DOI: 10.1002/zaac.19915980112. Neue oktaedrische Metallcluster des Zr und V Die Kristallstrukturen von [Cp6Zr6S9] und [V6Se8O(PMe3)6]

Neue oktaedrische Metallcluster des Zr und V Die Kristallstrukturen von [Cp6Zr6S9] und [V6Se8O(PMe3)6]

10.1002/zaac.19915980112

Crossref journal-article

Wiley

Zeitschrift für anorganische und allgemeine Chemie (311)

Abstract

AbstractBei der Reaktion von [CpZrCl3] mit S(SiMe3)2, bzw. von [CpVCl2(PMe3)2] mit Se(SiMe3)2 entstehen die sechskernigen Komplexe [Cp6Zr6S9] (1) bzw. [V6Se8O(PMe3)6] (2). Die Struktur von 1 besteht aus einem Zr6‐Oktaeder, dessen Polyederflächen von μ3‐S‐Liganden besetzt sind, und die Cp‐Liganden sind η5 an die Zr‐Atome gebunden. Auch in 2 liegt ein Oktaeder vor, das aus 6 V‐Atomen gebildet wird und von μ3‐Se‐Liganden koordiniert wird. 1 und 2 enthalten jeweils im Clusterzentrum ein zusätzliches S‐bzw. O‐Atom.

Bibliography

Fenske, D., Grissinger, M. A., Loos, M., & Magull, J. (1991). Neue oktaedrische Metallcluster des Zr und V Die Kristallstrukturen von [Cp6Zr6S9] und [V6Se8O(PMe3)6]. Zeitschrift FÃ¼r Anorganische Und Allgemeine Chemie, 598(1), 121â128. Portico.

Authors 4

D. Fenske (first)
M. A. Grissinger (additional)
M. Loos (additional)
J. Magull (additional)

References 35 Referenced 30

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Dates

Type	When
Created	20 years, 7 months ago (Jan. 2, 2005, 3 a.m.)
Deposited	1 year, 10 months ago (Oct. 22, 2023, 6:48 p.m.)
Indexed	1 year, 6 months ago (Feb. 20, 2024, 3:59 a.m.)
Issued	34 years, 2 months ago (June 1, 1991)
Published	34 years, 2 months ago (June 1, 1991)
Published Online	20 years, 9 months ago (Nov. 9, 2004)
Published Print	34 years, 2 months ago (June 1, 1991)

Funders 0

None

BibTeX

@article{Fenske_1991, title={Neue oktaedrische Metallcluster des Zr und V Die Kristallstrukturen von [Cp6Zr6S9] und [V6Se8O(PMe3)6]}, volume={598}, ISSN={1521-3749}, url={http://dx.doi.org/10.1002/zaac.19915980112}, DOI={10.1002/zaac.19915980112}, number={1}, journal={Zeitschrift für anorganische und allgemeine Chemie}, publisher={Wiley}, author={Fenske, D. and Grissinger, M. A. and Loos, M. and Magull, J.}, year={1991}, month=jun, pages={121–128} }

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