DOI: 10.1007/bf02636909. Phase behavior of aqueous systems of monoglycerides

Phase behavior of aqueous systems of monoglycerides

10.1007/bf02636909

Crossref journal-article

Wiley

Journal of the American Oil Chemists' Society (311)

Abstract

AbstractMonoglyceride‐H2O systems in the range above about 5% H2O exhibit a varied phase behavior with a number of mesomorphic states reminiscent of those found for soap‐H2O systems. There are fluid neat, stiff and 舠short舡 viscous isotropic, and plastic or stringy middle states.In the case of saturated monoglycerides, neat states prevail at low molecular weight as with monolaurin, but viscous isotropic and finally middle states appear at higher chain length as with monoarchidin and monobehenin.The phase diagrams for systems of unsaturated compounds resemble those for systems of saturated compounds, with corresponding phase regions occurring at lower temperatures. The monoelaidin‐H2O system closely resembles a shifted monostearin‐H2O system, neither system showing middle. Middle phase appears in a small island for monoolein and monolinolein near 90C and 20% water.Water dissolves negligible amounts of monoglycerides so that phases which are nearly 100% H2O exist for substantially all systems and conditions when H2O content is 60% or more.

Bibliography

Lutton, E. S. (1965). Phase behavior of aqueous systems of monoglycerides. Journal of the American Oil Chemistsâ Society, 42(12Part2), 1068â1070. Portico.

Authors 1

E. S. Lutton (first)

References 10 Referenced 206

{'key': 'e_1_2_1_2_1', 'first-page': '48', 'volume': '16', 'author': 'Vold R. D.', 'year': '1939', 'journal-title': 'JAOCS'} / JAOCS by Vold R. D. (1939)
{'key': 'e_1_2_1_3_1', 'first-page': '137', 'volume': '1', 'author': 'McBain J. W.', 'year': '1926', 'journal-title': 'Colloid Chemistry'} / Colloid Chemistry by McBain J. W. (1926)
Marsden S. S. Jr. andJ. W.McBain J. Phys. Colloid Chem.52 110(1948). (10.1021/j150457a012)
10.1007/BF02582741
10.1021/j100794a005
10.1021/cr50018a002
{'key': 'e_1_2_1_8_1', 'first-page': '168', 'volume-title': 'Melting and Solidification of Fats', 'author': 'Bailey A. E.', 'year': '1950'} / Melting and Solidification of Fats by Bailey A. E. (1950)
10.1007/BF02545595
Luzzati V. H.MustacchiandA.Skoulios Disc. Far. Soc.No.25 43(1958). (10.1039/df9582500043)
10.1038/180600a0

Dates

Type	When
Created	18 years, 2 months ago (May 25, 2007, 7:06 a.m.)
Deposited	1 year, 10 months ago (Sept. 27, 2023, 1:18 p.m.)
Indexed	3 weeks ago (Aug. 2, 2025, 12:13 a.m.)
Issued	59 years, 8 months ago (Dec. 1, 1965)
Published	59 years, 8 months ago (Dec. 1, 1965)
Published Online	59 years, 8 months ago (Dec. 1, 1965)
Published Print	59 years, 8 months ago (Dec. 1, 1965)

Funders 0

None

BibTeX

@article{Lutton_1965, title={Phase behavior of aqueous systems of monoglycerides}, volume={42}, ISSN={1558-9331}, url={http://dx.doi.org/10.1007/bf02636909}, DOI={10.1007/bf02636909}, number={12Part2}, journal={Journal of the American Oil Chemists’ Society}, publisher={Wiley}, author={Lutton, E. S.}, year={1965}, month=dec, pages={1068–1070} }

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