DOI: 10.1002/tcr.10034. Synthesis of Silylene and Silyl(silylene)metal Complexes

Synthesis of Silylene and Silyl(silylene)metal Complexes

10.1002/tcr.10034

Crossref journal-article

Wiley

The Chemical Record (311)

Abstract

AbstractIn 1987, two research groups published the first‐ever reports on the synthesis of silylene complexes and presented structural evidence. Since then, a range of synthetic methods have been developed and a number of silylene complexes have been prepared. In 1988, we reported on the first base‐stabilized bis(silylene) complexes that can be regarded as being masked silyl(silylene) complexes. These complexes occupy a unique position among silylene and silyl(silylene) complexes in that they provide a convenient tool for studying the reactivity of coordinated silylenes. They are stable enough to be isolated, but the bond between the silylene silicon atom and the internal base can easily be cleaved by thermal perturbation to generate real silyl(silylene) complexes. To date, a number of base‐stabilized bis(silylene) complexes have been prepared in which the central metals range from group 5 to group 9. Only two base‐free silyl(silylene) complexes have been prepared. One is prepared by reacting a platinum complex with a stable silylene; the other is produced by the photolysis of a tungsten complex in the presence of a hydrodisilane. © 2002 The Japan Chemical Journal Forum and Wiley Periodicals, Inc. Chem Rec 2: 291–306, 2002: Published online in Wiley InterScience (www.interscience.wiley.com) DOI 10.1002/tcr.10034

Bibliography

Ogino, H. (2002). Synthesis of Silylene and Silyl(silylene)metal Complexes. The Chemical Record, 2(5), 291â306. Portico.

Authors 1

Hiroshi Ogino (first)

References 60 Referenced 120

Abbreviations used in this paper: Cp = C5H5; Cp* = C5Me5; Cp′ = general expression for substituted and nonsubstituted cyclopentadienyl ligands; HMPA = hexamethylphosphoramide; OTf = trifluoromethanesulfonate ion; Mes = mesityl;pTol = p‐tolyl; TPP = meso‐tetra‐p‐tolylporphyrin.
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Recently we examined similar systems: for instance heating Si2Me5H in the presence of a catalytic amount ofcis‐PtMe2(PEt3)2at 90 °C for 18 h in C6D6afforded linear oligosilanes up to Si9Me19H.5
Tobita H.;Moteki Y.;Ogino H.Unpublished results.
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(a)Maddock S.M.;Rickard C.E.F.;Roper W.;Salter D.M.;Wright L.J.New Zealand Institute of Chemistry Conference Auckland 1993 INO‐OR 01. (b)Roper W.;Kwok W.‐H.;Mohlen M.;Rickard C.;Williamson A.;Woodman T.;Wright L.2000. International Chemical Congress of Pacific Basin Societies Hawaii INOR 1095.
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Dates

Type	When
Created	22 years, 10 months ago (Oct. 9, 2002, 2:11 a.m.)
Deposited	1 year, 10 months ago (Oct. 13, 2023, 5:26 p.m.)
Indexed	1 month, 4 weeks ago (July 2, 2025, 12:53 p.m.)
Issued	23 years ago (Sept. 1, 2002)
Published	23 years ago (Sept. 1, 2002)
Published Online	22 years, 10 months ago (Oct. 3, 2002)
Published Print	23 years ago (Sept. 1, 2002)

Funders 0

None

BibTeX

@article{Ogino_2002, title={Synthesis of Silylene and Silyl(silylene)metal Complexes}, volume={2}, ISSN={1528-0691}, url={http://dx.doi.org/10.1002/tcr.10034}, DOI={10.1002/tcr.10034}, number={5}, journal={The Chemical Record}, publisher={Wiley}, author={Ogino, Hiroshi}, year={2002}, month=sep, pages={291–306} }

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