DOI: 10.1007/bf02541032. A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions

A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions

10.1007/bf02541032

Crossref journal-article

Wiley

Journal of the American Oil Chemists' Society (311)

Abstract

AbstractAn empirical correlation is presented for the estimation of critical micellization concentrations (CMC) and critical micellization temperatures (CMT) for poly(ethylene oxide)‐block‐poly(propylene oxide)‐block‐poly(ethylene oxide) copolymers in aqueous solutions. The CMC and CMT are expressed as a function of the polyol molecular weight, composition, and temperature (for CMC determination) or concentration (in the case of CMT). The correlation was developed from experimental CMT data for a set of 12 polyols that covered a wide range of molecular weights (2900–14600) and poly(ethylene oxide) contents (30–80 wt%) and is based on a simple expression for the standard free energy of micellization. Such a correlation should be useful to practitioners of the field as it allows easy prediction of CMC and CMT for a wide range of polyols with a minimal number of input parameters.

Bibliography

Alexandridis, P., Holzwarth, J. F., & Alan Hatton, T. (1995). A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions. Journal of the American Oil Chemistsâ Society, 72(7), 823â826. Portico.

Authors 3

Paschalis Alexandridis (first)
Josef F. Holzwarth (additional)
T. Alan Hatton (additional)

References 16 Referenced 29

{'key': 'e_1_2_1_2_1', 'volume-title': 'Nonionic Surfactants', 'author': 'Schmolka I.R.', 'year': '1967'} / Nonionic Surfactants by Schmolka I.R. (1967)
10.1007/BF02894385
10.1016/0927-7757(94)03028-X
10.6028/NBS.NSRDS.36
{'key': 'e_1_2_1_6_1', 'volume-title': 'Dynamic Properties of Interfaces and Association Structures', 'author': 'Alexandridis P.', 'year': '1995'} / Dynamic Properties of Interfaces and Association Structures by Alexandridis P. (1995)
{'key': 'e_1_2_1_7_1', 'volume-title': 'Solubilization in Surfactant Aggregates', 'author': 'Hurter P.N.', 'year': '1995'} / Solubilization in Surfactant Aggregates by Hurter P.N. (1995)
10.1021/ma00087a009
10.1021/la00020a019
{'key': 'e_1_2_1_10_1', 'first-page': '730', 'volume': '11', 'author': 'Nivaggioli T.', 'year': '1995', 'journal-title': 'Ibid.'} / Ibid. by Nivaggioli T. (1995)
{'key': 'e_1_2_1_11_1', 'first-page': '1468', 'volume': '11', 'author': 'Alexandridis P.', 'year': '1995', 'journal-title': 'Ibid.'} / Ibid. by Alexandridis P. (1995)
10.1021/la00001a023
{'key': 'e_1_2_1_13_1', 'volume-title': 'Foundations of Colloid Science', 'author': 'Hunter R.J.', 'year': '1987'} / Foundations of Colloid Science by Hunter R.J. (1987)
{'key': 'e_1_2_1_14_1', 'volume-title': 'Thermodynamics and Dynamics of Micellization and Micelle‐Solute Interactions in Block‐Copolymer and Reverse‐Micellar Systems, Ph.D. Thesis', 'author': 'Alexandridis P.', 'year': '1994'} / Thermodynamics and Dynamics of Micellization and Micelle‐Solute Interactions in Block‐Copolymer and Reverse‐Micellar Systems, Ph.D. Thesis by Alexandridis P. (1994)
10.1021/ma00183a030
10.1063/1.456390
10.1016/0032-3861(91)90206-X

Dates

Type	When
Created	18 years, 8 months ago (Jan. 5, 2007, 1:58 a.m.)
Deposited	1 year, 11 months ago (Sept. 28, 2023, 5:32 a.m.)
Indexed	1 year, 8 months ago (Jan. 3, 2024, 12:39 a.m.)
Issued	30 years, 2 months ago (July 1, 1995)
Published	30 years, 2 months ago (July 1, 1995)
Published Online	30 years, 2 months ago (July 1, 1995)
Published Print	30 years, 2 months ago (July 1, 1995)

Funders 0

None

BibTeX

@article{Alexandridis_1995, title={A correlation for the estimation of critical micellization concentrations and temperatures of polyols in aqueous solutions}, volume={72}, ISSN={1558-9331}, url={http://dx.doi.org/10.1007/bf02541032}, DOI={10.1007/bf02541032}, number={7}, journal={Journal of the American Oil Chemists’ Society}, publisher={Wiley}, author={Alexandridis, Paschalis and Holzwarth, Josef F. and Alan Hatton, T.}, year={1995}, month=jul, pages={823–826} }

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