DOI: 10.1002/zaac.19905820124. CO hydrogenation over potassium promoted iron, cobalt, and nickel Catalysts Prepared from Cyanide Complexes

CO hydrogenation over potassium promoted iron, cobalt, and nickel Catalysts Prepared from Cyanide Complexes

10.1002/zaac.19905820124

Crossref journal-article

Wiley

Zeitschrift für anorganische und allgemeine Chemie (311)

Abstract

AbstractSeveral potassium promoted catalysts have been prepared by adsorption of K4[Fe(CN)6], K3[Co(CN)6] and K2[Ni(CN)4] on acid‐modified γ‐alumina. Subsequent H2 treatment with or without previous calcination step has been carried out in order to study the influence of the sample pretreatment on the catalytic behavior in the CO hydrogenation reaction. Some characteristics of the catalysts have been studied after reaction by means of Mössbauer and X‐ray photoelectron spectroscopic techniques. The catalytic properties for CO hydrogenation were found to be affected by the pretreatment conditions, especially for iron catalysts. A high selectivity to olefins and a low production of long chain hydrocarbons were obtained in the reaction over non‐calcined iron catalysts. For iron catalysts noticeable differences in the Anderson‐Schulz‐Flory distribution of hydrocarbons were induced by the catalyst pretreatment. Such differences induced by catalyst pretreatments were, however, smaller for cobalt‐containing catalysts. In the CO hydrogenation on potassium‐promoted nickel catalysts a high production of long chain hydrocarbons and a high selectivity to olefins were found when compared to the unpromoted nickel‐catalysts.

Bibliography

RodriguezâRamos, I., GuerreroâRuiz, A., Fierro, J. L. G., de la Piscina, P. R., & Homs, N. (1990). CO hydrogenation over potassium promoted iron, cobalt, and nickel Catalysts Prepared from Cyanide Complexes. Zeitschrift FÃ¼r Anorganische Und Allgemeine Chemie, 582(1), 197â210. Portico.

Authors 5

I. Rodriguez‐Ramos (first)
A. Guerrero‐Ruiz (additional)
J. L. G. Fierro (additional)
P. Ramirez de la Piscina (additional)
N. Homs (additional)

References 35 Referenced 3

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{'key': 'e_1_2_1_3_2', 'first-page': '276', 'volume': '4', 'author': 'Fischer F.', 'year': '1923', 'journal-title': 'Brennst. Chem.'} / Brennst. Chem. by Fischer F. (1923)
{'key': 'e_1_2_1_3_3', 'first-page': '217', 'volume': '5', 'year': '1924', 'journal-title': 'Brennst. Chem.'} / Brennst. Chem. (1924)
{'key': 'e_1_2_1_4_2', 'volume-title': 'The Fischer‐Tropsch and Related Synthesis', 'author': 'Storch H. H.', 'year': '1951'} / The Fischer‐Tropsch and Related Synthesis by Storch H. H. (1951)
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Dates

Type	When
Created	20 years, 8 months ago (Jan. 5, 2005, 10:18 a.m.)
Deposited	1 year, 10 months ago (Oct. 22, 2023, 11:17 a.m.)
Indexed	1 year, 10 months ago (Oct. 23, 2023, 1:08 a.m.)
Issued	35 years, 6 months ago (March 1, 1990)
Published	35 years, 6 months ago (March 1, 1990)
Published Online	20 years, 9 months ago (Nov. 9, 2004)
Published Print	35 years, 6 months ago (March 1, 1990)

Funders 0

None

BibTeX

@article{Rodriguez_Ramos_1990, title={CO hydrogenation over potassium promoted iron, cobalt, and nickel Catalysts Prepared from Cyanide Complexes}, volume={582}, ISSN={1521-3749}, url={http://dx.doi.org/10.1002/zaac.19905820124}, DOI={10.1002/zaac.19905820124}, number={1}, journal={Zeitschrift für anorganische und allgemeine Chemie}, publisher={Wiley}, author={Rodriguez‐Ramos, I. and Guerrero‐Ruiz, A. and Fierro, J. L. G. and de la Piscina, P. Ramirez and Homs, N.}, year={1990}, month=mar, pages={197–210} }

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