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Kauffmann, T. (n.d.). In search of new organometallic reagents for organic synthesis. Organic Chemistry, 109–147.

Authors 1
  1. Thomas Kauffmann (first)
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  86. For an analogous explanation of striking differences in 1H-NMR spectra of compounds C6H3D2CAlk3 and C6H3D2CHal3 see Whitesides, G. M., Selgestad, J. G., Thomas, S. P., Andrews, D. W., Morrison, B. A., Panek, E. J., San Fillipo, J., Jr.: J. Organomet. Chem. 22, 365 (1970) (10.1016/S0022-328X(00)86055-6) / J. Organomet. Chem. by G. M. Whitesides (1970)
  87. This compound is twice described in literature (Kraus, C. A., Eatough, H.: J. Am. Chem. Soc. 55, 5014 (1933); Mattson, D. S., Wilcsek, R. J.: J. Organomet. Chem. 57, 231 (1973)), but in each case the product is according to the melting point or the 1H-NMR-data not tris(triphenylstannyl)methane (41) which was obtained in our laboratory57) by reacting of bis(triphenylstannyl)methyllithium (40) with triphenylstannylchloride. The melting point of 41 is 181 °C (10.1021/ja01339a051) / J. Am. Chem. Soc. by C. A. Kraus (1933)
  88. Note added in proof: In the meantime we were able to realize the transformation in an olefin: A. Rensing, K.-J. Echsler, Th. Kauffmann, Tetrahedron Lett., in press
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Created 19 years, 8 months ago (Dec. 10, 2005, 10:40 p.m.)
Deposited 5 years, 4 months ago (April 11, 2020, 5:55 a.m.)
Indexed 11 months, 3 weeks ago (Sept. 4, 2024, 9:36 a.m.)
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@inbook{Kauffmann, title={In search of new organometallic reagents for organic synthesis}, ISBN={3540100482}, url={http://dx.doi.org/10.1007/bfb0034358}, DOI={10.1007/bfb0034358}, booktitle={Organic Chemistry}, publisher={Springer-Verlag}, author={Kauffmann, Thomas}, pages={109–147} }