DOI: 10.1002/zaac.200300051. A Novel 3D Framework Coordination Polymer based on Succinato bridged Helical Chains Connected by 4, 4' ‐ Bipyridine: [Cu(bpy)(H2O)2(C4H4O4)]?2H2O

A Novel 3D Framework Coordination Polymer based on Succinato bridged Helical Chains Connected by 4, 4' ‐ Bipyridine: [Cu(bpy)(H2O)2(C4H4O4)]?2H2O

10.1002/zaac.200300051

Crossref journal-article

Wiley

Zeitschrift für anorganische und allgemeine Chemie (311)

Abstract

AbstractBlue needle—shaped crystals of [Cu(bpy)(H2O)2(C4H4O4)]· 2H2O were obtained by slow evaporation of a methanolic aqueous solution containing a fresh Cu(C4H4O4)· 2H2O precipitate, 4, 4′—bipyridine, and ammonia. Within the complex, the six—coordinated Cu atoms are linked by bis—monodentate gauche succinate anions into chains propagating helically around the [001] axis. The chains are interconnected by 4, 4′—bipyridine ligands into a 3D framework with the crystal H2O molecules located in the channels along the [100], [010] and [110] directions. The Cu2+ ions are in distorted octahedral coordination of two nitrogen and four oxygen atoms (equatorial bonds: Cu—N 1.986(5), 2.015(5)Å; Cu—O 1.950(6), 1.954(6)Å; axial bonds Cu—O: 2.524(9), 2.539(8)Å). Furthermore, the thermal and magnetic behavior of the compound will be discussed. Crystal data: hexagonal, P61 (no. 169), a = 11.066(2)Å, c = 24.965(5)Å, V = 2647.5(8)Å3, Z = 6, R = 0.0528 and wR2 = 0.1103 for 1426 observed reflections (Fo2 > 2σ(Fo2)) out of 2170 unique reflections.

Bibliography

Zheng, Y., & Kong, Z. (2003). A Novel 3D Framework Coordination Polymer based on Succinato bridged Helical Chains Connected by 4, 4â â Bipyridine: [Cu(bpy)(H2O)2(C4H4O4)]?2H2O. Zeitschrift FÃ¼r Anorganische Und Allgemeine Chemie, 629(9), 1469â1471. Portico.

Authors 2

Yue‐Qing Zheng (first)
Zu‐Ping Kong (additional)

References 19 Referenced 47

10.1021/cr9900432
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Dates

Type	When
Created	22 years ago (Aug. 22, 2003, 9:57 a.m.)
Deposited	1 year, 9 months ago (Nov. 17, 2023, 6:58 p.m.)
Indexed	3 weeks, 2 days ago (July 30, 2025, 10:12 a.m.)
Issued	22 years ago (Aug. 1, 2003)
Published	22 years ago (Aug. 1, 2003)
Published Online	22 years ago (Aug. 11, 2003)
Published Print	22 years ago (Aug. 1, 2003)

Funders 0

None

BibTeX

@article{Zheng_2003, title={A Novel 3D Framework Coordination Polymer based on Succinato bridged Helical Chains Connected by 4, 4’ ‐ Bipyridine: [Cu(bpy)(H2O)2(C4H4O4)]?2H2O}, volume={629}, ISSN={1521-3749}, url={http://dx.doi.org/10.1002/zaac.200300051}, DOI={10.1002/zaac.200300051}, number={9}, journal={Zeitschrift für anorganische und allgemeine Chemie}, publisher={Wiley}, author={Zheng, Yue‐Qing and Kong, Zu‐Ping}, year={2003}, month=aug, pages={1469–1471} }

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  "abstract": "<jats:title>Abstract</jats:title><jats:p>Blue needle\u2014shaped crystals of [Cu(bpy)(H<jats:sub>2</jats:sub>O)<jats:sub>2</jats:sub>(C<jats:sub>4</jats:sub>H<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>)]\u00b7 2H<jats:sub>2</jats:sub>O were obtained by slow evaporation of a methanolic aqueous solution containing a fresh Cu(C<jats:sub>4</jats:sub>H<jats:sub>4</jats:sub>O<jats:sub>4</jats:sub>)\u00b7 2H<jats:sub>2</jats:sub>O precipitate, 4, 4\u2032\u2014bipyridine, and ammonia. Within the complex, the six\u2014coordinated Cu atoms are linked by bis\u2014monodentate gauche succinate anions into chains propagating helically around the [001] axis. The chains are interconnected by 4, 4\u2032\u2014bipyridine ligands into a 3D framework with the crystal H<jats:sub>2</jats:sub>O molecules located in the channels along the [100], [010] and [110] directions. The Cu<jats:sup>2+</jats:sup> ions are in distorted octahedral coordination of two nitrogen and four oxygen atoms (equatorial bonds: Cu\u2014N 1.986(5), 2.015(5)\u00c5; Cu\u2014O 1.950(6), 1.954(6)\u00c5; axial bonds Cu\u2014O: 2.524(9), 2.539(8)\u00c5). Furthermore, the thermal and magnetic behavior of the compound will be discussed. Crystal data: hexagonal, <jats:italic> P</jats:italic>6<jats:sub>1</jats:sub> (no. 169), a = 11.066(2)\u00c5, c = 24.965(5)\u00c5, <jats:italic>V</jats:italic> = 2647.5(8)\u00c5<jats:sup>3</jats:sup>, <jats:italic>Z</jats:italic> = 6, <jats:italic>R</jats:italic> = 0.0528 and <jats:italic>wR</jats:italic><jats:sub>2</jats:sub> = 0.1103 for 1426 observed reflections (<jats:italic>F<jats:sub>o</jats:sub><jats:sup>2</jats:sup></jats:italic> &gt; 2\u03c3(<jats:italic>F<jats:sub>o</jats:sub><jats:sup>2</jats:sup></jats:italic>)) out of 2170 unique reflections.</jats:p>",
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