DOI: 10.1002/star.19770290306. Preparation of 5‐Hydroxymethylfurfural Part I. Dehydration of Fructose in a Continuous Stirred Tank Reactor

Preparation of 5‐Hydroxymethylfurfural Part I. Dehydration of Fructose in a Continuous Stirred Tank Reactor

10.1002/star.19770290306

Crossref journal-article

Wiley

Starch - Stärke (311)

Abstract

AbstractA continuous process for the manufacture of 5‐hydroxy methylfurfural (HMF), using a stirred tank reactor with simultaneous reaction and extraction was studied. Methylisobutylketone (MIBK) was used as the extraction agent. The experiments were carried out at elevated temperatures and moderate acidity. Other process parameters were the initial concentration of D‐fructose, the residence time, and the ratio of MIBK and H2O. Though the effect of extraction was limited due to the fact that the formation of HMF was faster than its breakdown, the use of MIBK as a cosolvent appeared to have a beneficial influence on the course of the reaction. The productivity at short residence times is lowered due to the stability of intermediate products.

Bibliography

Kuster, B. F. M., & Van Steen, H. J. C. D. (1977). Preparation of 5âHydroxymethylfurfural Part I. Dehydration of Fructose in a Continuous Stirred Tank Reactor. Starch - StÃ¤rke, 29(3), 99â103. Portico.

Authors 2

B. F. M. Kuster (first)
H. J. C. Der Van Steen (additional)

References 19 Referenced 63

Kuster B. F. M. L. M.Tebbens:Carbohyd. Res.1977.
Kuster B. F. M. H. S.van der Baan:Carbohyd. Res.1977.
Kuster B. F. M.:Carbohyd. Res.1977.
Kuster B. F. M. H. M. G.Temmink:Carbohyd. Res.1977.
Kuster B. F. M.: Thesis T. H. Eindhoven (The Netherlands)1975.
10.1016/S0096-5332(08)60064-8
Breen J. J.: Thesis T. H. Delft (The Netherlands)1964.
{'key': 'e_1_2_1_9_2', 'first-page': '161', 'volume': '14', 'author': 'Moye C. J.', 'year': '1964', 'journal-title': 'Rev. Pure Appl. Chem.'} / Rev. Pure Appl. Chem. by Moye C. J. (1964)
U. S. Patents 2 498 918 (1952);
2 750 394 (1956);
2 917 520 (1959).
10.1002/star.19740261003
10.1021/ie50521a057
Brit. Patents 876 463 (1961);
925 812 (1963).
Australian Patents 250 453 (1964);
261 561 (1965).
U. S. Patents 2 929 823;
3 483 228.

Dates

Type	When
Created	18 years, 10 months ago (Nov. 3, 2006, 8:41 p.m.)
Deposited	1 year, 10 months ago (Nov. 3, 2023, 5:38 p.m.)
Indexed	5 months, 2 weeks ago (March 19, 2025, 11:54 a.m.)
Issued	48 years, 8 months ago (Jan. 1, 1977)
Published	48 years, 8 months ago (Jan. 1, 1977)
Published Online	18 years, 10 months ago (Oct. 23, 2006)
Published Print	48 years, 8 months ago (Jan. 1, 1977)

Funders 0

None

BibTeX

@article{Kuster_1977, title={Preparation of 5‐Hydroxymethylfurfural Part I. Dehydration of Fructose in a Continuous Stirred Tank Reactor}, volume={29}, ISSN={1521-379X}, url={http://dx.doi.org/10.1002/star.19770290306}, DOI={10.1002/star.19770290306}, number={3}, journal={Starch - Stärke}, publisher={Wiley}, author={Kuster, B. F. M. and Van Steen, H. J. C. Der}, year={1977}, month=jan, pages={99–103} }

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