E. J., San Fillipo, J., Jr.: J. Organomet. Chem. 22, 365 (1970)
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This compound is twice described in literature (Kraus, C. A., Eatough, H.: J. Am. Chem. Soc. 55, 5014 (1933); Mattson, D. S., Wilcsek, R. J.: J. Organomet. Chem. 57, 231 (1973)), but in each case the product is according to the melting point or the 1H-NMR-data not tris(triphenylstannyl)methane (41) which was obtained in our laboratory57) by reacting of bis(triphenylstannyl)methyllithium (40) with triphenylstannylchloride. The melting point of 41 is 181 °C
(
10.1021/ja01339a051
) / J. Am. Chem. Soc. by C. A. Kraus (1933) - Note added in proof: In the meantime we were able to realize the transformation in an olefin: A. Rensing, K.-J. Echsler, Th. Kauffmann, Tetrahedron Lett., in press