DOI: 10.1007/bf02666773. Chromatographic analysis of polyglycerols and their fatty acid esters

Chromatographic analysis of polyglycerols and their fatty acid esters

10.1007/bf02666773

Crossref journal-article

Wiley

Journal of the American Oil Chemists' Society (311)

Abstract

AbstractPolyglycerols and their fatty acid esters have been analyzed by gas‐liquid chromatography (GLC) as trimethylsilyl ether derivatives. Linear diglycerols and triglycerols were isolated from commercial polyglycerols by vacuum distillation. Mono‐ and di‐fatty acid esters were synthesized in the laboratory. Two isomers of diglycerol have been separated and identified. GLC analysis was carried out on columns packed with 3% JXR on Gas Chrom Q. Response factors for diglycerol and triglycerol relative to glycerol have been established. Commercial polyglycerol esters are shown to be mixtures of glycerol, free fatty acids, mono‐ and diglycerides, and mono‐ fatty acid esters of diglycerol and triglycerol. Separation of free polyglycerols and their esters is also demonstrated by thin‐layer chromatography on Silica Gel‐G containing 4.0% boric acid.

Bibliography

Sahasrabudhe, M. R. (1967). Chromatographic analysis of polyglycerols and their fatty acid esters. Journal of the American Oil Chemistsâ Society, 44(7), 376â378. Portico.

Authors 1

M. R. Sahasrabudhe (first)

References 26 Referenced 39

10.1021/jo01084a637
Harris M. U.S. Patent Nos. 2 022 766; 2 023 388 (1935).
{'key': 'e_1_2_1_4_1', 'first-page': '5', 'volume': '13', 'author': 'Isitin M.', 'year': '1946', 'journal-title': 'Ann. faculte sci. Marseille'} / Ann. faculte sci. Marseille by Isitin M. (1946)
{'key': 'e_1_2_1_5_1', 'first-page': '345', 'volume': '187', 'author': 'Rangier M.', 'year': '1928', 'journal-title': 'Compt. Rend.'} / Compt. Rend. by Rangier M. (1928)
10.1021/ja01180a018
10.1021/ac60209a054
10.1021/ja01632a028
10.1007/BF02638125
{'key': 'e_1_2_1_10_1', 'first-page': '394', 'volume': '35', 'author': 'Troy A.', 'year': '1958', 'journal-title': 'Ibid.'} / Ibid. by Troy A. (1958)
{'key': 'e_1_2_1_11_1', 'first-page': '209', 'volume': '11', 'author': 'Wurzinger J.', 'year': '1962', 'journal-title': 'Brot und Geback'} / Brot und Geback by Wurzinger J. (1962)
10.1021/ja01203a027
{'key': 'e_1_2_1_13_1', 'first-page': '446', 'volume': '68', 'author': 'Wright H. J.', 'year': '1946', 'journal-title': 'Ibid.'} / Ibid. by Wright H. J. (1946)
{'key': 'e_1_2_1_14_1', 'first-page': '179', 'volume': '6', 'author': 'Zajic J.', 'year': '1962', 'journal-title': 'Potravinarska technologie'} / Potravinarska technologie by Zajic J. (1962)
10.1021/ac60204a010
Langer S. H. P.PangalesandI.Wender Chem. Ind. (London)1664(1958).
10.1021/ja00899a032
10.1016/0006-3002(61)90426-7
10.1016/0003-2697(62)90003-9
{'key': 'e_1_2_1_20_1', 'first-page': '523', 'volume': '5', 'author': 'Mikita M. M.', 'year': '1963', 'journal-title': 'Ibid.'} / Ibid. by Mikita M. M. (1963)
10.1007/BF02541121
{'key': 'e_1_2_1_22_1', 'first-page': '379', 'volume': '44', 'author': 'Sahasrabudhe M. R.', 'year': '1967', 'journal-title': 'Ibid.'} / Ibid. by Sahasrabudhe M. R. (1967)
{'key': 'e_1_2_1_23_1', 'first-page': '62', 'volume-title': 'Fusion Methods in Chemical Microscopy', 'author': 'McCrone W. C.', 'year': '1957'} / Fusion Methods in Chemical Microscopy by McCrone W. C. (1957)
AOCS Official and Tentative Methods 2nd ed. Chicago 1946method Cd 4–40.
Hartman L. J. Chem. Soc. (London)3572(1957). (10.1039/jr9570003572)
Sahasrabudhe M. R. unpublished.
{'key': 'e_1_2_1_27_1', 'first-page': '337', 'volume': '49', 'author': 'Sahasrabudhe M. R.', 'year': '1966', 'journal-title': 'J. Assoc. Off. Anal. Chem.'} / J. Assoc. Off. Anal. Chem. by Sahasrabudhe M. R. (1966)

Dates

Type	When
Created	18 years, 1 month ago (July 16, 2007, 5:29 p.m.)
Deposited	2 years ago (Aug. 19, 2023, 8:07 a.m.)
Indexed	1 year, 6 months ago (Feb. 20, 2024, 3:56 a.m.)
Issued	58 years, 1 month ago (July 1, 1967)
Published	58 years, 1 month ago (July 1, 1967)
Published Online	58 years, 1 month ago (July 1, 1967)
Published Print	58 years, 1 month ago (July 1, 1967)

Funders 0

None

BibTeX

@article{Sahasrabudhe_1967, title={Chromatographic analysis of polyglycerols and their fatty acid esters}, volume={44}, ISSN={1558-9331}, url={http://dx.doi.org/10.1007/bf02666773}, DOI={10.1007/bf02666773}, number={7}, journal={Journal of the American Oil Chemists’ Society}, publisher={Wiley}, author={Sahasrabudhe, M. R.}, year={1967}, month=jul, pages={376–378} }

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