DOI: 10.1002/zaac.19673530503. Untersuchungen am Graphitoxid V. Über den Bildungsmechanismus des Graphitoxids

Untersuchungen am Graphitoxid V. Über den Bildungsmechanismus des Graphitoxids

10.1002/zaac.19673530503

Crossref journal-article

Wiley

Zeitschrift für anorganische und allgemeine Chemie (311)

Abstract

AbstractGraphitoxid entsteht aus Graphit und leicht Sauerstoff abgebenden Oxydationsmitteln nur dann, wenn der Graphit zuerst zum Graphitsalz (CA− · 2 HA) oxydiert wird. Die weitere Oxydation verläuft um so schneller und vollständiger, je mehr Wasser die Oxydations‐mischung enthält, wobei jedoch eine kritische Konzentration, bei der die Graphitsalze zersetzt werden, nicht überschritten werden darf. In konz. HClO4 gelingt auch die elektrochemische Oxydation zu Graphitoxid. Bei der Bildung von Graphitoxid geht nahezu kein Kohlenstoff verloren; das Netzwerk der Kohlenstoffatome in den Schichten des Graphitoxids enthält keine Löcher oder Fehlstellen.

Bibliography

Boehm, H. P., Eckel, M., & Scholz, W. (1967). Untersuchungen am Graphitoxid V. Ãber den Bildungsmechanismus des Graphitoxids. Zeitschrift FÃ¼r Anorganische Und Allgemeine Chemie, 353(5â6), 236â242. Portico.

Authors 3

H. P. Boehm (first)
M. Eckel (additional)
W. Scholz (additional)

References 21 Referenced 71

10.1002/jlac.19666910102
10.1098/rstl.1859.0013
10.1002/jlac.18601140103
10.1002/cber.18980310237
10.1021/ja01539a017
10.1002/zaac.19372340405
W.Scholz Dissertation Univ. Heidelberg1964.
10.1007/BF01518573
10.1002/cber.19390720417
{'key': 'e_1_2_1_9_2', 'first-page': '381', 'volume': '76', 'author': 'Ruess G.', 'year': '1946', 'journal-title': 'Mh. Chem.'} / Mh. Chem. by Ruess G. (1946)
10.1002/zaac.19572910502
{'key': 'e_1_2_1_11_2', 'first-page': '160', 'volume': '61', 'author': 'de Boer J. H.', 'year': '1958', 'journal-title': 'Proc. Kon. nederl. Akad. Wetensch., Ser. B'} / Proc. Kon. nederl. Akad. Wetensch., Ser. B by de Boer J. H. (1958)
10.1002/cber.19300630543
10.1002/jlac.19345100102
{'key': 'e_1_2_1_14_2', 'first-page': '242', 'volume': '61', 'author': 'de Boer J. H.', 'year': '1958', 'journal-title': 'Proc. Kon. nederl. Akad. Wetensch., Ser. B'} / Proc. Kon. nederl. Akad. Wetensch., Ser. B by de Boer J. H. (1958)
10.1002/zaac.19191050109
10.1002/zaac.19382380102
{'key': 'e_1_2_1_17_2', 'first-page': '920', 'volume': '148', 'author': 'Charpy G.', 'year': '1909', 'journal-title': 'C. R. hebd. Séances Acad. Sci.'} / C. R. hebd. Séances Acad. Sci. by Charpy G. (1909)
{'key': 'e_1_2_1_18_2', 'first-page': '26', 'volume': '40', 'author': 'Thiele H.', 'year': '1934', 'journal-title': 'Z. Elektrochem. angew. physik. Chem.'} / Z. Elektrochem. angew. physik. Chem. by Thiele H. (1934)
M. J.Bottomley G. S.Parry A. R.Ubbelohdeu.D. A.Young J. chem. Soc. [London]1963 5674. (10.1039/jr9630005674)
Vgl. z.B. A. R.Ubbelohdeu.F. A.Lewis Graphite and its Crystal Compounds S.18 ff. Oxford1960.

Dates

Type	When
Created	20 years, 7 months ago (Jan. 4, 2005, 10:17 p.m.)
Deposited	1 year, 11 months ago (Aug. 31, 2023, 9:08 a.m.)
Indexed	1 month, 3 weeks ago (June 25, 2025, 8:52 p.m.)
Issued	57 years, 11 months ago (Sept. 1, 1967)
Published	57 years, 11 months ago (Sept. 1, 1967)
Published Online	20 years, 9 months ago (Nov. 9, 2004)
Published Print	57 years, 11 months ago (Sept. 1, 1967)

Funders 0

None

BibTeX

@article{Boehm_1967, title={Untersuchungen am Graphitoxid V. Über den Bildungsmechanismus des Graphitoxids}, volume={353}, ISSN={1521-3749}, url={http://dx.doi.org/10.1002/zaac.19673530503}, DOI={10.1002/zaac.19673530503}, number={5–6}, journal={Zeitschrift für anorganische und allgemeine Chemie}, publisher={Wiley}, author={Boehm, H. P. and Eckel, M. and Scholz, W.}, year={1967}, month=sep, pages={236–242} }

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