Metal Clusters 22 The Polynuclear Rhodium Hydride Set {HRhL2}n
10.1007/978-1-4613-2958-9_33
Crossref book-chapter
Springer US
Fundamental Research in Homogeneous Catalysis (297)
Bibliography

Muetterties, E. L., Sivak, A. J., Brown, R. K., Williams, J. W., Fredrich, M. F., & Day, V. W. (1979). Metal Clusters 22 The Polynuclear Rhodium Hydride Set {HRhL2}n. Fundamental Research in Homogeneous Catalysis, 487–497.

Authors 6
  1. E. L. Muetterties (first)
  2. A. J. Sivak (additional)
  3. R. K. Brown (additional)
  4. J. W. Williams (additional)
  5. M. F. Fredrich (additional)
  6. V. W. Day (additional)
References 29 Referenced 3
  1. Paper 21 in this series. R. K. Brown, J. W. Williams, M. F. Fredrich and V. W. Day, Proc. Natl. Acad. Sci. 76, 0000 (1979). / Proc. Natl. Acad. Sci. by RK Brown (1979)
  2. To whom correspondence should be addressed. Present address: Department of Chemistry, University of California, Berkeley, CA 94720.
  3. E. L. Muetterties, Bull. Soc, Chim. Belg. 84, 959(1975), (10.1002/bscb.19750841006) / Bull. Soc, Chim. Belg. by EL Muetterties (1975)
  4. E. L. Muetterties, Bull. Soc, Chim. Belg. 85, 451 (1976). / Bull. Soc, Chim. Belg. by EL Muetterties (1976)
  5. E, L. Muetterties, Science 196, 839 (1977). / Science by EL Muetterties (1977)
  6. E. L. Muetterties, T. Rhodin, E. Band, C. Brucker and W. R. Pretzer, Chem. Rev. 79 0000 (1979). / Chem. Rev. by EL Muetterties (1979)
  7. E. Band and E. L. Muetterties, Chem. Rev. 78, 639 (1978). (10.1021/cr60316a003) / Chem. Rev. by E Band (1978)
  8. P. Chini, personal communication.
  9. V. G. Albano, A. Ceriotti, P. Chini, G. Ciani, S. Martinego and W. N. Anker, J. Chem. Soc., Chem. Commun. 859(1975). / J. Chem. Soc., Chem. Commun. by VG Albano (1975)
  10. S. Martinego, G. Ciani, A. Sironi and P. Chini, J. Am. Chem. Soc. 100, 7096 (1978). / Bull. Soc, Chim. Belg. by S Martinego (1975)
  11. V. Albano, M. Sansoni, P. Chini and S. Martinego, J. Chem. Soc., Dalton Trans. 651(1973). / J. Chem. Soc., Dalton Trans. by V Albano (1973)
  12. J. L. Vidal, R. A. Fiato, L. A. Cosby and R. L. Pruett, Inorg. Chem. 17, 2574 (1979). (10.1021/ic50187a043) / Inorg. Chem. by JL Vidal (1979)
  13. J. L. Vidal, personal communication.
  14. R. W. Broach, L. F. Dahl, G. Longoni, P. Chini, A. J. Schultz and J. M. Williams, Adv. Chem. Ser. 167, 93 (1978). (10.1021/ba-1978-0167.ch007) / Adv. Chem. Ser. by RW Broach (1978)
  15. J. Lewis and B. F. G. Johnson, J. Pure and Applied Chem. 44, 43 (1975). (10.1351/pac197544010043) / J. Pure and Applied Chem. by J Lewis (1975)
  16. L. Brewer, Progr. Material Science 13, 231 (1967). / Progr. Material Science by L Brewer (1967)
  17. L. Brewer, Science 161, 115 (1968). / Science by L Brewer (1968)
  18. J. A. Connor, Topics Current Chem. 71, 71(1977). (10.1007/BFb0047779) / Topics Current Chem by JA Connor (1977)
  19. See, for example, the synthesis, structure, and catalytic chemistry of our tetranickel isocyanide clusters: M. G. Thomas, W. R. Pretzer, B. F. Beier, F. J. Hirsekorn and E. L. Muetterties, J. Am. Chem. Soc. 99, 743(1977) and references therein. (10.1021/ja00445a014) / J. Am. Chem. Soc. by MG Thomas (1977)
  20. An alternative strategy that can successfully circumvent the proclivity of some clusters to fragment is use of a cluster that has one or more very weakly bound ligands that through facile dissociation processes can generate the requisite sites for substrate binding in catalytic cycles.
  21. A. J. Poë and M. V. Twigg, Inorg. Chem. 13, 2982 (1974) (10.1021/ic50142a040) / Inorg. Chem. by AJ Poë (1974)
  22. D. P. Keeton, S. K. Malik and A. J. Poë, J. Chem. Soc., Dalton Trans. 233(1977) and references therein. / J. Chem. Soc., Dalton Trans. by DP Keeton (1977)
  23. C. P. Casey and C. Cyr, J. Am. Chem. Soc. 95, 2248 (1973). (10.1021/ja00788a025) / J. Am. Chem. Soc. by CP Casey (1973)
  24. V. W. Day, M. F. Fredrich, G. S. Reddy, A. J. Sivak, W. R. Pretzer and E. L. Muetterties, J. Am. Chem. Soc. 99, 8091 (1977). (10.1021/ja00466a074) / J. Am. Chem. Soc by VW Day (1977)
  25. A.J. Sivak and E. L. Muetterties, J. Am. Chem. Soc. 101, 0000 (1979). (10.1021/ja00511a016) / J. Am. Chem. Soc. by AJ Sivak (1979)
  26. Here again fragmentation of a cluster may occur if the metal aggregate is weakly held together or if the largely M-M bonding orbitals are substantially affected in the generation of additional M-L ligand bonding orbitals in any part of the reaction cycle.
  27. Ligand or substrate binding may substantially weaken the metal-metal bonds at a metallic surface. Although an unzipping process to yield molecular species cannot occur for these surface atoms unless26 a volatile species, e. g., a metal carbonyl, is formed, there may be a surface (metal atom) reconstruction following or concurrent with the actual chemisorption process. Individual metal atoms at a surface are not rigidly fixed. Scission of metal-metal bonds can occur.
  28. Of course, reactants like oxygen, sulfur and halogens can generate non-metallic surfaces such as oxides, sulfides and halides whereby there is no essential metal-metal bonding extant in the outer surface layers.
  29. E. L. Muetterties, Boron Hydride Chemistry, Academic Press, New York, 1975, pp. 1–3. / Boron Hydride Chemistry by EL Muetterties (1975)
Dates
Type When
Created 13 years, 9 months ago (Nov. 9, 2011, 10:28 a.m.)
Deposited 4 years, 3 months ago (May 1, 2021, 3:59 a.m.)
Indexed 11 months, 3 weeks ago (Sept. 6, 2024, 10:15 a.m.)
Issued 46 years, 7 months ago (Jan. 1, 1979)
Published 46 years, 7 months ago (Jan. 1, 1979)
Published Print 46 years, 7 months ago (Jan. 1, 1979)
Funders 0

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@inbook{Muetterties_1979, title={Metal Clusters 22 The Polynuclear Rhodium Hydride Set {HRhL2}n}, ISBN={9781461329589}, url={http://dx.doi.org/10.1007/978-1-4613-2958-9_33}, DOI={10.1007/978-1-4613-2958-9_33}, booktitle={Fundamental Research in Homogeneous Catalysis}, publisher={Springer US}, author={Muetterties, E. L. and Sivak, A. J. and Brown, R. K. and Williams, J. W. and Fredrich, M. F. and Day, V. W.}, year={1979}, pages={487–497} }